• Title/Summary/Keyword: Sub-gradient method

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The Electronic Structures and Magnetism of Monolayer Fe on CuGaSe2(001)

  • Jin, Ying-Jiu;Lee, Jae-Il
    • Journal of Magnetics
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    • v.12 no.2
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    • pp.59-63
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    • 2007
  • Ferromagnet/Semiconductor heterostructures have attracted much attention because of their potential applications in spintronic devices. We investigated the electronic structures and magnetism of monolayer Fe on $CuGaSe_2(001)$ by using the all-electron full-potential linearized augmented plane-wave method within a generalized gradient approximation. We considered the monolayer Fe deposited on both the CuGa atoms terminated (CuGa-Term) and the Se atom terminated (Se-Term) surfaces of $CuGaSe_2(001)$. The calculated magnetic moment of the Fe atom on the CuGa-Term was about $2.90\;{{\mu}_B}$. Those of the Fe atoms on the Se-Term were in the range of $2.85-2.98\;{{\mu}_B}$. The different magnetic behaviors of the Fe atoms on two different surfaces were discussed using the calculated layer-projected density of states.

Monitoring of Veterinary Antibiotics in Agricultural Soils using Liquid Chromatography Coupled with Tandem Mass Spectrometry (LC-MS/MS를 이용한 농경지 토양 중 항생제 모니터링)

  • Lee, Young-Jun;Choi, Jeong-Heui;Chung, Hyung Suk;Lee, Han Sol;Park, Byung-Jun;Kim, Jang-Eok;Shim, Jae-Han
    • Korean Journal of Environmental Agriculture
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    • v.35 no.3
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    • pp.166-174
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    • 2016
  • BACKGROUND: The current study developed a monitoring method of 6 veterinary antibiotics (amoxicillin, ampicillin, enrofloxacin, tetracycline, chlortetracycline, oxytetracycline) in agricultural soils using liquid chromatography-tandem mass spectrometry (LC-MS/MS) in positive electrospray ionization mode.METHODS AND RESULTS: Sample preparation was carried out using acidic acetonitrile and citrate salts followed by purification with dispersive solid phase extraction (d-SPE). Separation on Eclipse Plus C18 column was conducted in gradient of the mobile phase, 0.1% formic acid and 5 mM ammonium formate in methanol (A) and 0.1% formic acid and 5 mM ammonium formate in distilled water (B). The linearity of the matrix-matched calibrations expressed as the coefficient of determination was good with R2≥0.9900. The limit of quantifications (LOQs) ranged from 0.5 to 10 μg/kg for all analytes. Analysis of 51 agricultural soil samples taken in the Republic of Korea revealed concentrations less than 1.9 μg/kg for enrofloxacin, 75.5 μg/kg for chlortetracycline.CONCLUSION: The method was successfully applied to monitor 6 veterinary antibiotics from 51 field incurred agricultural soil samples in 17 provincial areas throughout the Republic of Korea. The developed method was simple, easy, and versatile and can be used for monitoring various veterinary antibiotics in soil.

Estimation of Flood Discharge Based on Observation Data Considering the Hydrological Characteristics of the Han Stream Basin in Jeju Island (한천유역의 수문학적 특성을 고려한 관측자료 기반 홍수량 산정)

  • Yang, Sung-Kee;Kim, Min-Chul;Kang, Bo-Seong;Kim, Yong-Seok;Kang, Myung-Soo
    • Journal of Environmental Science International
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    • v.26 no.12
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    • pp.1321-1331
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    • 2017
  • This study reviewed the applicability of the existing flood discharge calculation method on Jeju Island Han Stream and compared this method with observation results by improving the mediating variables for the Han Stream. The results were as follows. First, when the rain-discharge status of the Han Stream was analyzed using the flood discharge calculation method of the existing design (2012), the result was smaller than the observed flood discharge and the flood hydrograph differed. The result of the flood discharge calculation corrected for the curve number based on the terrain gradient showed an improvement of 1.47 - 6.47% from the existing flood discharge, and flood discharge was improved by 4.39 - 16.67% after applying the new reached time. In addition, the sub-basin was set separately to calculate the flood discharge, which yielded an improvement of 9.92 - 32.96% from the existing method. In particular, the steepness and rainfall-discharge characteristics of Han Stream were considered in the reaching time, and the sub-basin was separated to calculate the flood discharge, which resulted in an error rate of -8.77 to 8.71%, showing a large improvement of 7.31 - 28.79% from the existing method. The flood hydrograph also showed a similar tendency.

Microstructure and Electrical Properties of (YNdSm)-Ba-Cu-O High Tc Composite Superconductors by Zone Melting Process (존멜팅법으로 제조한 (YNdSm)-Ba-Cu-O계 고온복합초전도체의 미세구조 및 전기적 특성)

  • Kim, So-Jung;Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.2
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    • pp.110-113
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    • 2016
  • (YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of $(YNdSm)_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting $(YNdSm)_2BaCuO_5$ inclusions of the melt-textured (YNS)1.8 sample with $CeO_2$ additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without $CeO_2$ additive, showed an onset $T_c{\geq}90K$ and sharp superconducting transition. The critical current density $J_c$ value of the (YNdSm)1.8 superconductor with $CeO_2$ additive were 840 A, $1.2{\times}104A/cm^2$ in 77 K, 0 Tesla by direct current transport method.

Quantitative Determination of the Six Marker Compounds in Eucommiae Cortex by Processing Method (포제에 따른 두충의 지표성분 함량분석)

  • Seo, Chang-Seob;Kim, Jung-Hoon;Shin, Hyeun-Kyoo;Kim, Byoung-Soo
    • Korean Journal of Pharmacognosy
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    • v.46 no.2
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    • pp.123-132
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    • 2015
  • In this study, we carried out quantification analysis of the six marker components, geniposidic acid, chlorogenic acid, geniposide, pinoresinol diglucoside, liriodendrin, and genipin in the 70% ethanol extracts of non-processed Eucommiae Cortex and processed Eucommiae Cortex using a high-performance liquid chromatography coupled with photodiode array detector. The six components were separated on Gemini C18 column (5 μm, 4.6×250 mm) by the gradient elution with 1.0% (v/v) acetic acid in water and 1.0% (v/v) acetic acid in acetonitrile as mobile phase. The flow rate was 1.0 mL/min and the injection volume was 10 mL. The amount of geniposidic acid, chlorogenic acid, geniposide, pinoresinol diglucoside, liriodendrin, and genipin in non-processed Eucommiae Cortex were 1.31, 0.31, 0.66, 0.46, 0.46, and 0.03%, respectively, while the amount of the six compounds in non-processed Eucommiae Cortex were 0.04-0.78, 0.01-0.14%, 0.05-0.63%, 0.01-0.37%, 0.15-0.42%, and not detected, respectively. After processing treatment, the contents of three iridoids, two lingnan, and one phenylpropanoid decreased in Eucommiae Cortex.

Analysis of Land Cover Characteristics with Object-Based Classification Method - Focusing on the DMZ in Inje-gun, Gangwon-do - (객체기반 분류기법을 이용한 토지피복 특성분석 - 강원도 인제군의 DMZ지역 일원을 대상으로 -)

  • Na, Hyun-Sup;Lee, Jung-Soo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.2
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    • pp.121-135
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    • 2014
  • Object-based classification methods provide a valid alternative to traditional pixel-based methods. This study reports the results of an object-based classification to examine land cover in the demilitarized zones(DMZs) of Inje-gun. We used land cover classes(7 classes for main category and 13 classes for sub-category) selected from the criteria by Korea Ministry of Environment. The average and standard deviation of the spectrum values, and homogeneity of GLCM were chosen to map land cover types in an hierarchical approach using the nearest neighborhood method. We then identified the distributional characteristics of land cover by considering 3 topographic characteristics (altitude, slope gradient, distance from the Southern Limited Line(SLL)) within the DMZs. The results showed that scale 72, shape 0.2, color 0.8, compactness 0.5 and smoothness 0.5 were the optimum weight values while scale, shape and color were most influenced parameters in image segmentation. The forests (92%) were main land cover type in the DMZs; the grassland(5%), the urban area (2%) and the forests (broadleaf forest: 44%, mixed forest: 42%, coniferous forest: 6%) also occupied mostly in land cover classes for sub-category. The results also showed that facilities and roads had higher density within 2 km from the SLL, while paddy, field and bare land were distributed largely outside 6 km from the SLL. In addition, there was apparent distinction in land cover by topographic characteristics. The forest had higher density at above altitude 600m and above slope gradient $30^{\circ}$ while agriculture, bare land and grass land were distributed mainly at below altitude 600m and below slope gradient $30^{\circ}$.

A Fuzzy-Neural network based IMM method for Tracking a Maneuvering Target (기동표적 추적을 위한 퍼지 뉴럴 네트워크 기반 다중모델 기법)

  • Son, Hyun-Seung;Joo, Young-Hoon;Park, Jin-Bae
    • Proceedings of the KIEE Conference
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    • 2006.07d
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    • pp.1858-1859
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    • 2006
  • This paper presents a new fuzzy-neural-network based interacting multiple model (FNNBIMM) algorithm for tracking a maneuvering target. To effectively handle the unknown target acceleration, this paper regards it as additional noise, time-varying variance to target model. Each sub model characterized by the variance of the overall process noise, which is obtained on the basis of each acceleration interval. Since it is hard to approximate this time-varying variance adaptively owing to the unknown acceleration, the FNN is utilized to precisely approximate this time-varying variance. The gradient descendant method is utilized to optimize each FNN. To show the feasibility of the proposed algorithm, a numerical example is provided.

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Flexible Nonlinear Learning for Source Separation

  • Park, Seung-Jin
    • Journal of KIEE
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    • v.10 no.1
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    • pp.7-15
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    • 2000
  • Source separation is a statistical method, the goal of which is to separate the linear instantaneous mixtures of statistically independent sources without resorting to any prior knowledge. This paper addresses a source separation algorithm which is able to separate the mixtures of sub- and super-Gaussian sources. The nonlinear function in the proposed algorithm is derived from the generalized Gaussian distribution that is a set of distributions parameterized by a real positive number (Gaussian exponent). Based on the relationship between the kurtosis and the Gaussian exponent, we present a simple and efficient way of selecting proper nonlinear functions for source separation. Useful behavior of the proposed method is demonstrated by computer simulations.

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Bidirectional Link Resource Allocation Strategy in GFDM-based Multiuser SWIPT Systems

  • Xu, Xiaorong;Sun, Minghang;Zhu, Wei-Ping;Feng, Wei;Yao, Yingbiao
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.1
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    • pp.319-333
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    • 2022
  • In order to enhance system energy efficiency, bidirectional link resource allocation strategy in GFDM-based multiuser SWIPT systems is proposed. In the downlink channel, each SWIPT user applies power splitting (PS) receiver structure in information decoding (ID) and non-linear energy harvesting (EH). In the uplink channel, information transmission power is originated from the harvested energy. An optimization problem is constructed to maximize weighted sum ID achievable rates in the downlink and uplink channels via bidirectional link power allocation as well as subcarriers and subsymbols scheduling. To solve this non-convex optimization problem, Lagrange duality method, sub-gradient-based method and greedy algorithm are adopted respectively. Simulation results show that the proposed strategy is superior to the fixed subcarrier scheme regardless of the weighting coefficients. It is superior to the heuristic algorithm in larger weighting coefficients scenario.

o-DGT as a Biomimic Surrogate to Assess Phytoaccumulation of Phenanthrene in Contaminated Soils (o-DGT를 생체모사 대표물질로 이용한 오염토양에서 phenanthrene의 식물축적 평가)

  • Choi, Jiyeon;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
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    • v.24 no.6
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    • pp.16-25
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    • 2019
  • Anthropogenic polycyclic aromatic hydrocarbons (PAHs) are formed by the incomplete combustion of fuels and industrial waste. PAHs can be widely exposed to the environment (water, soil and groundwater). PAHs are potentially toxic, mutagenic and/or carcinogenic. Fundamental studies such as biota uptake (e.g., earthworm and plant) of PAHs are highly needed. It is necessary to develop alternative ways to evaluate bioavailability of PAHs instead of using living organisms because it is time-consuming, difficult to apply in the field, and also exaction method is tedious and time-consuming. In this study, sorption behaviors of phenanthrene were evaluated to predict the fate of PAHs in soils. Moreover, bioaccumulation of PAHs in an artificially contaminated soil was evaluated using pea plant (Pisum sativum) as a bioindicator. A novel passive sampler, organic-diffusive gradient in thin-film (o-DGT) for PAHs was newly synthesized, tested as a biomimic surrogate and compared with plant accumulation. Sorption partitioning coefficient (KP) and sorption capacity (KF) were in the order of natural soil > loess corresponding to the increase in organic carbon content (foc). Biota-to-soil accumulation factor (BSAF) and DGT-to-soil accumulation factor (DSAF) were evaluated. o-DGT uptake was linearly correlated with pea plant uptake of phenanthrene in contaminated soil (R2=0.863). The Tenax TA based o-DGT as a biomimic surrogate can be used for the prediction of pea plant uptake of phenanthrene in contaminated soil.