• Title/Summary/Keyword: Substrate Efficiency

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The Substrate Specificity of Pyranose Oxidase: the Activity of L-Gulono-1 4-lactone Oxidase

  • Kwon, Jae-youl;Kang, Sa-Ouk
    • Proceedings of the Korean Biophysical Society Conference
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    • 1997.07a
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    • pp.37-37
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    • 1997
  • The catalytic efficiency of pyranose oxidase (EC 1.1.3.10.) determined for various sugars showed that D-glucose is the preferred substrate and the enzyme oxidized the various aldonolactones. The specificity constants of pyranose oxidase determined for deoxy- and deoxyfluoro-D-glucoses showed that a hydroxy group at C-4 of D-glucose acts as a hydrogen-bone acceptor, at C-6 as a hydrogen-bond donor, and at C-1 as a hydrogen-bond donor.(omitted)

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Determination optimal ratio of ammonium to nitrite in application of the ANAMMOX process in the mainstream (Mainstream ANAMMOX 공정 적용시 암모니아성 질소 대비 아질산성 질소 비율 도출 연구)

  • Lee, Dawon;Lee, Jiwon;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.23 no.1
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    • pp.60-66
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    • 2021
  • As the concentration of nitrogen in the sewage flowing into the sewage treatment plant increases due to urbanization and industrialization, the degree of adverse effects such as eutrophication and toxicity to the aquatic ecosystem is also increasing. In order to treat sewage containing high concentration of nitrogen, various studies on the biological nitrogen removal process are being conducted. Existing biological nitrogen removal processes require significant costs for supplying oxygen and supplementing external carbon sources. In this respect, as a high-level nitrogen removal process with economic improvement is required, an anaerobic ammonium oxidation process (ANAMMOX), which is more efficient and economical than the existing nitrification and denitrification processes, has been proposed. The purpose of this study is to confirm the stability of the ANAMMOX process in the water treatment process and to derive the ratio of ammonia nitrogen (NH4+) to nitrite nitrogen (NO2-) for the implementation of the mainstream ANAMMOX process. A laboratory-scale Mainstream ANAMMOX reactor was operated by applying the ratio calculated based on the substrate ratio suggested in the previous study. In the initial range, the removal efficiency of NH4+ was 58~86%, and the average removal efficiency was 70%. In the advanced range, the removal efficiency of NH4+ was 94~99%, and the average removal efficiency was 95%. As a result of the study, as the NH4+/NO2- ratio increased, the stability of the mainstream ANAMMOX process was secured, and it was confirmed that the NH4+ removal efficiency and the total nitrogen (TN) removal efficiency increased. As a result, the results of this study are expected to be used as basic data in the application of the ANAMMOX process in the mainstream.

Conformal coating of Al-doped ZnO thin film on micro-column patterned substrate for TCO (TCO 응용을 위한 패턴된 기판위에 증착된 AZO 박막의 특성 연구)

  • Choi, M.K.;Ahn, C.H.;Kong, B.H.;Cho, H.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.28-28
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    • 2009
  • Fabrications of antireflection structures on solar cell were investigated to trap the light and to improve quantum efficiency. Introductions of patterned substrate or textured layer for Si solar cell were performed to prevent reflectance and to increase the path length of incoming light. However, it is difficult to deposit conformally flat electrode on perpendicular plane. ZnO is II-VI compound semiconductor and well-known wide band-gap material. It has similar electrical and optical properties as ITO, but it is nontoxic and stable. In this study, Al-doped ZnO thin films are deposited as transparent electrode by atomic layer deposition method to coat on Si substrate with micro-scale structures. The deposited AZO layer is flatted on horizontal plane as well as perpendicular one with conformal 200 nm thickness. The carrier concentration, mobility and resistivity of deposited AZO thin film on glass substrate were measured $1.4\times10^{20}cm^{-3}$, $93.3cm^2/Vs$, $4.732\times10^{-4}{\Omega}cm$ with high transmittance over 80%. The AZO films were coated with polyimide and performed selective polyimide stripping on head of column by reactive ion etching to measure resistance along columns surface. Current between the micro-columns flows onto the perpendicular plane of deposited AZO film with low resistance.

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Interaction Models of Substrate Peptides and β-Secretase Studied by NMR Spectroscopy and Molecular Dynamics Simulation

  • Lee, Jee-Young;Lee, Sung-Ah;Kim, Jin-Kyoung;Chae, Chi-Bom;Kim, Yangmee
    • Molecules and Cells
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    • v.27 no.6
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    • pp.651-656
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    • 2009
  • The formation of ${\beta}$-amyloid peptide ($A{\beta}$) is initiated from cleavage of amyloid precursor protein (APP) by a family of protease, ${\alpha}$-, ${\beta}$-, and ${\gamma}$-secretase. Sub W, a substrate peptide, consists of 10 amino acids, which are adjacent to the ${\beta}$-cleavage site of wild-type APP, and Sub M is Swedish mutant with double mutations on the left side of the ${\beta}$-cleavage site of APP. Sub W is a normal product of the metabolism of APP in the secretary pathway. Sub M is known to increase the efficiency of ${\beta}$-secretase activity, resulting in a more specific binding model compared to Sub W. Three-dimensional structures of Sub W and Sub M were studied by CD and NMR spectroscopy in water solution. On the basis of these structures, interaction models of ${\beta}$-secretase and substrate peptides were determined by molecular dynamics simulation. Four hydrogen bonds and one water-mediated interaction were formed in the docking models. In particular, the hydrogen bonding network of Sub M-BACE formed spread over the broad region of the active site of ${\beta}$-secretase (P5-P3'), and the side chain of P2- Asn formed a hydrogen bond specifically with the side chain of Arg235. These are more favorable to the cleavage of Sub M by ${\beta}$-secretase than Sub W. The two substrate peptides showed different tendency to bind to ${\beta}$-secretase and this information may useful for drug development to treat and prevent Alzheimer's disease.

Heat Resistant Low Emissivity Oxide Coating on Stainless Steel Metal Surface and Characterization of Emissivity (스테인리스강 금속 표면에 내열 저방사 산화물 코팅제 적용과 방사 특성 평가)

  • Lim, Hyung-Mi;Kwon, Tae-Il;Kim, Dae-Sung;Lee, Sang-Yup;Kang, Dong-Pil;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.649-656
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    • 2009
  • Inorganic oxide colloids dispersed in alcohol were applied to a stainless steel substrate to produce oxide coatings for the purpose of minimizing emissive thermal transfer. The microstructure, roughness, infrared emissive energy, and surface heat loss of the coated substrate were observed with a variation of the nano oxide sol and coating method. It was found that the indium tin oxide, antimony tin oxide, magnesium oxide, silica, titania sol coatings may reduce surface heat loss of the stainless steel at 300${\circ}C$. It was possible to suppress thermal oxidation of the substrate with the oxide sol coatings during an accelerated thermal durability test at 600${\circ}C$. The silica sol coating was most effective to suppress thermal oxidation at 600${\circ}C$, so that it is useful to prevent the increase of radiative surface heat loss as a heating element. Therefore, the inorganic oxide sol coatings may be applied to improve energy efficiency of the substrate as the heating element.

Characterization of EFG Si Solar Cells

  • Park, S.H.
    • Journal of Sensor Science and Technology
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    • v.5 no.5
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    • pp.1-10
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    • 1996
  • Solar cells made of the edge-defined film-fed growth Si are characterized using current-voltage, surface photovoltage, electron beam induced current, electron microprobe, scanning electron microscopy, and electron backscattering. The weak temperature dependence of the I-V curves in the EFG solar cells is due to a voltage variable shunt resistance giving higher diode ideality factors than the ideal one. The voltage variable shunt resistance is modeled by a modified recombination mechanism which includes carrier tunneling to distributed impurity energy states in the band gap within the space-charge region. The junction integrity and the substrate quality are characterized simultaneously by combining I-V and surface photovoltage (SPV) measurements. The diode ideality factors and the surface photovoltages characterize the junction integrity while the SPV diffusion lengths characterizes the substrate quality. Most of the measured samples show the voltage variable shunt resistance although how serious it is depends on the solar cell efficiency. The voltage variable shunt resistance is understood as one of the most important factors of the degradation of EFG solar cells.

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A Study on the Improvement of Light-Extraction Efficiency of Organic Light-Emitting Diodes with a Use of Random-Textured Film (랜덤 택스쳐 필름을 이용한 유기 발광 소자의 광추출 효율 향상에 관한 연구)

  • Kim, Hye Sook;Hwang, Deok Hyeon;Jang, Kyeong Uk;Kim, Tae Wan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.446-449
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    • 2015
  • An improvement of light-extraction efficiency of organic light-emitting diodes was studied by using random-textured films (RTF). Device was made in a structure of RTF/glass/ITO/TPD/$Alq_3$/LiF/Al. RTF mold was made by spreading PDMS solution on a sandpaper. By pressing this mold on the glass substrate pre-coated with ZPU material, the RTF was obtained. From this study, there was an improvement of external quantum efficiency by about 30% in the device with the random-textured film (RTF 40) compared to that of the reference one.

Analysis on the Optical Properties and Fabrication of Textured AZO Thin Films for Increasing the Efficiency of LED (LED 효율 향상을 위한 Texture구조 AZO 박막의 제조와 광학적 특성분석)

  • Kim Kyeong-Min;Jin Eun-Mi;Park Choon-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.901-906
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    • 2006
  • The transparent conductive oxide(TCO) has been used in necessity as front electrode for increasing efficiency of LED. In our paper, aluminium-doped zinc oxide films(AZO), which has transparent conducting were prepared with RF magnetron sputtering system on glass substrate(corning 1737) and annealed at $400^{\circ}C$ for 2 hr in vacuum ambient and $600^{\circ}C$ for 2hr with $O_2$ ambient respectively. The smooth AZO films were etched in diluted HCL(0.5 %) to examine the surface properties, which in ambient post-annealing process. We confirmed that the electric, structural and optical properties of textured AZO thin films, which implemented using the methods of XRD, FWHM, AFM and Hall measurement. The properties of textured AZO thin films especially depended on the ambient post-annealing process. We presumed that the change of transmittances as R G B LED and the ambient post-annealing process will be increasing the efficiency of LED.

A Study on an Aerobic Fluidized-Bed Biofilm Reactor for Treating Industrial Wastewaters(II) -Effect of Organic Shock Loading Rate on Biomass Characteristics- (산업폐수처리를 위한 호기성 생물막 유동층 반응기의 연구(II) -유기물 충격 부하가 미생물 성장에 미치는 영향-)

  • 안갑환;박영식;최윤찬;김동석;송승구
    • Journal of Environmental Science International
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    • v.2 no.4
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    • pp.325-330
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    • 1993
  • A number of experiments were conducted in order to investigate the organic removal efficiency and biomass characteristics according to the organic shock loading rate in a fluidized bed biofilm reactor. At the operation conditions of HRT, 8.44 hour, superficial upflow velocity, 0.9 cm/sec and temperature, 22$\pm$$1^{\circ}C$, the removal efficiency of SCOD was founded to be 96.5, 92 and 90 % with the organic shock loading rate of 3.5, 10.8 and 33 kgCOD/m$^3$ㆍday, respectively. Within the F/M ratio ranged 0.4 to 2.0 kgCOD/kgVSSㆍday, the SCOD removal efficiency was shown as 90% at F/M ratio of 2.0 kgCOD/kgVSSㆍday, but the TCOD removal efficiency was 72 % at F/M ratio of 1.8 kgCOD/kgVSSㆍday. The average biomass concentrations were 7800, 14950 and 27532 mg/l on the organic shock loading rate of 3.5, 10.8 and 33 kgCOD/$\textrm{m}^3$ㆍday, respectively. This result was agreed with the fact that more biomass could be produced at high concentration of substrate, but some biomass was detached at the onset of shock and easily acclimated at the shock condition.

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Study on Behavior of Organic, Nitrogen, and Phosphorus in the Sequencing Batch Reactor (연속회분식 반응기(Sequencing Batch Reactor)에서 유기물, 질소 및 인의 거동에 관한 연구)

  • 한기백;박동근
    • Journal of Environmental Science International
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    • v.6 no.5
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    • pp.521-529
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    • 1997
  • In the study, we Investigated the behavior and removal efficiency of organics, nitrogen. phosphorus with operating conditions in SBRs. Substrate used was synthetic wastewater in which the ratio of $COD_{cr}$. : N : P was 100 : 12 : 2. The cycling the in SBRs was adjusted at 6 hours and 8 hours, and then certainly Included anaerobic and aerobic conditions. Also, for each cycling time. we performed 2 series of experiment simultaneously which was set up 10 days and 20 days as SRT. The removal efficiency of $COD_{cr}$. was over 97% in all operating conditions. In the 6 hours cycling time, the removal efficiency of $PO_4^{3-}-P$ reached almost 100% in steady state. And then we could observe a typical phonemena of phosphorus release and uptake, and the removal efficiency of N was 67%, Residual N source was almost TKN and most of the rest remained as $NO_2-N$. Also the difference in both SRTs was not observed practically. In the 8 hours cycling time, dissolution of sludge appeared. and, $PO_4^{3-}-P was not nearly removed but nitrogen was removed up to 75%, And the residual nitrogen was accumulated as $NO_2^--N$.

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