• Transactions on Electrical and Electronic Materials
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• 제12권1호
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• pp.32-34
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• 2011

A zero-shrinkage sintering process in which the shrinkage of the x-y axis is controlled to be zero is in great demand due to the high integration trend in ceramic modules. Among the zero-shrinkage sintering processes available, the glass infiltration method proposed in the preliminary study with an $Al_2O_3/Glass/Al_2O_3$ structure is one promising method. However, problems exist in regard to the glass infiltration method, including partially incomplete joining between $Al_2O_3$ and glass layers due to the precipitate of Ti-Pb rich phase during the sintering process. Therefore, we wish to solve the de-lamination problems and suggest a mechanism for delamination and the solutions in the zero-shrinkage low temperature co-fired ceramic (LTCC) layers. The de-lamination problems diminished using the Pb-BSi-O glass without $TiO_2$ in Pb-B-Ti-Si-O glass and produced a very dense zero-shrinkage LTCC.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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• pp.203-204
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• 2016

In this research, it used cement power and reduction slag, which generates high hydration heat in hydration reation without heat cure below -5℃ degree. Purpose of final research is preventing freezing and thawing by making the compressive strength 5MPa in 3days below zero temperature due to own heat of concrete. and it is the result of physical characteristic and thermal property evaluation of reduction slag. Because reduction sag generates high hydration heat, compressive strength development is excellent. By generating highly Hydration heat by C₁₂A₇ and C₃A in reduction slag, compressive strength is developed in low temperature. In case of displacing only reduction slag without SO₃, it is indicated that quick-setting occurs by shortage of SO₃. For preventing quick-setting, gypsum is used essentially. According to this research result, in case of using reduction slag and gypsum as a ternary system, Compressive strength developed 5MPa in 3days below zero temperature. It is identified to prevent early frost damage of concrete below zero temperature.

• 한국해양공학회지
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• 제28권4호
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• pp.306-313
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• 2014

Super duplex stainless steels (sDSS) are excellent for use under severely corrosive conditions such as offshore and marine applications like pipelines and flanges. sDSS has better mechanical properties and corrosion resistance than the standard duplex stainless steel (DSS) but it is easier for a sigma phase to appear, which depresses the mechanical property and corrosion resistance, compared to DSS, because sDSS has a higher alloy element than DSS. In addition, sDSS has a feeble ductile-brittle transition temperature (DBTT) because it has a 50% ferrite microstructure. In the actual operating environment, sDSS would be thermally affected by welding and a sub-zero temperature environment. This study analyzed how precipitated sDSS behaves at a sub-zero temperature through annealing heat treatment and a sub-zero tensile test. Six types of specimens with annealing times of up to 60 min were tested in a sub-zero chamber. According to the experimental results, an increase in the annealing time reduced the elongation of sDSS, and a decrease in the tensile test temperature raises the flow stress and tensile stress. In particular, the elongation of specimens annealed for 15 min and 30 min was clearly lowered with a decrease in the tensile test temperature because of the increasing sigma phase fraction ratio.

• International Journal of Naval Architecture and Ocean Engineering
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• 제10권6호
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• pp.670-682
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• 2018

This paper presents the experimental and numerical investigation results of the response of low-temperature steel (LT-FH32 grade steel) beams under repeated impacts at room temperature and a single impact at a sub-zero temperature. After conducting tensile tests at room and sub-zero, repeated impact tests were conducted on two clamped single-beam models at room temperature, and single-impact tests of two other clamped single-beam models were conducted at $-50^{\circ}C$. The single and repeated impact tests were conducted by releasing a knife-edge striker using a drop testing machine. The permanent deflection of the model measured after each impact gradually increased with increasing number of impacts. Under the reduced temperature, the permanent deflection of the models slightly decreased. The numerical analyses were also performed to predict the damage response of the tested single-beam models. A comparison of the numerical prediction with those of experiments showed quite reasonable agreement.

• 한국지반환경공학회 논문집
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• 제19권3호
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• pp.5-13
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• 2018

최근 해빙기에 발생하는 지반붕괴로 인한 건설재해가 증가하고 있으며 이는 동절기에 시행되는 다짐시공과 관련이 많다. 영하온도에서 다짐을 실시할 경우 다짐효과가 감소하며 이에 따른 해빙기 지반의 거동 변화를 파악하는 것은 유용한 자료로 활용될 수 있을 것으로 판단된다. 또한 최근 국내 지반공학 분야에서 불포화 영역에 대한 관심이 높아지고 있는 만큼 지반재료의 영하온도 다짐 및 동결융해에 따른 불포화 특성을 파악한다면 앞으로 관련 분야의 연구자들에게도 좋은 정보를 제공할 수 있을 것으로 판단된다. 따라서 본 연구에서는 동절기 다짐에 따른 지반의 불포화 특성을 파악하기 위해 상온($18^{\circ}C$)과 영하온도($-3^{\circ}C$, $-8^{\circ}C$)에서 수행한 다짐시험의 결과를 바탕으로 성형한 시료에 불포화 함수특성시험과 불포화 일축압축시험을 수행하였으며, 시료에 동결융해를 반복적으로 가한 후 불포화 함수특성시험 및 일축압축시험을 수행하여 동결융해가 작용함에 따른 지반의 흡수력 및 불포화 특성의 변화를 파악하였다. 시험결과 영하온도에서의 다짐 및 동결융해에 의한 흡수력의 변화와 강도 및 강성의 감소를 확인하였다. 특히 풍화토의 경우 영하온도에서의 다짐과 동결융해가 진행될수록 강도와 흡수력이 상당히 감소하는 것으로 나타나 지반의 안정성에 상당한 영향을 미칠 것으로 판단된다.

• 한국세라믹학회지
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• 제40권5호
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• pp.455-459
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• 2003

LPE(Liquid Phase Epitaxial)법을 이용하여 성장시킨 B $i_2$S $r_2$Ca(C $u_{1-x}$ N $i_{x}$ )$_2$ $O_{8+}$$\delta$/ 막(film)을 break junction 법을 이용하여 터널링 분광을 측정하였다. Ni 조성비 $\chi$$_{L}$의 증가에 따라 에너지 간격 2$\Delta$의 크기는 증가하였다. 에너지 간격 2$\Delta$(4.2 K)는 54.4~64 meV, 2$\Delta$/ $k_{B}$ $T_{c}$ $^{zero}$는 7.36~10.14로 BCS 이론에 의한 값 보다 큰 결과를 얻었다. 융액(melting solution) 속의 Ni 조성비 $\chi$$_{L}$의 증가에 따라, 임계온도 $T_{c}$ $^{zero}$와 격자상수 c-축의 길이는 감소하는 경향을 보였다.을 보였다.$^{zero}$와 격자상수 c-축의 길이는 감소하는 경향을 보였다.

• 한국재료학회지
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• 제23권6호
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• pp.329-333
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• 2013

The structural phase transformations of $0.7Pb(Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) were studied using high resolution x-ray diffraction (HRXRD) as a function of temperature and electric field. A phase transformational sequence of cubic (C)${\rightarrow}$tetragonal (T)${\rightarrow}$rhombohedral (R) phase was observed in zero-field-cooled conditions; and a $C{\rightarrow}T{\rightarrow}$monoclinic $(M_C){\rightarrow}$ monoclinic ($M_A$) phase was observed in the field-cooled conditions. The transformation of T to $M_A$ phase was realized through an intermediate $M_C$ phase. The results also represent conclusive and direct evidence of a $M_C$ to $M_A$ phase transformation in field-cooled conditions. Beginning from the zero-field-cooled condition, a $R{\rightarrow}M_A{\rightarrow}M_C{\rightarrow}T$ phase transformational sequence was found with an increasing electric field at a fixed temperature. Upon removal of the field, the $M_A$ phase was stable at room temperature. With increasing the field, the transformation temperature from T to $M_C$ and from $M_C$ to $M_A$ phase decreased, and the phase stability ranges of both T and $M_C$ phases increased. Upon removal of the field, the phase transformation from R to $M_A$ phase was irreversible, but from $M_A$ to $M_C$ was reversible, which means that $M_A$ is the dominant phase under the electric field. In the M phase region, the results confirmed that lattice parameters and tilt angles were weakly temperature dependent over the range of investigated temperatures.

• 한국지반환경공학회 논문집
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• 제16권8호
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• pp.13-20
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• 2015

인구가 증가하고 자원이 고갈되면서 새로운 자원개발을 위한 대안으로 극한지 개발이 떠오르고 있다. 전 세계 육지 면적 중 14%가 극한지 지역에 해당되며, 이 지역들의 개발을 위한 해외극지 건설시장이 많이 확대되었다. 이미 선진국들은 극한지 연구의 필요성을 인식하고 기술 개발에 많은 투자를 하고 있는 반면, 우리나라의 경우 극한지 개발을 위한 기술이 선진국에 비해 매우 낮으며 관련 연구 또한 미약한 실정이다. 국내의 동절기 시공의 경우 지반동결에 의한 강도 및 변형특성에 대한 명확한 기준이 마련되어있지 않으며 현장에서의 간단한 지침을 통해서만 관리되고 있다. 따라서 본 연구에서는 상온($18^{\circ}C$), $-3^{\circ}C$, $-8^{\circ}C$에서 세립분 함량을 0%, 5%, 10%, 15%로 변화하면서 D 다짐 시험을 실시하여 영하온도에서의 다짐특성에 대해 살펴보았으며, 기존의 문헌연구와 비교를 통해 영하온도에서의 다짐에너지에 따른 다짐 효과에 대해 평가하였다. 시험 결과 영하온도에서 다짐에너지가 클수록 최대건조단위중량은 증가하는 것으로 나타났으며, $-3^{\circ}C$에서의 D다짐 시험결과는 상온의 결과와 크게 다르지 않으나 $-8^{\circ}C$ 이하에서의 다짐시공 시 다짐성능의 저하가 상당한 것으로 나타났다.

• Transactions on Electrical and Electronic Materials
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• 제16권3호
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• pp.112-116
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• 2015

This work studied the thickness and contact angle of solder joints between SAC 305 lead-free solder alloy and a Copper (Cu) substrate. Intermetallic compound (IMC) thickness and contact angle of 3Sn-Ag-0.5Cu (SAC 305) leadfree solder were measured using varying aging times, at a fixed temperature at 30℃. The thickness of IMC and contact angle depend on the aging time. IMC thickness increases as the aging increases. The contact angle gradually decreased from 39.49° to 27.59° as aging time increased from zero to 24 hours for big solder sample. Meanwhile, for small solder sample, the contact angle increased from 32.00° to 40.53° from zero to 24 hours. The IMC thickness sharply increased from 0.007 mm to 0.011 mm from zero to 24 hours aging time for big solder. In spite of that, for small solder the IMC thickness gradually increased from 0.009 mm to 0.017 mm. XRD analysis was used to confirm the intermetallic formation inside the sample. Cu₆Sn₅, Cu₃Sn, Ni₃Sn and Ni₃Sn₂ IMC layers were formed between the solder and the copper substrate. As the aging time increased, the strength of the solder joint mproved due to reduced contact angle.

• 한국재료학회지
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• 제32권2호
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• pp.66-71
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• 2022

In this article, Pb₂Ba_1.7Sr_0.3Ca₂Cu₃O_10+δ superconductor material was synthesized using conventional solid-state reaction method. X-ray diffraction (XRD) analysis demonstrated one dominant phase 2223 and some impurities in the product powder. The strongest peaks in the XRD pattern were successfully indexed assuming a pseudo-tetragonal cell with lattice constants of a = 3.732, b = 3.733 and c = 14.75 Å for a Pb-Based compound. The crystallite size and lattice strain between the layers of the studied compound were estimated using several methods, namely the Scherrer, Williamson-Hall (W.H), size-strain plot (SSP) and Halder Wagner (H.W) approach. The values of crystallite size, calculated by Scherrer, W.H, SSP and H.W methods, were 89.4540774, 86.658638, 87.7555823 and 85.470086 Å, respectively. Moreover, the lattice strain values obtained by W.H, SSP and H.W methods were 0.0063240, 0.006325 and 0.006, respectively. It was noted that all crystallite size results are consistent; however, the best method is the size-strain plot because it gave a value of R² approaching one. Furthermore, degree of crystallites was calculated and found to be 59.003321%. Resistivity analysis suggests zero-resistance, which is typical of superconducting materials at critical temperature. Four-probe technique was utilized to measure the critical temperature at onset T_c(onset), zero resistivity T_{c(off set)}, and transition (width ΔT), corresponding to temperatures of 128 K, 116 K, and 12 K, respectively.