• Title/Summary/Keyword: Substitution Ratio

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Alkylation and Allylation of Lithium Arylborates Factors Affecting the Di/Mono Substitution Ratio$^\dag$

  • Lee, Ho-Seong;Song, Yang-Sup;Lee, Dong-Doo
    • Bulletin of the Korean Chemical Society
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    • v.8 no.5
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    • pp.424-425
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    • 1987
  • Alkylation and allylation of arylborates give mono(ipso) and/or di(ortho and ipso) substitution products. Those factors which promote polarization or ionization of alkylating agents favor di substitution. The ${\sigma}$-type(ipso) substitution reaction of arylborates involves direct interaction of the carbon-boron bonds rather than predissociation of arylborates into aryllithiums and boranes.

An Experimental Study on the Recycled! Concrete Durability (재생 콘크리트의 내구성에 관한 실험적 연구)

  • 이명규;정상화;김인수
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.675-680
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    • 2003
  • In this study, various tests are performed for the durability of the concrete using domestic recycled coarse aggregate including drying shrinkage, permeability, freezing-thawing resistance and $CO_2$ diffusivity. Tests of freezing-thawing resistance, chloride ion permeability and $CO_2$ diffusivity of recycled concrete show favorable results. But, the maximum drying shrinkage ratio to normal concrete is increased 24% with increasing substitution ratio of recycled aggregate. Therefore, for the use of recycled concrete in structures, the preventive measures of drying shrinkage is necessary in mix design and the adequate substitution ratio of recycled aggregate should be proposed.

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A Fundamental Study on the Characteristics of Concrete with the Substitution Ratio of the Rapidly Cooled Steel Slag (급냉제강슬래그의 대체율에 따른 콘크리트의 특성에 관한 기초적 연구)

  • Kim, Nam-Wook;Bae, Ju-Seong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.1 s.53
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    • pp.78-87
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    • 2009
  • When the steel slag is utilized to the concrete as the alternative fine aggregate, its use is limited as the concrete aggregate because of expansibility caused by much quantity of free CaO. So, this study is intended to examine the characteristics of the concrete which uses the rapidly cooled steel slag whose content of free CaO is sharply reduced by rapidly cooling the steel slag as the fine aggregate. Accordingly, by comparing and considering the results of the concrete slump loss test with the different substitution ratio and fine aggregate ratio of rapidly cooled steel slag, hydration by XRD and SEM analysis, compressive test by age, a length variation test and rapid chloride ion penetration test, the rapidly cooled steel slag's proper substitution ratio and the fine aggregate ratio was derived.

A Study on Chloride Diffusion in Concrete Containing Lightweight Aggregate Using Crushed Stone-powder (폐석분을 활용한 경량골재 콘크리트의 염화물 확산에 관한 연구)

  • Lee, Dae-Hyuk;Jee, NamYong;Kim, Jae-Hun;Jeong, Yong;Shin, Jae-Kyung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.127-131
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    • 2009
  • The purpose of this study is to provide fundamental data on chloride diffusion from lightweight aggregate concrete by utilizing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated after experiment based on NT BUILD 492. Diffusion coefficient of SLG and CLG were little bit higher than CG Concrete, but the difference is meaningless. Also, chloride diffusion coefficient indicates that it is highly affected by water-binder ratio, and it decreases with the decrease in water-binder ratio. The admixture substitution indicates decrease only with water-binder ratio of 0.4 for FA15% case, but admixture substitution indicates decrease with all levels of ratio for FA10 + BFS20% which means more appropriate. According to the analysis result of chloride diffusion from lightweight aggregate concrete, crushed stone-powder utilized lightweight aggregate concrete indicates higher chloride diffusion coefficient than CG concrete, which is not a significant difference, and can improve resistance through water-binder ratio and admixture substitution.

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Concrete physical properties with substitution ratio of recycled Coarse aggregate and recycled fine aggregate (순환굵은골재와 순환잔골재 치환율에 따른 콘크리트의 물리적 특성에 관한 연구)

  • Yoon, Seung-Joe;Seo, Soo-Yeon;Lee, Woo-Jin;Kim, Dae-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.161-164
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    • 2006
  • The main objective of this study was to evaluated the physical properties of concrete with substitution ratio of recycled fine aggregate and recycled coarse aggregate made of waste concrete. The replacement ratios of recycled coarse and fine aggregate decided 0%, 30%, 40% and 50% respectively to get the deregulate of floor space Index. The test result showed that compression strength of cylinder mold decrease with the substitution ratio increase but its strength of replaced recycled fine aggregate higher than OPC.

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Histological Effects of Fishery By-product Fermented Fishmeal on the Liver and Muscle of the Olive Flounder Paralichthys olivaceus (수산부산물 발효어분이 넙치(Paralichthys olivaceu)의 간 및 근육에 미치는 영향에 관한 조직학적 연구)

  • Lee, Bo-Ram;Kim, Ji-Hye
    • Journal of Life Science
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    • v.29 no.11
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    • pp.1235-1240
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    • 2019
  • The aim of this study was to clarify histologically the effects of fermented fishmeal on the growth rate of fish. For this purpose, olive flounders were fed on fermented fishmeal at the substitution ratios of 0, 25, 50, 75, and 100%, and the effects on the liver and muscle were examined by microscopy. The olive flounder fed on fermented fishmeal at the 25% substitution ratio had the best hepatic condition, as indicated by the highest hepatosomatic index and the lowest fatty liver level, when compared with fish fed the other substitution ratios. The olive flounder fed on fermented fishmeal at the 25% substitution ratio had good motility, based on the presence of wide myocytes. The high growth rate in the olive flounder fed on fermented fishmeal at the 25% substitution ratio therefore seemed to be related to the health status of the liver and muscles. Higher amounts of the fermented fishmeal (75% and 100% substitution ratios) suppressed the growth rate due to adverse effects on hepatic function and motility of the olive flounder.

The Analysis of Manufactured Cellulose Acetate Using Old Newsprint by Acetosolv Pulping (초산펄프화법에 의해 신문고지로부터 제조된 셀룰로오스 아세데이트의 분석)

  • 임부국;이종윤;양재경;장준복
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.41-47
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    • 2003
  • Recently, interest in utilization plan of recycling paper have been enhanced. Therefore, this research aimed to develop the manufacture process of cellulose acetate using old newsprint by acetosolv pulping process. And the manufactured cellulose acetate was also analyzed, especially based on chemical properties. The summarized results in this research were as follows; Reaction time, kind and amount of catalyst, and ratio of liquor to material were varied during acetosolv pulping process of old newsprint. Ratio of liquor to material did not give the significant difference in reaction product. Delignification rate was increased with increasing reaction time during acetosolv pulping, but yield and degree of substitution decreased with increasing reaction time. Sulfuric acid are better catalyst than hydrochloric acid in acetosolv pulping process for old newsprint, and optimal addition amount of catalyst was 1% based on reaction material. Delignification, yield, and degree of substitution were influenced by the catalyst and reaction time. Under pulping condition of $120^{\circ}C$ in 1/12 liquor to material ratio and 60min, degree of substitution was about 0.7. The acetylation reaction was not completely caused by these reaction condition. The examination of the FT-IR spectra revealed that absorption band(1200$\textrm{cm}^{-2}$, 1,750$\textrm{cm}^{-1}$) caused by carbonyl group were confirmed.

An Experimental Study on the Strength and Behavior of Reinforced Concrete Columns Containing Shells Substituted a Fine Aggregate (패각류를 잔골재 대체재로 사용한 철근콘크리트 기둥의 내력 및 거동에 관한 실험적 연구)

  • Koo, Hae-Shik
    • KIEAE Journal
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    • v.8 no.3
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    • pp.69-76
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    • 2008
  • This is an experimental study on the maximum load value and structural behavior of reinforced concrete columns containing shells as a substitute fine aggregate of concrete, through making reinforced concrete test columns with shells. In this study, the main factors consist of the grain sizes and the percentage of substitution of shells to fine aggregate in two kinds of water cement ratio. The results of the study showed as followed. The maximum load value decreased with increased the rate of substitution about shells and as the grain size of shells became smaller, the load values of them were somewhat changed higher but it is important that we must consider absorption rate of shells sufficiently. If we have a proper water cement ratio in column productions containing the shells, we can meet the requirement of the percentage of substitution until 30%. The deflection and deformation properties of reinforced concrete columns with shells represented typical curves like that of normal reinforced concrete. But as the failture types, they are able to make some change without being out of the fundamental graph forms. After the analyzing structural behaviors and the properties of reinforced concrete test columns containing shells, the most excellent grain size of shells represented 3.0mm and less with taking uniformly, and the percentage of practicable substitution of them to fine aggregate was about 30%.

An Experimental Study on the Properties of the High Strength Crushed Sand Concrete Using Blast-Furnace Slag (고로슬래그를 사용한 고강도 부순모래 경화콘크리트의 물성에 관한 실험적 연구)

  • Choi, Young-Wha;Kim, Jong-In
    • Journal of the Korean Society of Industry Convergence
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    • v.8 no.3
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    • pp.169-176
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    • 2005
  • The purpose of this study is to develop the high strength crushed sand concrete in conditions of water binder ratios of 25, 30, 35% and blast-furnace slag substitutions of 0, 15, 30, 45%. Additionally, in case of water binder ratio of 30%, the maximum size of coarse aggregate is two kinds of 13, 19 mm. The conclusions of this study are as follows ; 1. The compressive strength appeared lower in early age as compared with that of plain concrete according to increasing of the blast-furnace slag substitution. But, the compressive strength was respectively 5, 6, 10% larger than that of plain concrete in case of 25, 30, 35% water binder ratios, 28 days, 30% blast-furnace slag substitution and 19mm coarse aggregate. 2. According to increasing of the blast-furnace slag substitution, the modulus of elasticity and the tensile strength of concrete increased. 3. The length change by the shrinkage increased when the larger coarse aggregate was used, and decreased according to higher blast-furnace slag substitution.

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Comparison among methods of effective energy evaluation of corn silage for beef cattle

  • Wei, Ming;Chen, Zhiqiang;Wei, Shengjuan;Geng, Guangduo;Yan, Peishi
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.6
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    • pp.851-858
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    • 2018
  • Objective: This study was conducted to compare different methods on effective energy evaluation of corn silage for beef cattle. Methods: Twenty Wandong bulls (Chinese indigenous yellow cattle) with initial body weight of $281{\pm}15.6kg$, were assigned to 1 of 5 dietary treatments with 4 animals per treatment in a randomized complete block design. Five dietary treatments included group 1 with corn silage only diet, group 2 with corn silage-concentrate basal diet (BD) and 3 groups with 3 test diets, which were the BD partly substituted by corn silage at 10%, 30%, and 60%. The total collection digestion trial was conducted for 5 d for each block after a 10-d adaptation period, and then an open-circuit respiratory cage was used to measure the gas exchange of each animal in a consecutive 4-d period. Results: The direct method-derived metabolizable energy and net energy of corn silage were 8.86 and 5.15 MJ/kg dry matter (DM), expressed as net energy requirement for maintenance and gain were 5.28 and 2.90 MJ/kg DM, respectively; the corresponding regression method-derived estimates were 8.96, 5.34, 5.37, and 2.98 MJ/kg DM, respectively. The direct method-derived estimates were not different (p>0.05) from those obtained using the regression method. Using substitution method, the nutrient apparent digestibility and effective energy values of corn silage varied with the increased corn silage substitution ratio (p<0.05). In addition, the corn silage estimates at the substitution ratio of 30% were similar to those estimated by direct and regression methods. Conclusion: In determining the energy value of corn silage using substitution method, there was a discrepancy between different substitution ratios, and the substitution ratio of 30% was more appropriate than 10% or 60% in the current study. The regression method based on multiple point substitution was more appropriate than single point substitution on energy evaluation of feedstuffs for beef cattle.