• Journal of the Microelectronics and Packaging Society
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• v.9 no.1
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• pp.35-41
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• 2002

Flip-chip interconnection that uses solder bump is an essential technology to improve the performance of micro-electronics which require higher working speed, higher density, and smaller size. In this paper, the shear strength of Cr/Cr-Cu/Cu UBM structure of the high-melting solder bump and that of low-melting solder bump after aging is evaluated. Observe intermetallic compound and bump joint condition at the interface between solder and UBM by SEM and TEM. And analyze the shear load concentrated to bump applying finite element analysis. As a result of experiment, the maximum shear strength of Sn-97wt%Pb which was treated 900 hrs aging has been decreased as 25% and Sn-37wt%Pb sample has been decreased as 20%. By the aging process, the growth of $Cu_6/Sn_5$ and $Cu_3Sn$ is ascertained. And the tendency of crack path movement that is interior of a solder to intermetallic compound interface is found.

• Corrosion Science and Technology
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• v.3 no.5
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Journal of the Korea Institute of Building Construction
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• v.14 no.5
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• pp.397-405
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• 2014

There are many literatures reporting that the service life of re-bars in concrete structures is reduced in the oceanic environment due to chloride attack. To solve this problem, this study used geo-polymer as a mix material for concrete to increase its resistance to salt damage, and the external voltage method, one of the electric methods, is was applied to evaluate the likelihood of re-bars in the oceanic structure being exposed to the extreme salt environment. The items evaluated include the natural potential of re-bars and the corrosion rate. The results of the tests showed that in all of the salt environmental conditions (submerged zone, tidal zone, and crack), the tested materials were remarkably effective compared with ordinary concrete. The corrosion protective property was found not only in the evaluation of the natural potential but also in the evaluation of the corrosion rate, suggesting that the external voltage method can be used stably for geo-polymer RC structures in an extreme salt environment.

• Journal of the Korean Ceramic Society
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• v.54 no.3
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• pp.243-248
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• 2017

Pd-doped $SnO_2$ thick film with a pure tetragonal phase was prepared on patterned Pt electrodes by an ink dropping method. Nanostructured $SnO_2$ powder with a diameter of 10 nm was obtained by a modified hydrazine method. Then the ink solution was fabricated by mixing water, glycerol, bicine and the Pd-doped $SnO_2$ powder. When the Pd doping concentration was increased, the grain size of the Pd-doped $SnO_2$ thick film became smaller. However, an agglomerated and extruded surface morphology was observed for the films with Pd addition over 4 wt%. The orthorhombic phase disappeared even at a low Pd doping concentration and a PdO peak was obtained for a high Pd doping concentration. The crack-free Pd-doped $SnO_2$ thick films were able to successfully fill the $30{\mu}m$ gap of the patterned Pt electrodes by the optimized ink dropping method. The prepared 3 wt% Pd-doped $SnO_2$ thick films showed monoxide gas responses ($R_{air}/R_{CO}$) of 4.0 and 35.6 for 100 and 5000 ppm, respectively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.6
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• pp.176-181
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• 2018

Concrete structures are degraded physically and chemically due to various reasons after construction. Because the deterioration of concrete structure reduces the service life, reasonable repair and maintenance techniques are needed. Recently, in order to efficiently repair concrete structures, many researches on hybrid repair materials having improved adhesion performance have been carried out actively. In this study, we developed a hybrid repair material containing rapid hardening cement, PVA powder, nylon fiber, and latex to improve adhesion and water-tightness of existing concrete. The compressive strength, drying shrinkage and the adhesion strength test were carried out to evaluate the performance of the repair material. In addition, the flexure bond performance was evaluated before and after repair. From the results, the bending strength was 110% ~ 150% in all specimens except for the specimen containing only the rapid hardening cement, and all the specimens behaved with the existing concrete in the crack pattern generated by the bending strength.

• Journal of Conservation Science
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• v.7 no.2
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• pp.68-79
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• 1998

The protecting-chamber for a standing Buddha of Mireuk-ri temple site at Jungwon is composed of granite of Cretaceous age which mainly consists of quartz, perthite, plagioclase, and biotite with minor amounts of muscovite, apatite, chlorite, sericite and opaque mineral. There are abundant cracks which may be developed by strong weathering and differential loading by structural unbalances of the whole protecting-chamber. Cracks can be divided into three types based on genesis as those formed by exfoliation, intrinsic, and pressure. The exfoliation occurred along the onion structure of the granite. The pressure cracks are generally superimposed on the exfoliation ones, which might be developed by structural unbalance of the protecting-chamber resulted from differential loading in places. The structural unbalance may be due to change in physical properties of the rocks according to strong weathering, differential settling of basement soil by difference in loading in places of protecting-chamber, westward creep of the basement soil below the West wall and related different resistance of the basement soil against the loading, and partial depression of the West wall. For the conservation of the protecting-chamber, it must be considered the method of stabilizing the basement and treatment of the cracks.

• Microbiology and Biotechnology Letters
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• v.40 no.3
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• pp.169-179
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• 2012

Microbiological calcium carbonate precipitation (MCCP) is being applied for the aesthetic restoration of cement buildings destroyed by biochemical processes and to block water penetration into the cement's inner structure. After determining the advantages of this technique, many related studies in the area of architecture concerning the application of microorganisms to improve construction material have been reported in both America and Europe. The techniques compatibility with cement material is especially interesting because of the needed screening of various calcium carbonate forming-bacteria and the required development of their application methods. The purpose of this review is to describe the mechanism of MCCP and related researches with eco-friendly construction materials. Mainly, we describe the methodological studies focused on biodeposition on the surface of building materials and the research trends concerning the addition of microorganisms to improve the durability of cement structures. Additionally, the concepts and technical aspects focused on the development of self-healing smart concrete, with the use of multi-functional bacteria, have been considered.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.3
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• pp.70-79
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• 2020

The main objective of this research to develop an IoT based wireless contactless ultrasonic system (ICUS) and its application to concrete structure. The developed system consists of 16 mems, 2Mhz digitizer, amplifying circuit, FPGA, and wifi module, enabling to measure leaky surface waves from concrete specimens without physical coupling process and wires. Multi-channel analysis is performed to improve the accuracy of data analysis, and the velocity of leaky surface waves and acoustics are derived. Field inspection of railroad concrete sleepers is conducted to evaluate the performance of the system and to compare the results with conventional ultrasonic pulse velocity (UPV). As a result of the field inspection, UPV was limited to evaluate damages. This is because crack pattern of railroad sleepers is parallel to ultrasonic ray path and accessibility of the railroad at the field is disadvantageous to contact-based UPV. On the other hand, ICUS possibly detect the damages as reduction of dynamic modulus by up to 59% compared to non-damaged specimen.

• Korean Journal of Materials Research
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• v.24 no.5
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• pp.259-265
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• 2014

$ZrO_2$ films were coated on aluminum etching foil by the sol-gel method to apply $ZrO_2$ as a dielectric material in an aluminum(Al) electrolytic capacitor. $ZrO_2$ films annealed above $450^{\circ}C$ appeared to have a tetragonal structure. The withdrawal speed during dip-coating, and the annealing temperature, influenced crack-growth in the films. The $ZrO_2$ films annealed at $500^{\circ}C$ exhibited a dielectric constant of 33 at 1 kHz. Also, uniform $ZrO_2$ tunnels formed in Al etch-pits $1{\mu}m$ in diameter. However, $ZrO_2$ film of 100-200 nm thickness showed the withstanding voltage of 15 V, which was unsuitable for a high-voltage capacitor. In order to improve the withstanding voltage, $ZrO_2$-coated Al etching foils were anodized at 300 V. After being anodized, the $Al_2O_3$ film grew in the directions of both the Al-metal matrix and the $ZrO_2$ film, and the $ZrO_2$-coated Al foil showed a withstanding voltage of 300 V. However, the capacitance of the $ZrO_2$-coated Al foil exhibited only a small increase because the thickness of the $Al_2O_3$ film was 4-5 times thicker than that of $ZrO_2$ film.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.6
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• pp.1015-1022
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• 2001

The objective of this paper is to develop an expert system called NPIES for nuclear piping integrity. This paper describes the structure and the development strategy of the NPIES system. The NPIES system consists of 3 part; the data input part, the analysis part and the output part. The data input part consists of the material properties database module and the suer interface module. The analysis part consists of the LEFM, CDFD, J/T, limit load modules and the 12 analysis routines for different cracks and loading conditions are provided respectively. Analysis results are presented to screen, printer and text file in the output part. Several case studies on circumferentially cracked piping were performed to evaluate the accuracy and the usefulness of the code. Maximum piping loads predicted by the NPIES system agreed well with those by the 3-dimensional finite element analysis. In addition, even if the material properties were not fully given, the NPIES system provided reasonable evaluation results with the predicted material properties inferred from the material properties database module.