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Adsorption of methylene blue from an aqueous dyeing solution by use of santa barbara amorphous-15 nanostructure: Kinetic and isotherm studies

  • Alizadeh, Reza;Zeidi, Amir
    • Advances in environmental research
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    • v.6 no.2
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    • pp.113-125
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    • 2017
  • Santa Barbara Amorphous-15(SBA-15) nanoparticles were utilized as the inexpensive and effective adsorbents to remove methylene blue dye from the aqueous solution.SBA-15 was created by Zhao et al method. Infrared spectroscopy, X-ray diffraction and scanning electron microscopy (SEM) were used for the evaluated physical properties of SBA-15. The results of diffraction X-ray indicated that was the crystalline structure for it. Also IR spectroscopy indicated was a silica the whole structure of the groups and SEM image verify the structure of relatively identical particles size of SBA-15. Factors affecting adsorption including the amounts of adsorbent, pH and contact time were investigated by a SBA-15 nanomaterial design. The extent of dye removal enhanced with increasing initial dye concentration and pH from 4 to 10. The higher percentage adsorption were obtained under optimum conditions of variables (sorbent dose of 200 mg/liter, initial MB concentration 10 mg/liter, initial pH of 10 and temperature of $25^{\circ}C$). Maximum adsorption happened after the 2 hour and the kinetic processes of the dyes adsorption were described by applying the pseudo-first-order and the pseudo-second-order and the relatively High correlation with the kinetic Ellovich models. It was found that the pseudo-second-order models kinetic equation described the data of dye adsorption with a good correlation (R2>0.999) which indicated chemisorption mechanism. Freundlich and Langmuir adsorption models were investigated in conditions of variables (adsorbent dose 0.01 gr/liter, MB concentration 10, 20, 30 mg/liter, pH of 4, 7, 10, contact time 90 min and temperature of $27^{\circ}C$). The adsorption data were represented by Langmuir isotherm model. These values are higher than the adsorption capacities of some other adsorbents that have recently been published in the literature.

Synthesis of Tialite Ceramic Pigments and Coloring in Glazes (Tialite계 세라믹 안료의 합성 및 유약에서의 발색)

  • Kim, Yeon-Ju;Lee, Byung-Ha
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.450-455
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    • 2011
  • [ $Al_2TiO_5$ ]has a high refractive index and good solubility of the chromophore in the $Al_2TiO_5$ lattice, which allows this structure to be a good candidate for the development of new ceramic pigments. However, pure $Al_2TiO_5$ is well known to decompose on firing at $900{\sim}1100^{\circ}C$. However, this process can be inhibited by the incorporation of certain metal cations into its crystalline lattice. In this study, the synthesis of gray ceramic pigment was performed by doping cobalt on the $Al_2TiO_5$ crystal structure. The $Al_2TiO_5$ was synthesized using $Al_2O_3$ and $TiO_2$, and doped with $Co_3O_4$ as a chromophore material. In order to prevent the thermal decomposition during the cooling procedure, MgO was added to samples by 0.05 mole, 0.1 mole, and 0.15 mole as a stabilizer. The samples were fired at $1500^{\circ}C$ for 2 hours and cooled naturally. The crystal structure, solubility limit, and color of the synthesized pigment were analyzed using XRD, Raman spectroscopy, UV, and UV-vis. $Al_2O_3$ was available for the formation of $CoAl_2O_4$, which should also be considered in order to explain the small amount of this phase detected in the sample with the higher $Co^{2+}$ content (${\geq}$ 0.03 mole). It was found that the solubility limit of $Co^{2+}$ in the $Al_2TiO_5$ crystal was 0.02 mole% through an analysis of Raman spectroscopy. Through the addition of a pigment with 0.02 mole% of $Co^{2+}$ to lime-barium glaze, stabilized gray color pigments with 66.54, -2.35, and 4.68 as CIE-$L^*a^*b^*$ were synthesized.

Isolated and Identification of Biological Activity Compounds from Leaves and Stem of Paeonia lactiflora Pallas (작약 잎과 줄기의 생리활성 물질 분리 및 동정)

  • Kim, Se-Jong;Park, Jun-Hong;Choi, Seong-Yong;Son, Kun-Ho;Kim, Kil-Ung
    • Korean Journal of Medicinal Crop Science
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    • v.15 no.1
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    • pp.6-11
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    • 2007
  • This study was conducted to identify physiologically active substances from leaves and stems of peony plant. MeOH extracts and column chromatography were employed to isolate active compounds and chemical structure were identified by IR, UV, Mass and NMR. The results obtained can be summerized as followings : Chemical structure of compound 1 was identified as oleanolic acid (white color form) of triterpenoid group, which is firstly identified from the above part of peony. Compound 2 was identified as kaempferol (yellow needle form) of flavonoid group, which was firstly identified from the root, leaf and stem of peony. Compound 3 was identified as methyl gallate (white power form) of phenol group, which was firstly identified from the above part of peony. Compound 4 was identified as astragalin (bright yellow needle form) of flavonoid group, that was firstly identified from the leaf and stem of peony. Compound 5 was identified as paeoniflorin (white color form) of monoterpene group, that was firstly identified from the above part of peony.

Development of Autometic Tomato Grade System with Using a Color Image Processing (칼라 영상을 이용한 토마토 자동 선별시스템의 개발)

  • 이지훈;최연호;김우현;윤경섭;권우현
    • Proceedings of the IEEK Conference
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    • 2003.07c
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    • pp.2529-2532
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    • 2003
  • The quality of agricultural products is represented a degree of freshness and a special qualify that has a close relation to commercial value. To grade tomatoes, it used to nondestructive equipment of a charge-coupled device(CCD) camera and near-infrared(NIR) spectrum analysis method. The NIR spectrum analysis method is used to determine internal qualities such as a brix and an acidity. The CCD camera is used to measure external qualities like color and a size of tomatoes. This paper explaines the structure and movement of the automatic grade system and applies the algorithm for deformed tomtatoes and characteristics of tomatoes through image processing to the grade system.

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The Treatment of Box-mill Wastewater Using Aerobic Cometabolism Process - Practical Plant Test - (호기성 공동대사작용에 의한 판지폐수처리 - 현장 적용 테스트 -)

  • Cho, Yong Duck;Lee, Sang Wha
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.128-137
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    • 2006
  • This study aims at developing the practical technology in the treatment of box-mill wastewater using the aerobic co-metabolism principle. The conventional activated sludge method exhibited the removal efficiency of $TBOD_5$ and $TCOD_{Mn}$ as 30~50% and 40~50%, respectively. Color was rather increased by 30~130% because the conventional treatment under the aerobic condition did not induce the conversion of molecular structure of dyeing agents. Meanwhile, when the aerobic co-metabolism principle was applied to the same wastewater, the removal efficiency of $TBOD_5$ and $TCOD_{Mn}$ were obtained as 92~97% and 90~94%, respectively. In particular, color was significantly reduced down to 65~85%. The enhancement of treatment efficiency was ascribed to occur not only that the non-degradables were converted to the second substrates, but also that the enzyme activity was increased as MLVSS was kept 3000mg/l or more with the first substrates injected.

Development of New LTPS Process

  • Yi, Chung;Park, Kyung-Min;Choi, Pil-Mo;Kim, Ung-Sik;Kim, Dong-Byum;Kim, Chi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1024-1026
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    • 2004
  • We have developed the five mask $PMOS^1$ and the six mask CMOS process architecture for poly-Si TFT. In order to have a competitive process with that for a-Si TFT, the simple co-planar electrode structure whose data line electrode and pixel electrode are on the same plane was adopted. In addition, RGB + White four color $technology^2$ were applied to achieve high aperture ratio and transmittance. Using the aforementioned process architecture and four color technology, 2.0 inch qCIF transmissive micro-reflectance (TMR) device was successfully fabricated.

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Mechanism of High Luminous Efficiency in Delta Color Arrayed, Enclosed Sub-pixel Structured AC PDP with High Xe Content

  • Bae, Hyun-Sook;Kim, Tae-Jun;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.59-62
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    • 2004
  • We investigated the effect of Xe content variation on the luminous efficiency of two different sub-pixel types, i.e., segmented electrode in delta color arrayed enclosed sub-pixel (SDE) and conventional stripe barrier type, in an ac plasma display panel through three-dimensional numerical simulations. The conventional cell type was found to have higher VUV generation efficiency as compared with that of SDE structure, but as the Xe content increased, the SDE type showed higher improvements in efficiency due to the lower plasma loss to the barrier walls.

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Development of Automatic Cucumber Grade System with Using a Color Image processing (컬러 영상처리를 이용한 오이 자동 선별 제어 시스템 개발)

  • Son, Hyun-Woo;Cho, Nae-Su;Kwon, Woo-Hyen;Lim, Sung-Woon;Choi, Yon-Ho;Kim, Woo-Hyun
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.453-455
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    • 2004
  • The quality of agricultural products is represented a degree of freshness and a special quality related to a commercial value. To grade cucumber, the charge-coupled device(CCD) camera is only used to measure external qualities like color. size and degree of bended cucumber The processed area of the image replaces the weigh of cucumber. That means there is no longer used the weighing beams. The system consists of Image processing system and distributing system. This paper explains the structure and movement of the automatic grade system and applies the algorithm for deformed cucumber and characteristics of cucumber through image processing to the grade system.

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Biological Treatemnt of Dye Wastewater Using an Anaerobic-Aerobic System (혐기-호기 공정을 이용한 염료페수의 생물학적 처리)

  • 박영식;문정현;안갑환
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.569-576
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    • 2002
  • Anaerobic/aerobic reactor system was used to treat a synthetic wastewater with glucose as carbon sources(0.38~2.29 kg COD/m3.day) and Acid Red 14(1.05 "24.00 g Acid Red 141m3.day, color degree of 570 ~ 1710). COD removal efficiency by the anaerobic stage in operation period were above 90 % organic loading rate of 0.38 ~ 2.29 kg COD/m3.day(except, adaptation period) and the removal efficiency of the whole system were above 96 %. The decolorization of the Acid Red 14 was through the alteration of the dye structure(or cleavage of the Azo bond) during the anaerobic treatment. In the A/A system, the anaerobic stage played an essential role in removing both color and COD. In addition it also improves biodegradability of dye f3r further aerobic treatment. After operation, average MLSS concentration of anaerobic sludge reactor, anaerobic fixed-bed reactor and aerobic fixed-bed reactor were 17100mg/L, 20000mg/L, and 10000mg/L, respectively.

PPMXL PHOTOMETRIC STUDY OF FOUR OPEN CLUSTER CANDIDATES (IVANOV 2, IVANOV 7, IVANOV 9 AND HARVARD 9)

  • Tadross, A.L.;Bendary, R.
    • Journal of The Korean Astronomical Society
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    • v.47 no.4
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    • pp.137-145
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    • 2014
  • The astrophysical parameters of four unstudied open star cluster candidates; Ivanov 2, 7, 9, and Harvard 9; are estimated for the first time using the PPMXL database. The stellar density distributions and color-magnitude diagrams for each cluster are used to determine the geometrical structure (cluster center, limited radius, core and tidal radii, the distances from the Sun, from the Galactic center and from the Galactic plane). Also, the main photometric parameters (age, distance modulus, color excesses, membership, total mass, relaxation time, luminosity and mass functions) are estimated.