• Title/Summary/Keyword: Sulfate source

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Source-Receptor Relationships of Transboundary Air Pollutants in East Asia Region Simulated by On-Line Transport Model

  • Jang, Eun-Suk;Itsushi Uno
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.2
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    • pp.111-116
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    • 2000
  • Transboundary air pollution has recently become an area of increasing scientific interest and political concern as countries are receiving air pollutants from their neighbors. In order to gain a better understanding of the long-range transport processes of air pollutants and the source-receptor relationships among neighboring countries, an atmospheric transport model coupled with a RAMS(Regional Atmospheric Modeling System) model was applied to the East Asia region during the entire month of January 1993. The scalar transport option of the RAMS model was used to calculate special atmospheric constituents such as trace gases or aerosols. The sulfate production in clouds and rainwater and its removal processes by dry and wet deposition were considered. The sulfate budget from source regions to receptor regions was estimated by analysing the source-receptor relationships. When a specific receptor site revealed a sulfate value higher than the sulfate concentration based on its own source origin, this was taken to indicate long-range transport from another source region. The contribution ratio from various source region was calculated. The contribution ratio of dry and wet deposition was higher on the main continent of the East region. Furthermore, the high deposition amounts were identified on the west coast of Korea and the East China Sea.

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Effect of Sulfate Source on Removal Efficiency in Electrokinetic Bioremediation of Phenanthrene-Contaminated Soil (Pnenanthrene-오염토양의 동전기 생물학적복원에서 제거효율에 대한 황산염원의 영향)

  • Kim, Sang-Joon;Park, Ji-Yeon;Lee, You-Jin;Yang, Ji-Won
    • KSBB Journal
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    • v.21 no.6 s.101
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    • pp.428-432
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    • 2006
  • This study investigated the effect of sulfate source on removal efficiency in electrokinetic bioremediation which needs sulfate to degrade contaminants by an applied microorganism. The representative contaminant and the applied microorganism were phenanthrene and Sphingomonas sp. 3Y, respectively. When magnesium sulfate was used, the magnesium ion combined with hydroxyl ion electrically-generated at cathode to cause the decrease of electrolyte pH, and then the microbial activity was inhibited by that. When ammonium sulfate and disodium sulfate were used to solve the pH control problem, the pH values of electrolyte and soil solution were maintained neutrally, and also the high microbial activity was observed. With the former sulfate source, however, ammonium retarded the phenanthrene degradation, and so the removal efficiency decreased to 12.0% rather than 21.8% with magnesium sulfate. On the other hand, the latter improved the removal efficiency to 27.2%. This difference of removal efficiency would be outstanding for an elongated treatment period.

Removal of Heavy Metals from Acid Mine Drainage Using Sulfate Reducing Bacteria (황산염환원균을 이용한 폐광폐수의 중금속 제거)

  • Paik, Byeong Cheon;Kim, Kwang Bok
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.2
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    • pp.47-54
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    • 1999
  • SRB(Sulfate Reducing Bacteria) converts sulfate into sulfide using an organic carbon source as the electron donor. The sulfide formed precipitates the various metals present in the AMD (Acid Mine Drainage). This study is the fundamental research on heavy metal removal from AMD using SRB. Two completely mixed anaerobic reactors were operated for cultivation of SRB at the temperature of $30^{\circ}C$ and anaerobic batch reactors were used to evaluate the effects of carbon source, COD/sulfate($SO_4^=$) ratio and alkalinity on sulfate reduction rate and heavy metal removal efficiency. AMD used in this study was characterized by low pH 3.0 and 1000mg/l of sulfate and dissolved high concentration of heavy metals such as iron, cadmium, copper, zinc and lead. It was found that glucose was an organic carbon source better than acetate as the electron donor of SRB for sulfate reduction in AMD. Amount of sulfate reduction maximized at the COD(glucose)/sulfate ratio of 0.5 in the influent and then removal efficiencies of heavy metals were 97.5% of Cu, 100% of Pb, 100% of Cr, 49% of Mn, 98% of Zn, 100% Cd and 92.4% of Fe. Although sulfate reduction results in an increase in the alkalinity of the reactor, alkalinity of 1000mg/1 (as $CaCo_3$) should be should be added continuously to the anaerobic reactor in order to remove heavy metals from AMD.

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Source Apportionment of Fine Particle $PM_{2.5}$ in Beijing, China

  • Zhang, Yuanhang;Zhu, Xianlei;Zeng, Limin;Wang, Wei
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.216-225
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    • 2003
  • Fine particles with aerodynamic diameter less than 2.5 ${\mu}m$ (PM2.5) were collected from three sites in Beijing during April, August, and November 2000 and January 2001. After chemical components in samples are analyzed, a chemical mass balance (CMB) receptor model using PARs as tracers is applied to quantify the source contributions to PM2.5 in Beijing. The results show that the major sources are coal combustion, fugitive dust, vehicle exhaust, secondary sulfate and nitrate, and organic matter while biomass burning and construction dust contribute only a small fraction. In addition, source inventory in Beijing is used to determine the primary source contributions. The two methods result in comparable results. Source apportionment at three sampling sites presents similar contributions to PM2.5 although the sites are far away from each other. However, distinct seasonal pattern is presented for the source contributions from coal combustion, fugitive dust, biomass burning, secondary sulfate and nitrate.

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동위원소를 이용한 폐금속광산 지역 오염원 추적 연구

  • Yeom Seung-Jun;Lee Pyeong-Gu;Lee In-Gyeong;Lee Uk-Jong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.209-212
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    • 2006
  • Using sulfur sotope analysis of dissolved sulfate in surface water, we have investigated the source of sulfate in order to identify the abandoned metallic mines, which have the potential of heavy metal contamination within watershed. The range of the sulfur isotope values for dissolved sulfate in stream waters (DD-1 and 2) are similar to those of sulfides from the Dunjun mine, which suggests that oxidation of sulfides is the principal source of $SO_4^{2-}$ in these stream waters. Also, heavier sulfur isotopes in waters near Baekjun and Hamchang mines imply the possibility of contamination in waters by these metallic mines.

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Effects of Medium Components on L-Ornithine Production by Brevibacterium ketoglutamicum

  • TaeHo Lee;Yon
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.41-45
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    • 1996
  • Effects of yeast extract and ammonium sulfate were investigated on the production of L-or-nithine by an arginine auxotroph, Brevibacterium ketoglutamicum in flask and batch cultures. Yeast extract as an arginine source and ammonium sulfate as an inorganic nitrogen source had significant effects on L-ornithine production and cell growth. L-ornithine production was repressed by the excessive addition of arginine. Reversion of auxotrophic cells to the wild type was observed when the initial yeast extract concenfration was too low. There existed optimum concentrations of yeast extract and ammonium sulfate for L-or-nithine production. The effects of yeast extract and ammonium sulfate concentrations of the Leudeking-Piret model parameters were examined to analyze the relationship between cell growth and L-ornithine production.

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Estimation of Source Contribution for PM10 by Chemical Mass Balance(CMB) in Busan

  • Jeon, Byung-Il;Lee, Young-Mi
    • Journal of Environmental Science International
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    • v.17 no.4
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    • pp.359-364
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    • 2008
  • PM10 samples were collected from July 2007 to Oct. 2007 at Gwaebopdong(inland area) and Dongsamdong(coastal area), in Busan. This paper investigates the contribution of emission sources to PM10 mass in Busan. Source apportionment results derived from the chemical mass balance(CMB) method. A source profiles applied in this study is organized to minimize the collinearity among sources type via statistical method. Source profiles applied in this study utilized a measured value of fine particle directly sampled from metropolitan area such as Seoul and Incheon, After a CMB modeling, sulfate and nitrate related sources among those contributing to PM10 in Busan showed high contribution by 36.53% in Gwaebopdong and 42.02% in Dongsamdong.

Effect of Medium Components on the Production of Cyclosporin A by Immobilized Fungal Cell, Tolypocladium inflatum (배지성분이 고정화 곰팡이 세포를 이용한 Cyclosporin A 생산에 미치는 영향)

  • 이태호;장용근전계택
    • KSBB Journal
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    • v.11 no.5
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    • pp.613-621
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    • 1996
  • The effects of important medium components such as carbon, nitrogen sources and amino acids on the production of cyclosporin A(CyA) were investigated in an immobilized fungal cell fermentation using Tolypocladium inflatum. As carbon sources in the synthetic medium, fructose and maltose stimulated CyA production remarkably compared to glucose when ammonium sulfate was supplemented as a nitrogen source. In the absence of ammonium sulfate in the medium, however, CyA biosynthesis was reduced considerably without regard to C-sources tested. Ammonium sulfate was found to be the best N-source, and also ammonium phosphate and ammonium citrate showed some positive effects on CyA production. Optimum concentration of ammonium sulfate was 10g/L, and supplementation of ammonium sulfate at the start of fermentation was found to be the most efficacious for maximal production of CyA. Among the constituent amino acids of cyclic peptide, CyA, L-valine had the most significant effect on the biosynthesis of CyA, and maximum CyA production was observed when 10 g/L of L-valine was initially added.

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Isolation and Identificatioh~ of a Phthalate Ester Degrading Bacterium and the Optimal Culture Conditions for Production of One Degrading Enzyme (프탈레이트 에스터 분해세균의 분리 및 분해효소의 최적 생성조건)

  • Kim, Byung-O;Kim, Ran-Sug;Jin, Ing-Nyol;Park, Wan
    • Microbiology and Biotechnology Letters
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    • v.18 no.6
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    • pp.553-559
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    • 1990
  • A strain degrading phthalate ester was isolated from a sludge of Taegu area and identified as a strain of Klebsiella. The optimum culture conditions for the protocatechuate dioxygenase production were also investigated. This strain produced the enzyme in question under the shaking cultivation at $30^{\circ}C$for the 48 hrs in the medium containing 0.1% protocatechuate as the sole carbon source, 0.1% ammonium sulfate and 0.1% yeast extract as the nitrogen source and mineral salt mixture of magnesium sulfate, sodium chloride, calcium chloride, ferric chloride, manganese sulfate, zinc sulfate and cupric sulfate. This enzyme was intracellularl j localized and probably linked to cell membrane, and induced by protocatechuate.

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Study on Extraction of Mucopolysaccharide-protein Containing Chondroitin Sulfate from Chicken Keel Cartilage

  • Shin, S.C.;You, S.J.;An, B.K.;Kang, C.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.4
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    • pp.601-604
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    • 2006
  • The objective of this study was to investigate technical methods for extraction of mucopolysachharide-protein containing chondroitin sulfate from keel cartilage of chickens. The chemical composition of chicken keel cartilage was determined. For the preparation of mucopolysaccharide-protein from lyophilized chicken keel cartilage, hot water extraction and alcalase hydrolysis methods were examined. Results showed that the optimum condition of hot water extraction was incubation for 120 min with a yield of 40.09% and chondroitin sulfate content of 28.46%. For alcalase hydrolysis, the most effective condition was 2% alcalase in 10 volumes of distilled water for 120 min. The yield of hydrolysate was 75.87%, and chondroitin sulfate content was 26.61%. For further separation of chondroitin sulfate from the alcalase hydrolysate, which has a higher yield than that of hot water, 60% ethanol precipitation was performed. The yield of the ethanol precipitate was 21.41% and its chondroitin sulfate content was 46.31%. The hot water extract, alcalase hydrolysate and ethanol precipitate showed similar electrophoretic migration with standard chondroitin sulfate (chondroitin sulfate A), using cellulose acetate membrane electrophoresis. These results indicated that a significant amount of mucopolysaccharide-protein containing chondroitin sulfate could be acquired form chicken keel cartilage. Therefore, keel cartilage in chicken may provide an inexpensive source of chondroitin sulfate for commercial purposes.