• Textile Coloration and Finishing
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• v.32 no.4
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• pp.217-225
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• 2020

In this study, the dyeing characteristics of nylon fabric which is dyed with supercritical fluid were investigated. There were two dyes used in the dyeing experiment: C.I. Disperse Red 167 and C.I. Disperse Violet 93. Dyeing temperature, pressure, and leveling time were fixed at 110℃, 250bar, 60minutes, and the experiment was conducted with dyeing concentration of 0.1, 0.3, 0.5, and 0.85% o.w.f. The analysis of the experimental results was found out through the measurement of washing fastness and color coordinate. In addition, the calibration curve of each dye was drawn up and the amount of remaining dye was checked by measuring the absorbance of the residual dye. As a result of color difference measurement, as the concentration increased, the L⁎ value decreased and the K/S value increased. However, the increase in K/S value compared to the amount of input decreased as the concentration increased. The comparative experiment on the amount of residual dye(C.I. Disperse Red 167) in the pot showed that 99.14% of the amount was dyed at the concentration of 0.1% o.w.f, while it rapidly decreased to 77% at 0.85% o.w.f. C.I. Disperse Violet 93 dye also decreased from 0.5% o.w.f to 93.91%. In the washing fastness experiment of both dyes, the level of washing fastness began to decrease from samples dyed at 0.5% o.w.f. It may be because the simply absorbed dye was produced instead of completely being fixed in the amorphous region of the nylon fiber.

• Proceedings of the Korean Fiber Society Conference
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• 2000.04a
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• pp.225-228
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• 2000

• Fashion Information and Technology
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• v.7
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• pp.22-26
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• 2010

• Textile Coloration and Finishing
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• v.33 no.1
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• pp.10-23
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• 2021

In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Textile Coloration and Finishing
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• v.34 no.2
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• pp.93-101
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• 2022

In this study, the dyeing properties of supercritical fluid dyed cotton fabrics were investigated which use two types of dyes, such as C.I. Disperse orange and C.I. Disperse red 167. Dyeing temperature, pressure and leveling time were equally applied at 130 ℃, 250 bar, and 60 minutes with reference to the related literature, and experiments were performed at concentrations of 0.04, 0.1, 0.4 and 0.8 % o.w.f with different concentrations. Dyeability was confirmed through measurement of washing fastness and color coordinate, and a calibration curve of each dye was drawn up and the absorbance of the residual dye was measured to confirm the amount of residual dye and the dye exhaustion rate at the corresponding concentration. As a result of color difference measurement, as the concentration increased, the L^* value decreased and the K/S value increased. However, as the concentration increased, the increase in K/S value decreased compared to the input amount, and this tendency was more obvious in C.I. Disperse red 167 than in C.I. Disperse orange 155. The dye exhaustion rate which was calculated by using the amount of residual dye in the pot was also C.I. Disperse orange 155 was 96.16 % and C.I. Disperse red 167 was 94.57 %. However, as the dyeing concentration increased, the dye exhaustion rate decreased, that C.I. Disperse orange was 95.33 % and C.I. Disperse red 167 was 90.63 %. As a result of the washing fastness test for both dyes, dyed samples of which concentrations were 0.4 and 0.8 % o.w.f decreased by 0.5 ~ 1.0 grade. This is predicted because the dye did not completely adhere to the amorphous region of the cotton fiber and the dye simply adsorbed. The fastness to rubbing also maintained at least grade 3-4 up to the 0.1 % o.w.f concentration, but at the concentration of 0.4 % o.w.f or higher, it fell to grade 1 or lower, showing a very poor friction fastness.

• Polymer(Korea)
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• v.35 no.5
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• pp.458-466
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• 2011

In the mixed system of supercritical carbon dioxide/organic solvents, poly(vinyl alcohol)(PVA) film of high degree of hydrolysis could be dyed with a dichroic dye of C. I. direct black 22(DB22) and as a result, high durability was obtained. Especially, as a dye dispersant in a supercritical fluid phase, a mixed solvent system of ethylene glycol: dimethyl sulfoxide=4 : 6 weight ratio was investigated. Then the optimum pressure for dyeing could be reduced down to 200 bar. Using this supercritical fluid system, the maximum dyeing appeared as the transmittance of less than 1% and the waste amount was reduced to the level of 1/10. After 500% drawing of this PVA film, both the polarizing efficiency of 94% and the single piece transmittance of 30% were obtained. The limitation of DB22 and further improvements were also discussed.

• Clean Technology
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• v.17 no.2
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• pp.110-116
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• 2011

The dyeing of polyester fiber with two different disperse dyes (Disperse Red 60 and Disperse Yellow 54) was carried out using supercritical carbon dioxide ($SCCO_2$) as a dyeing medium at temperatures ranging from $50^{\circ}C$ to $90^{\circ}C$ and at pressures from 15 MPa to 30 MPa. The dye uptake of Disperse Red 60 on polyester fiber was found to increase with temperature at constant pressure and $SCCO_2$ density (700 kg/$m^3$). At $90^{\circ}C$ and 30 MPa, the dye uptake on polyester fiber increased with dyeing time and the saturation concentration of Red 60 was attained within 240 min, while a longer dyeing time was required for Yellow 54 to reach its saturation concentration. When dyestuff mixtures with mixing ratios of 0.01 to 9.0 (Red 60/Yellow 54) were used, the uptake ratio of the two dyes was found to be proportional to 0.26 power of their mixing ratio. Dyed fibers showed an orange color and the depth of the color depended upon the mixing ratio of the dyestuffs.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.135-146
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• 2019

A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Clean Technology
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• v.10 no.3
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• pp.149-158
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• 2004

Supercritical carbon dioxide is often promoted as an environmentally friendly solvent having useful properties for a wide range of technical and chemical processes. But the limited ability of $CO_2$ to dissolve polar or non-volatile compounds represents a major drawback in many processes, because the key components will often fail to form homogeneous solution under practical conditions. The design of $CO_2$ soluble ($CO_2$-philic) surfactant to aid this process is therefore paramount in these areas, which has advanced the "greening" of demanding yet important applications in dyeing, cleaning of fibers and texiles, polymerization and polymer processing, photoresist removal, electroplating, and chemical synthesis.