• 제목/요약/키워드: Sulfonated $TiO_2$

검색결과 3건 처리시간 0.175초

Fabrication and separation performance of polyethersulfone/sulfonated TiO2 (PES-STiO2) ultrafiltration membranes for fouling mitigation

  • Ayyaru, Sivasankaran;Ahn, Young-Ho
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.199-209
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    • 2018
  • Polyethersulfone (PES)/sulfonated $TiO_2$ ($STiO_2$) nanoparticles (NPs) UF blended membranes were fabricated with different loadings of $STiO_2$. The modified membranes exhibited significant improvement in surface roughness, porosity, and pore size when compared to the PES membrane. The $P-STiO_2$ 1 and $P-TiO_2$ 1 blended membranes exhibited higher water flux, approximately 102.4% and 62.6%, respectively, compared to PES. SPP-$STiO_2$ and $P-STiO_2$ showed lower Rir fouling resistance than the $P-TiO_2$ blended membrane. Overall, the $STiO_2$-blended membranes provide high hydrophilicity permeability, anti-fouling performance, and improved BSA rejection attributed to the hydrogen bonding force and more electrostatic repulsion properties of $STiO_2$.

Preparation and Characterization of $TiO_2$Filled Sulfonated Poly(ether ether ketone) Nanocomposite Membranes for Direct Methanol Fuel Cells

  • Kim Han-Joo;Kalappa Prashantha;Son Won-Keun;Park Jong-Eun;Oshaka Tetsuya;Kim Hyun-Hoo;Hong Ji-Sook;Park Soo-Gil
    • KIEE International Transactions on Electrophysics and Applications
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    • 제5C권4호
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    • pp.165-170
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticle content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.