• Title/Summary/Keyword: Sub-division method

Search Result 855, Processing Time 0.031 seconds

Photoluminescence and Long-phosphorescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor by Glycine-nitrate Combustion Method (글리신-질산염 연소법으로 합성된 SrAl2O4:Eu2+,Dy3+ 형광체의 발광 및 장잔광 특성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
    • /
    • v.20 no.7
    • /
    • pp.364-369
    • /
    • 2010
  • A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

Fabrication of Gd1.5Ba2Cu3O7-y Bulk Superconductors from the Powder Synthesized by a Solid-State Reaction Method (고상반응법으로 합성한 분말로부터 Gd1.5Ba2Cu3O7-y 벌크 초전도체의 제조)

  • Kim, Yong Ju;Park, Seung Yeon;You, Byung Youn;Park, Soon-Dong;Kim, Chan-Joong
    • Korean Journal of Materials Research
    • /
    • v.23 no.6
    • /
    • pp.309-315
    • /
    • 2013
  • $GdBa_2Cu_3O_{7-y}$(Gd123) powders were synthesized by the solid-state reaction method using $Gd_2O_3$ (99.9% purity), $BaCO_3$ (99.75%) and CuO (99.9%) powders. The synthesized Gd123 powder and the Gd123 powder with $Gd_2O_3$ addition ($Gd_{1.5}Ba_2Cu_3O_{7-y}$(Gd1.5)) were used as raw powders for the fabrication of Gd123 bulk superconductors. The Gd123 and Gd1.5 bulk superconductors were fabricated by sintering or a top-seeded melt growth (TSMG) process. The superconducting transition temperature ($T_{c,onset}$) of the sintered Gd123 was 93 K and the transition width was as large as 20 K. The $T_{c,onset}$ of the TSMG processed Gd123 was 82 K and the transition width was also as large as 12 K. The critical current density ($J_c$) at 77 K and 0 T of the sintered Gd123 and TSMG processed Gd123 were as low as a few hundreds A/$cm^2$. The addition of 0.25 mole $Gd_2O_3$ and 1 wt.% $CeO_2$ to Gd123 enhanced the $T_c$, $J_c$ and magnetic flux density (H) of the TSMG processed Gd123 sample owing to the formation of the superconducting phase with high flux pinning capability. The $T_c$ of the TSMG processed Gd1.5 was 92 K and the transition width was 1 K. The $J_cs$ at 77 K (0 T and 2 T) were $3.2{\times}10^4\;A/cm^2$ and $2.5{\times}10^4\;A/cm^2$, respectively. The H at 77 K of the TSMG-processed Gd1.5 was 1.96 kG, which is 54% of the applied magnetic field (3.45 kG).

Evaluation of Korean distant water tuna fisheries in the Western and Central Pacific Ocean using ecosystem-based fishery risk assessment (중서부태평양해역 다랑어어업의 생태계기반 어업 위험도 평가)

  • KWON, Youjung;LIM, Jung-hyun;LEE, Mi Kyung;LEE, Sung Il
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • v.56 no.4
    • /
    • pp.299-315
    • /
    • 2020
  • Tuna fisheries were applied to an integrated ecosystem-based fishery risk assessment method using indexes of target species status, inhabited species in a target ecosystem, habitat quality and socio-economic benefit of affected fisheries. This study suggested more effective and efficient management measures to break away from traditional management methods, such as limitation of catch and fishing effort. The results presented that the objective risk index (ORIS) on sustainability of bigeye and yellowfin tunas by purse seine fishery was estimated high due to the high catch ratio of small fishes. The ORIs of biodiversity (ORIB) and habitat quality (ORIH) of purse seine fishery were also estimated at a high level from using fish-aggregating devices (FAD). However, due to skipjack tuna's high catches, the ORI of socio-economic benefit (ORIE) was estimated at a very low level. Due to the high bycatch rate, ORIB was high, and ORIS and ORIH were evaluated at a low level in longline fishery. Due to strengthern of fishing restrictions and increase of fishing costs, the ORIE was assessed to be very high. The ecosystem risk index (ERI) for two tuna fisheries was assessed low, but the overall FAD management by purse seine fishery is necessary at the ecosystem level.

Oxygen Equilibrium and the Solubility of MgO in CaO-FetO-MgO-SiO2(≤5mass%)-ΣMxOy Slags and Molten Iron (CaO-FetO-MgO-SiO2(≤5mass%)-ΣMxOy계 슬래그의 MgO포화용해도와 용철 간 산소평형)

  • Shin, Dong-Yeop;Lee, Joo-Ho;Hong, Seong-Hun;You, Byung-Don;Seo, Seong-Mo;Park, Jong-Min
    • Korean Journal of Metals and Materials
    • /
    • v.48 no.8
    • /
    • pp.765-774
    • /
    • 2010
  • Oxygen equilibrium and the solubility of MgO have been measured in the $CaO-Fe_tO-MgO-SiO_2({\leq}5mass%)-{\Sigma}M_xO_y$ slag in equilibrium with liquid iron in the temperature range of 1550 to $1700^{\circ}C$. The effect of oxides on the MgO solubility, and a method for calculating the solubility of MgO using slag composition and temperature,were discussed. The solubility of MgO is increased with increasing temperature and $Fe_tO$ content, and with decreasing basicity (C/S). The effect of ${\Sigma}M_xO_y$ on the solubility of MgO is a dilution effect due to the increase in slag volume. The activity and activity coefficient of $Fe_tO$ decreased with increasing basicity (B). The effect of temperature on the activity was negligible. The value of ${\rho}=Fe^{3+}/Fe^{2+}$ increased with the increase of the slag basicity (B") and the decrease of the $Fe_tO$ content in the slag.

A Practical Method to Quantify Very Low Fluxes of Nitrous Oxide from a Rice Paddy (벼논에서 미량 아산화질소 플럭스의 정량을 위한 실용적 방법)

  • Okjung, Ju;Namgoo, Kang;Hoseup, Soh;Jung-Soo, Park
    • Korean Journal of Agricultural and Forest Meteorology
    • /
    • v.24 no.4
    • /
    • pp.285-294
    • /
    • 2022
  • In order to accurately calculate greenhouse gas emissions in the agricultural field, Korea has been developing national-specific emission factors through direct measurement of gas fluxes using the closed-chamber method. In the rice paddy, only national-specific emission factors for methane (CH4) have been developed. It is thus necessary to develop those for nitrous oxide (N2O) affected by the application of nitrogen fertilizer. However, since the concentration of N2O emission from rice cultivation is very low, the QA/QC methods such as method detection and practical quantification limits are important. In this study, N2O emission from a rice paddy was evaluated affected by the amount of nitrogen fertilizer, by taking into account both method detection and practical quantification limits for N2O concentration. The N2O emission from a rice paddy soils affected by the nitrogen fertilizer application was estimated in the following order. The method detection limit (MDL) of N2O concentration was calculated at 95% confidence level based on the pooled standard deviation of concentration data sets using a standard gas with 98 nmol mol-1 N2O 10 times for 3 days. The practical quantification limit (PQL) of the N2O concentration is estimated by multiplying 10 to the pooled standard deviation. For the N2O flux data measured during the rice cultivation period in 2021, the MDL and PQL of N2O concentration were 18 nmol mol-1 and 87 nmol mol-1, respectively. The measured values above the PQL were merely about 12% of the total data. The cumulative N2O emission estimated based on the MDL and PQL was higher than the cumulative emission without nitrogen fertilizer application. This research would contribute to improving the reliability in quantification of the N2O flux data for accurate estimates of greenhouse gas emissions and uncertainties.

Random-Oriented (Bi,La)4Ti3O12 Thin Film Deposited by Pulsed-DC Sputtering Method on Ferroelectric Random Access Memory Device

  • Lee, Youn-Ki;Ryu, Sung-Lim;Kweon, Soon-Yong;Yeom, Seung-Jin;Kang, Hee-Bok
    • Transactions on Electrical and Electronic Materials
    • /
    • v.12 no.6
    • /
    • pp.258-261
    • /
    • 2011
  • A ferroelectric $(Bi,La)_4Ti_3O_{12}$ (BLT) thin film fabricated by the pulsed-DC sputtering method was evaluated on a cell structure to check its compatibility to high density ferroelectric random access memory (FeRAM) devices. The BLT composition in the sputtering target was $Bi_{4.8}La_{1.0}Ti_{3.0}O_{12}$. Firstly, a BLT film was deposited on a buried Pt/$IrO_x$/Ir bottom electrode stack with W-plug connected to the transistor in a lower place. Then, the film was finally crystallized at $700^{\circ}C$ for 30 seconds in oxygen ambient. The annealed BLT layer was found to have randomly oriented and small ellipsoidal-shaped grains (long direction: ~100 nm, short direction: ~20 nm). The small and uniform-sized grains with random orientations were considered to be suitable for high density FeRAM devices.

Compensation of Timing Offset and Frequency Offset in the Multi-Band Receiver with Sub-Sampling Method (Sub-Sampling 방식의 다중 대역 수신기에서 타이밍 오프셋과 주파수 오프셋 보상)

  • Lee, Hui-Kyu;Ryu, Heung-Gyoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.22 no.5
    • /
    • pp.501-509
    • /
    • 2011
  • Software defined radio(SDR) has a goal that places the analog-to-digital converter(ADC) as near the antenna as possible. But current technique actually can't do analog-to-digital converting about RF band signals. So one method is studying that samples RF band signals to IF band. One of the ways Sub-Sampling technique can convert signals from RF band to IF band without oscillator. If Sub-Sampling technique is used, over 2 bands can convert signals from RF band to IF band. But due to the filter performance in RF band, it is possible to generate interference between signals that is converted in low frequency band. The effect degrades performance. In this paper, we propose one method that uses time division multiplexing(TDM) method as a solution to avoid interference between signals. By doing TDM and Sub-Sampling at the same time that method can get signals without large changes of structures.

Electrochemical Properties of LiMn1.92Co0.08O4 and LiNi0.7Co0.3O2 Mixtures Prepared by a Simplified Combustion Method (단순화한 연소법에 의해 합성한 LiMn1.92Co0.08O4와 LiNi0.7Co0.3O2 혼합물의 전기화학적 특성)

  • Song, Myoungyoup;Kwon, IkHyun;Kim, Hunuk
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.10 s.269
    • /
    • pp.735-741
    • /
    • 2004
  • $LiMn_{1.92}Co_{0.08}O_4$ and $LiNi_{0.7}Co_{0.3}O_2$ synthesized by a simplified combustion method had good electrochemical properties. Mixtures $LiMn_{1.92}Co_{0.08}O_4$-x wt$\%$ $LiNi_{0.7}Co_{0.3}O_2$ (x=9, 23, 33, 41, and 47) were prepared by milling for 30 min and their electrochemical properties were investigated. The electrode with x=9 had a relatively large first discharge capacity (109.9 mAh/g at 0.1 C) and good cycling performance. The decrease in the discharge capacity of the mixture electrodes with cycling is considered to result mainly from the degradation of $LiNi_{0.7}Co_{0.3}O_2$, caused by coating of $LiNi_{0.7}Co_{0.3}O_2$ with Mn dissolved from $LiMn_{1.92}Co_{0.08}O_4$.

Synthesis and Photoluminescence Studies on Sr1-xBaxAl2O4 : Eu2+, Dy3+

  • Ryu, Ho-Jin;Singh, Binod Kumar;Bartwal, Kunwar Singh
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.3
    • /
    • pp.146-149
    • /
    • 2008
  • Strontium-substituted $Sr_{1-x}Ba_xAl_2O_4:Eu^{2+},\;Dy^{3+}$ compositions were prepared by the solid state synthesis method. These compositions were characterized for their phase, crystallinity and morphology using powder x-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. Photoluminescence properties were investigated by measuring excitation spectra, emission spectra and decay time for varying Ba/Sr concentrations. Photoluminescence results show higher luminescence and long decay time for $Sr_{1-x}Ba_xAl_2O_4:Eu^{2+},\;Dy^{3+}$(x=0). This is probably due to the influence of the 5d electron states of $Eu^{2+}$ in the crystal field. Long persistence was observed for these compositions due to $Dy^{3+}$ co-doping.

Surface Hardness Measurement of Anodic Oxide Films on AA2024 based an Ink-Impregnation Method

  • Moon, Sungmo;Rha, Jong-joo
    • Journal of the Korean institute of surface engineering
    • /
    • v.53 no.2
    • /
    • pp.80-86
    • /
    • 2020
  • This paper is concerned with type of imperfections present within the anodic oxide films on AA2024 and surface hardness of the anodic film measured after ink-impregnation. The anodic oxide films were formed for 25 min at 40 mA/㎠ and 15±0.5℃ and 300 rpm of magnet stirring rate in 20% sulfuric acid solution. The ink-impregnation allows clear observations of not only the imperfections within the anodic oxide films but also an indentation mark on the oxide film surface made by a pyramidal-diamond penetrator for the hardness measurement. There were observed four different regions in the anodic oxide films on AA2024 and the surface hardness of the anodic oxide films appeared to be crucially dependent on the type of defects, showing 60~100 Hv on the oxide surface region I with large size black defect, 100~140 Hv on the oxide surface region II with large size grey defect, 140~170 Hv on the oxide surface region III with mall size black and/or grey defects and 170~190 Hv on the oxide surface region IV without defects. The pyramidal indentation marks were observed to be distorted in the regions with a large size black and grey defects, while no distortion of the indentation mark was observed in the regions with small size defects and without visible defects.