• Title/Summary/Keyword: Sudden Temperature Change

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Coil-to-globule transition of thermo-responsive γ-substituted poly (ɛ-caprolactone) in water: A molecular dynamics simulation study

  • Koochaki, Amin;Moghbeli, Mohammad Reza;Nikkhah, Sousa Javan
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1313-1319
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    • 2018
  • The coil-to-globule behavior of poly{${\gamma}$-2-[2-(2methoxyethoxy)ethoxy]ethoxy-3-caprolactone} (PMEEECL) as a ${\gamma}$-substituted poly (${\varepsilon}$-caprolactone) was investigated via atomistic molecular dynamics (MD) simulation. For this purpose, radius of gyration, end-to-end distance and radial distribution function of the chain in the presence of water were calculated. Consequently, the lower critical solution temperature (LCST) of PMEEECL chain at which the coil-to-globule transition takes place, was determined in each calculated parameter curve. The simulation results indicated that the LCST of PMEEECL was occurred at close to 320 K, which is in a good agreement with previous experimental results. Additionally, the appearance of sudden change in both Flory-Huggins interaction parameter (${\chi}$) and interaction energy between the PMEEECL chain and water molecules at about 320 K confirmed the calculated LCST result. The radial distribution function (RDF) results showed that the affinity of the PMEEECL side chain to water molecules is lower than its backbone.

Analysis of Thermal Flow Characteristics according to the Opening Ratio of High-Pressure Valve for Hydrogen Storage Tank (수소 저장 탱크용 고압 밸브의 개도율에 따른 열·유동 특성 분석)

  • JUNG, DA WOON;CHOI, JIN;SUH, HYUN KYU
    • Journal of Hydrogen and New Energy
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    • v.33 no.5
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    • pp.525-533
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    • 2022
  • In this study, in order to numerically analyze the heat flow characteristics in the valve according to the opening rate for the solenoid valve for hydrogen supply applied to the hydrogen storage tank, flow characteristics were comparatively analyzed. Through the analysis of pressure and temperature distributions within the valve according to the high-pressure supply condition of 70 MPa or more, the heat flow characteristics in the valve, inlet and outlet passage according to the opening rate of the valve were identified. As a result a sudden change in the fluid behavior appears in the neck region of the valve, and it is understood that the flow separation caused by the flow path shape of the expanded tube has a dominant influence on the flow characteristics. And, it was confirmed that the shape of the valve seat is a factor significantly affecting the improvement of flow rate and differential pressure performance.

An Experiment on the Optimum Growth Temperature and Wintering Temperature of the Catfish, Clarias batrachus, in the Aquarium (열대산메기, Clarias batrachus의 수조내사육시의 적정사육 수온과 월동수온에 관한 연구)

  • JO Jae-Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.3
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    • pp.197-205
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    • 1984
  • From 1981 to 1982, a series of experiments on the optimum growth temperature, wintering temperature and lethal minimum temperature of the walking catfish Clarias batrachus, of about 12 to 40 g yearlings, were carried out using indoor recirculating aquariums at water temperature between $14^{\circ}C\;and\;34^{\circ}C$. The results are as follows. The optimum temperature of this species was turned out to be approximately $25^{\circ}C$ with highest feed intake and growth rates, and lowest conversion rate than at any other temperatures. The minimum temperature at which the fish can show growth turned out to be $18^{\circ}C$, At this temperature daily growth rate for 62 days was about $0.1\%$ and all fish survived. When this species was kept at $16^{\circ}C$ or lower, no fish survived more than one month and at lower than $14^{\circ}C$ all fish died out in 1 to 7 days. In accordance with these results it could be inferred that $18^{\circ}C$ is the minimum wintering temperature. Rearing this species at the minimum growth temperature for a long time, for wintering for instance, the sudden change of water temperature, especially decreasing to lower than $15^{\circ}C$ can be lethal for all fish.

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Overview of Climate Change and Unusual Regional Climate and the Future (기후변화와 이상기상 발생의 현황과 미래)

  • Moon Sung-Euii
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2000.11a
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    • pp.3-11
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    • 2000
  • The Asian summer monsoon has a profound social and economic impact in East Asia and its surrounding countries. The monsoon is basically a response of the atmosphere to the differential heating between the land mass of the Asian continent and the adjacent oceans. The atmospheric response, however, is quite complicated due to the interactions between the atmospheric heat sources, land-sea contrast, and topography, The occurrence of extreme summertime floods in Korea, Japan, and China in 1998 and 1999 has highlighted the range of variability of the East Asian summertime monsoon circulation and spurred interest in investigating the cause of such extreme variability. While ENSO is often considered a prime mechanism responsible for the unusual hydrological disasters in East Asia, understanding of the connection between ENSO and the East Asian monsoon is hampered by their dynamic complexities. Along with a recent phenomenon of weather abnormalities observed in many parts of the globe, Korea has seen its share of increased weather abnormalities such as the record-breaking heavy rainfalls due to a series of flash floods in the summers of 1998 and 1999, following devastating Yangtze river floods in China. A clear regime shift is found in the tropospheric mean temperature in the northern hemisphere middle latitudes and the surface temperature over the Asian continent during the summer with a sudden warming since 1977. Either decadal climate variation or climate regime shift in the Asian continent is evident and may have altered the characteristics of the East Asian summer monsoon. Considering the summertime rainfall amount in Korea is overall increased lately, the 1998/99 heavy rainfalls may not be isolated episodes related only to ENSO, but could be a part of long-term climate variation. The record-breaking heavy summer rainfalls in Korea may not be direct impact of ENSO. Instead, the effects of decadal climate variation and ENSO may be coupled to each other and also to the East Asian summer monsoon system, while their individual impacts are difficult to separate.

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Physical Environment Changes in the Keum River Estuary Due to Dike Gate Operation: III. Tidal Modulation of Low-salinity Water (하구언 수문 작동으로 인한 금강 하구역의 물리적 환경변화: III. 저염수의 조석동조)

  • Choi, Hyun-Yong;Kwon, Hyo-Keun;Lee, Sang-Ho
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.3
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    • pp.115-125
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    • 2001
  • To examine the movement of the freshwater discharged artificially into the estuary during ebbing period in the Keum River dike we observed surface salinity variations in three stations along the estuary channel in May 1998 and July 1997 and surface temperature and salinity along the ferry-route between Kunsan and Changhang during eighteen days in July 1999. Based upon the typical features of observed salinity variation, we analyzed the excursion and decay processes of the discharged water. When freshwater is discharged, the low-salinity water forms strong salinity front over the entire estuary width, which basically moves forth and back by tidal modulation along the channel, producing the sudden change of surface salinity with the front passage. Salinity distribution along the channel, which is deduced from time variation of mean salinity over the estuary width, after one tidal period from gate operation suggests that diluted low-salinity water is trapped to the front and surface salinity increases gradually toward the upstream region. This frontal distribution of salinity is interpreted to be produced by the sudden gate operation supplying and stopping of freshwater within about two hours. Daily repeat of freshwater discharge produces separation (double front) or merge between decaying and new-generated fronts depending on dike-gate opening time, and the front decays with salinity increasing if the freshwater supply is stopped more than two days. In addition, the observed fluctuations and deviations in surface salinity variation is explained in terms of the differences of fronts intensity, their transition time and temporal salinity front running along the channel, which can be generated due to artificial gate-operation for the discharging time and water volume in the estuary dike.

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A Study on Emission Properties of Green House Gas on Duration Combustion of Constructive Wood Materials (건축용 목재의 연소시 지구온난화 가스의 배출특성에 관한 연구)

  • An, Hyung-Hwan
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.123-128
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    • 2018
  • MDF was treated on the surface of MDF with fire retardant lacquer, water-soluble flame retardant coat and water-soluble wood cover on the MDF wood, and the pyrolysis characteristics and the atmospheric noxious gas generation characteristics were investigated by using the large capacity thermal analyzer. As a result of investigating pyrolysis and combustion gas generation characteristics after treatment of 0.11 / 11.55 g in terms of mass ratio, it was found that combustion starting time was slightly longer than that of pure MDF in the case of treatment with fire retardant lacquer. The combustion temperature was increased from $340^{\circ}C$ to $450^{\circ}C$. The pyrolysis and combustion gas generation characteristics of the MDF wood treated with the aqueous flame retardant coat showed the changes in combustion starting time and temperature from $260^{\circ}C$ to $542^{\circ}C$ for about 26 minutes at the mass ratio of 0.13 / 11g. Also, when the commercially available waterproof wood cover was treated with 0.13 / 11.55 g of MDF, the sudden weight change tended to increase from $300^{\circ}C$ to $370^{\circ}C$ and showed a second change at approximately $500^{\circ}C$.

Heat Transfer Characteristics of CO2 at Supercritical Pressure in a Vertical Circular Tube (수직원형관에서 초임계압 CO2의 열전달 특성)

  • Yoo, Tae-Ho;Bae, Yoon-Yong;Kim, Hwan-Yeol
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.1
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    • pp.23-31
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    • 2011
  • At supercritical pressure, the physical properties of fluid change substantially and the heat transfer at a temperature similar to the critical or pseudo-critical temperature improves considerably; however, the heat transfer may deteriorate due to a sudden increase in the wall temperature at a certain condition of a mass and heat flux. In this study, the heat transfer rates in $CO_2$ flowing vertically upward and downward in a circular tube with a diameter of 4.57 mm under various conditions were calculated by measuring the temperature of the outer wall of the tube. The published heat transfer correlations were analyzed by comparing their prediction values with 7,250 experimental data. By introducing a buoyancy parameter, a heat transfer correlation, which could be applied only to a normal heat transfer regime, was extended such that it can be applied to regime of heat transfer deterioration. The published criteria for heat transfer deterioration were evaluated against the conditions obtained from the experiment in this study.

An Experimental Study of the Turbulent Swirling Flow and Heat Transfer Downstream of an Abrupt Expansion in a Circulat Pipe with Uniform Heat Flux (급확대관내에서 류유선회유동의 열전달에 관한 연구)

  • 권기린;허종철
    • Journal of Ocean Engineering and Technology
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    • v.10 no.3
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    • pp.138-152
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    • 1996
  • Many studies of heat transfer on the swirling flow or unswirled flow in a abrupt pipe expansion are widely carried out. The mechanism is not fully found evidently due to the instabilities of flow in a sudden change of the shape and appearance of turbulent shear layers in a recirculation region and secondary vortex near the corner. The purpose of this study is to obtain data through an experimental study of the swirling flow and heat transfer downstream of an abrupt expansion in a circular pipe with uniform heat flux. Experiments were carried out for the turbulent flow nd heat transfer downstream of an abrupt circular pipe expansion. The uniform heat flux condition was imposed to the downstream of the abrupt expansion by using an electrically heated pipe. Experimental data are presented for local heat transfer rates and local axial velocities in the tube downstream of an abrupt 3:1 & 2:1 expansion. Air was used as the working fluid in the upstream tube, the Reynolds number was varied from 60, 00 to 120, 000 and the swirl number range (based on the swirl chamber geometry, i.e. L/d ratio) in which the experiments were conducted were L/d=0, 8 and 16. Axial velocity increased rapidly at r/R=0.35 in the abrupt concentric expansion turbulent flow through the test tube in unswirled flow. It showed that with increasing axial distance the highest axial velocities move toward the tube wall in the case of the swirling flow abrupt expansion. A uniform wall heat flux boundary condition was employed, which resulted in wall-to-bulk temperatures ranging from 24.deg. C to 71.deg. C. In swirling flow, the wall temperature showed a greater increase at L/d=16 than any other L/d. The bulk temperature showed a minimum value at the pipe inlet, it also exhibited a linear increase with axial distance along the pipe. As swirl intensity increased, the location of peak Nu numbers was observed to shift from 4 to 1 step heights downstream of the expansion. This upstream movement of the maximum Nusselt number was accompanied by an increase in its magnitude from 2.2 to 8.8 times larger than fully developed tube flow values.

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Spatiotemporal Assessment of the Late Marginal Heading Date of Rice using Climate Normal Data in Korea (평년 기후자료를 활용한 국내 벼 안전출수 한계기의 시공간적 변화 평가)

  • Lee, Dongjun;Kim, Junhwan;Kim, Kwang Soo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.4
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    • pp.316-326
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    • 2014
  • Determination of the late marginal heading date (LMHD), which would allow estimation of the late marginal seeding date and the late marginal transplanting date, would help identification of potential double cropping areas and, as a result, establishment of cropping systems. The objective of this study was to determine the LMHD at 51 sites in Korea. For these sites, weather data were obtained from 1971 to 2000 and from 1981 to 2010, which represent past and current normal climate conditions, respectively. To examine crop productivity on the LMHD, climatic yield potential (CYP) was determined to represent the potential yield under a given climate condition. The LMHD was calculated using accumulated temperature for 40 days with threshold values of $760^{\circ}C$, $800^{\circ}C$, $840^{\circ}C$ and $880^{\circ}C$. The value of CYP on a given LMHD was determined using mean temperature and sunshine duration for 40 days from the LMHD. The value of CYP on the LMHD was divided by the maximum value of CYP (CYPmax) in a season to represent the relative yield on the LMHD compared with the potential yield in the season. Our results indicated that the LMHD was delayed at most sites under current normal conditions compared with past conditions. Spatial variation of the LMHD differed by the threshold temperature. Overall, the minimum value of CYP/CYPmax was 81.8% under all of given conditions. In most cases, the value of CYP/CYPmax was >90%, which suggested that yield could be comparable to the potential yield even though heading would have occurred on the LMHD. When the LMHD could be scheduled later without considerable reduction in yield, the late marginal transplanting date could also be delayed accordingly, which would facilitate doublecropping in many areas in Korea. Yield could be affected by sudden change of temperature during a grain filling period. Yet, CYP was calculated using mean temperature and sunshine duration for 40 days after heading. Thus, the value of CYP/CYPmax may not represent actual yield potential due to change of the LMHD, which suggested that further study would be merited to take into account the effect of weather events during grain filling periods on yield using crop growth model and field experiments.

An Experimental Study on the Toluene Control Characteristics of Biofilter Packed with Compost, Peatmoss and GAC (Compost, Peatmoss, GAC의 복합 메디아로 충전된 Biofilter의 Toluene 제어특성에 관한 실험적 연구)

  • Eom, Yun-Sung;Han, Se-Hyun;Jung, Yong-Won
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.3
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    • pp.265-276
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    • 2007
  • The primary objective of this study is to investigate the effect of media on the performance of biofilters. Two types of experiments were carried out in this study. The first type of experiment used a biofilter with the media composed of three different packing materials of compost, peatmoss and GAC(granular activated carbon), whereas the second type used a biofilter with the media composed of compost only. It was found from the two experiments that the biofilter composed of compost, peatmoss and GAC showed better performance than the one composed of compost only with the higher toluene removal efficiency, lower pressure drop, and more uniform media moisture content. In particular, no appreciable media compression occurred for the biofilter composed of compost, peatmoss and GAC, whereas significant media compression took place in the biofilter composed of compost only. As suggested by the other researchers, it is likely that GAC may be responsible for the higher toluene removal efficiency in the case of the biofilter composed of mixed media especially for the early stage of biofiltration due to its adsorption capability of toluene of such high concentration as 300 ppm. It was also regarded that GAC may playa major role in maintaining lower media pressure drop in the case of the mixed media than the media with compost only because of its mechanical strength resisting to the compression. Nonetheless, further refined experiments may need to draw more accurate conclusion. The results of the additional test run using the same mixed media showed that the biofilter system using the mixed media can be consistently operated for more than 100 days very stably despite sudden change in operating conditions of temperature and flow rate.