• Title/Summary/Keyword: Sub-division method

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Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.20
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    • pp.39-46
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    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

Optimization of Spark Plasma Sintering Temperature Conditions for Enhancement of Thermoelectric Performance in Gas-Atomized Bi0.5Sb1.5Te3 Compound

  • Jeong, Kwang-yong;Lee, Chul Hee;Dharmaiah, Peyala;Hong, Soon-Jik
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.108-114
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    • 2017
  • We fabricate fine (<$20{\mu}m$) powders of $Bi_{0.5}Sb_{1.5}Te_3$ alloys using a large-scale production method and subsequently consolidate them at temperatures of 573, 623, and 673 K using a spark plasma sintering process. The microstructure, mechanical properties, and thermoelectric properties are investigated for each sintering temperature. The microstructural features of both the powders and bulks are characterized by scanning electron microscopy, and the crystal structures are analyzed by X-ray diffraction analysis. The grain size increases with increasing sintering temperature from 573 to 673 K. In addition, the mechanical properties increase significantly with decreasing sintering temperature owing to an increase in grain boundaries. The results indicate that the electrical conductivity and Seebeck coefficient ($217{\mu}V/K$) of the sample sintered at 673 K increase simultaneously owing to decreased carrier concentration and increased mobility. As a result, a high ZT value of 0.92 at 300 K is achieved. According to the results, a sintering temperature of 673 K is preferable for consolidation of fine (<$20{\mu}m$) powders.

Comparison of the Real-time Measurements for PM2.5 and Quality Control Method (PM2.5 자동측정장비 비교 및 정도관리 방안)

  • Park, Mikyung;Park, Jin Su;Jo, Mira;Lee, Yong Hwan;Kim, Hyun Jae;Oh, Jun;Choi, Jin Soo;Ahn, Joon Young;Hong, You Deog
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.6
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    • pp.616-625
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    • 2017
  • Measurements using five real-time particle samplers were compared to measurements using three NRM (National Reference Method system) filter-based samplers(Gravimetric method) at Incheon, Korea, between May and August, 2014. The purpose of this study was to suggest the quality assurance/quality control (QA/QC) method of each instrument for use in a real-time continuous particle sampler to measure the mass of airborne particles with an aerodynamic diameter less than $2.5{\mu}m$ ($PM_{2.5}$). Five real-time particle samplers of BAM1020, FH62C_14, TEOM, PM-711 and SPM-613 were evaluated by comparing its measured 23 hr average $PM_{2.5}$ concentrations with those measured with NRM filter-based samplers simultaneously. The parameters(e.g. Inlet heating condition, Slope factor, Film response, Intercept, Background, Span value) of the real-time samplers were optimized respectively by conducting test performance evaluation during 7 days in field sampling. For example, inlet heating temperature of TEOM sampler controls $35{\sim}40^{\circ}C$ to minimize the fluctuation of the real-time measurement data and background value of BAM1020 is the key factor affecting the accuracy of $PM_{2.5}$ mass concentration. We classified the $PM_{2.5}$ concentration according to relative humidity (80%) to identify water absorbed in aerosols by measuring the ${\beta}$-ray samplers(BAM1020, FH62C_14) and TEOM. ${\beta}$-ray samplers were not strongly affected by relative humidity that the difference of the average $PM_{2.5}$ concentration was about 5%. On the other hand, The TEOM sampler overestimated $PM_{2.5}$ mass concentration about 15% at low relative humidity (<80%).

Photosynthesis by Leaf Age and Fruit Characteristics by Fruiting Nodes in Vertical and Hydroponic Cultivation of Oriental Melon Applied with Air Duct for High-temperature Season (고온기 송풍 덕트 적용 수직·수경재배 참외의 엽령별 광합성과 착과 절위별 과실 특성)

  • Youngsin Hong;Sohyun Park;Sungwook Yun;Jinkyung Kwon;Siyoung Lee;Sanggyu Lee;Jongpil Moon;Jaekyung Jang;Hyojun Bae;Jeongsu Hwang
    • Journal of Bio-Environment Control
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    • v.32 no.2
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    • pp.89-96
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    • 2023
  • This study was conducted to apply with an air duct for the cooling and a utilizing cultivating method that uses the fruiting node and the defoliation to the high-temperature vertical and hydroponic cultivation of the oriental melon. The lower fruiting node (LF) was to remove all third vines generated from 5 nodes of a secondary vine. The higher fruiting node (HF) was fruiting on the third vine generated from a first node of the third vine. The direction of the stem string; upward (UW), downward (DW). Four treatment conditions were applied with the LF-UW, LF-DW, HF-UW (control), and HF-DW. The leaf age of melon leaves was measured for photosynthesis at 3 days intervals, and the fruit characteristic was conducted on 79 fruits in each treatment. The photosynthesis rate steadily increased after leaf development, reaching 20.8 μmol CO2·m-2·s-1 on the 10 days, gradually increasing to 21.3 μmol CO2·m-2·s-1 on the 19 days, and reaching 23.4 μmol CO2·m-2·s-1 on the 32 days. After that, it lowered to 16.8 μmol CO2·m-2·s-1 on the 38 days and dropped significantly to 7.6 μmol CO2·m-2·s-1 on the 47 days. As a result of the fruit characteristics by fruiting nodes, the treatments of the fruit length was 12.6-13.4 cm, respectively, which was significant, and the fruit width was 7.9- 8.6 cm, respectively, was not significant. The soluble content ranged from 12.9 to 15.7°Brix, and the significance of all treatments, and higher than of LF-DW and HF-UW. The photosynthesis rate of melon leaves was good until 32 days after leaf development, but after that, the rate decreased. As for fruit quality, it was conformed that melons can be cultivated at the LF because the fruit enlargement and soluble content dose not decrease even when set at the LF. Results indicated that those can be used for LF and defoliation in the development of vertical and hydroponic cultivation method in high-temperature season.

Thickness-Dependent Properties of Undoped and Mn-doped (001) PMN-29PT [Pb(Mg1/3Nb2/3)O3-29PbTiO3] Single Crystals

  • Oh, Hyun-Taek;Joo, Hyun-Jae;Kim, Moon-Chan;Lee, Ho-Yong
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.290-298
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    • 2018
  • In order to investigate the effect of thickness on the dielectric and piezoelectric properties of (001) PMN-29PT single crystals, three different types of PMN-29PT samples were prepared using the solid-state single crystal growth (SSCG) method: high density crystal [99%], low density crystal [95%], and high density crystal doped with Mn [98.5%]. When their thickness decreased from 0.5 mm to 0.05 mm, their dielectric constant ($K_3{^T}$), piezoelectric constants ($d_{33}$ and $g_{33}$), and electromechanical coupling factor ($k_t$) decreased continuously. However, their dielectric loss (tan ${\delta}$) increased. The addition of Mn to PMN-PT induced an internal bias electric field ($E_I$), increased the coercive electric field ($E_C$), and prevented local depoling. Therefore, Mn-doped PMN-PT crystals show high stability as well as high performance, even in the form of very thin plates (< 0.2 mm), and thus are suitable for application to high frequency composites, medical ultrasound probes, non-destructive testing devices (NDT), and flexible devices.

Fabrication of Nanostructured MoSi2-TaSi2 Composite by High-Frequency Induction Heating and its Mechanical Properties (고주파유도 가열에 의한 나노구조 MoSi2-TaSi2 복합재료 제조 및 기계적 특성)

  • Ko, In-Yong;Park, Na-Ra;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.5
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    • pp.369-374
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    • 2012
  • Nanopowders of Mo, Ta and Si were made by high-energy ball milling. A dense nanostructured $MoSi_2-TaSi_2$ composite was sintered by the high-frequency induction heated combustion method within 2 minutes from mechanically activated powder of Mo, Ta and Si. A highly dense $MoSi_2-TaSi_2$ composite was produced under simultaneous application of a 80 MPa pressure and the induced current. Mechanical properties and microstucture were investigated. The hardness and fracture toughness of the $MoSi_2-TaSi_2$ composite were $1200kg/mm^2$ and $3.5MPa.m^{1/2}$, respectively. The mechanical properties were higher than those of monolithic $MoSi_2$.

Low-temperature Synthesis of (TiC+Al2O3) Reinforced Al Matrix Composite Based on Self-combustion Reaction (자발연소반응을 이용한 (TiC+Al2O3)/Al 복합재료의 저온합성)

  • Lee, Jung-Moo;Kim, Su-Hyeon;Cho, Young-Hee;Kim, Je-Woo;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.1001-1004
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    • 2011
  • The formation of TiC and $Al_2O_3$ particles based on the self-combustion reaction of the $Al-TiO_2-C-CuO$ system in an Al alloy melt was investigated. With an adequate amount of CuO in the system, a spontaneous reaction occurred within the Al alloy melt at $850^{\circ}C$ and thereafter was self-maintained, producing an Al matrix composite reinforced with thermodynamically stable TiC and $Al_2O_3$ particles. TiC and $Al_2O_3$ particles contributed to a considerable increase in the strength and stiffness, demonstrating the feasibility of this method as a practical application for structural parts.

Electrochemical Properties of LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+ Synthesized by Combustion Method (연소법으로 합성한 LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+ 전기화학적 특성)

  • Kwon, Ikhyun;Song, Myoungyoup
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.276-281
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    • 2005
  • $LiNi_{1-y}M_{y}O_{2}(M=Zn^{2+},\;Al^{3+},\;and\;Ti^{4+},\;0.000\{\le}y{\le}0.100)$ were synthesized by the combustion method by calcining in $O_{2}$ stream at $750^{\circ}C$ for 36 h. XRD analyses, observation by FE-SEM and measurement of the variation of discharge capacity with the number of cycles were carried out. The composition $LiNi_{0.99}M_{0.01}O_{2}(M=Zn^{2+},\;Al^{3+},\;and\;Ti^{4+})$ of all the compositions showed relatively good electrochemical properties. $LiNi_{0.99}M_{0.01}O_{2}$ exhibited poor crystallinity and $LiNi_{0.99}M_{0.01}O_{2}$ showed the cation mixing of large fraction. $LiNi_{0.99}M_{0.01}O_{2}$ with improved cycling performance showed good crystallinity and the cation mixing of small fraction.

Study on the Synthesis by Milling and Solid-State Reaction Method and Electrochemical Properties of LiNiO2 (기계적 혼합과 고상법에 의한 LiNiO2의 합성과 전기화학적 특성)

  • Kim, Hunuk;Youn, SunDo;Lee, Jaecheon;Park, HyeRyoung;Song, Myoungyaup
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.319-325
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    • 2005
  • [ $LiNiO_2$ ] was synthesized by the solid-state method after mixing $LiOH{\cdot}H_2O$ and $Ni(OH)_2$ with SPEX mill. The optimum condition for the synthesis of $LiNiO_2$ was the calcination at $750^{\circ}C$ for 30h in $O_2$ stream after milling for 1 h. The $LiNiO_2$ synthesized under this condition showed relatively large value of $I_{003}/I_{104}$ and relatively small value of R-factor. When $LiNiO_2$ was cycled in 2.7$\~$4.15 V at 0.1C-rate, the first discharge capacity was not very large (145.8 mAh/g) but it showed good cycling performance. When $LiNiO_2$ was cycled in 2.7$\~$4.2 V at 0.1C-rate, the first discharge capacity was large but ,it showed poor cycling performance probably because of the transition of H2 hexagonal structure to H3 hexagonal structure. In addition, when $LiNiO_2$ was cycled in 1.0$\~$4.8 V at 1/24C- rate, the first discharge capacity was very large (257.7 mAh/g) and the discharge capacity increased with the number of cycles.

Preparation and Properties of Hollow Fiber Membrane for CO2/H2 Separation (이산화탄소/수소 분리용 중공사형 기체분리막의 제조 및 특성)

  • Hyung Chul Koh;Mi-jin Jeon;Sang-Chul Jung;Yong-Woo Jeon
    • Membrane Journal
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    • v.33 no.4
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    • pp.222-232
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    • 2023
  • In this study, a hollow fiber support membrane was prepared by a non-solvent induced phase separation (NIPS) method using a polysulfone (PSf). The prepared hollow fiber support membrane was coated with PDMS and Pebax to prepare a hollow fiber composite membrane. The prepared composite membrane was measured for permeance and selectivity for pure CO2, H2, O2 and N2. Gas separation performance of the module having the highest selectivity (CO2/H2) among the prepared composite membrane modules was measured according to the change in stage cut using simulated gas. The composition of the simulated gas used at this time was 70% CO2 and 30% H2. In the 1 stage experiment, it was possible to obtain values of about 60% of H2 concentration and 12% of H2 recovery. In order to overcome the low H2 concentration and recovery, 2 stage serial test was performed, and through this, it was possible to achieve 70% H2 concentration and 70% recovery. Through this, it was possible to derive a separation process configuration for CO2/H2 separation.