• Journal of the Korean Chemical Society
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• v.33 no.5
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• pp.468-476
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• 1989

Kineties for the reactions of pyridines with 1-anthracenesulfonyl chloride (1-ASC) and 3-phenanthrenesulfonyl chloride (3-PSC) was investigated in methanol as solvent. Structural variation in pyridine followed $Br{\o}$ nsted and Hammett relations for both 1-ASC and 3-PSC; the corresponding coefficients, {\beta}\;and\;{\rho}\;at\;20^{\circ}C$ were 0.55, -3.5 for 1-ASC, and 0.43, -2.6 for 3-PSC respectively. Reactivity-selectivity principle was checked in competition system 1-ASC/3-PSC. As a result, this principle was found to hold at experimental temperatures, whereas to break down over in the range of isoselective temperature ($34.3^{\circ}C$). Judging from the above results and activation parameters, we concluded that these reactions proceeded by synchronous $S_n2$ mechanism in rate-determining step.

• Structural Engineering and Mechanics
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• v.43 no.5
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• pp.637-655
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• 2012

In this study, stochastic responses of a cable-stayed bridge subjected to the spatially varying earthquake ground motion are investigated by the finite element method taking into account soil-structure interaction (SSI) effects. The considered bridge in the analysis is Quincy Bay-view Bridge built on the Mississippi River in between 1983-1987 in Illinois, USA. The bridge is composed of two H-shaped concrete towers, double plane fan type cables and a composite concrete-steel girder deck. In order to determine the stochastic response of the bridge, a two-dimensional lumped masses model is considered. Incoherence, wave-passage and site response effects are taken into account for the spatially varying earthquake ground motion. Depending on variation in the earthquake motion, the response values of the cable-stayed bridge supported on firm, medium and soft foundation soil are obtained, separately. The effects of SSI on the stochastic response of the cable-stayed bridge are also investigated including foundation as a rigidly capped vertical pile groups. In this approach, piles closely grouped together beneath the towers are viewed as a single equivalent upright beam. The soil-pile interaction is linearly idealized as an upright beam on Winkler foundation model which is commonly used to study the response of single piles. A sufficient number of springs on the beam should be used along the length of the piles. The springs near the surface are usually the most important to characterize the response of the piles surrounded by the soil; thus a closer spacing may be used in that region. However, in generally springs are evenly spaced at about half the diameter of the pile. The results of the stochastic analysis with and without the SSI are compared each other while the bridge is under the sway of the spatially varying earthquake ground motion. Specifically, in case of rigid towers and soft soil condition, it is pointed out that the SSI should be significantly taken into account for the design of such bridges.

• Journal of the Society of Naval Architects of Korea
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• v.33 no.4
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• pp.97-105
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• 1996

For the minimum weight design of ship structures it is desirable that tank arrangement is predetermined to obtain the minimum weight and then structural arrangement and scanting of each murder is determined to obtain the minimum weight within the given tank arrangement. To carry out the tank arrangement to give minimum weight a minimum weight design program which covers whole ship structures is developed by the combination of minimum weight design program of longitudinal members by classification rules and minimum weight design program of transverse members by generalized slope deflection method which were developed by the authors. The hullweight is estimated by summation of the weight of cargo hold part and the weight except cargo hold part which can be estimated by the empirical formula. In this study, the variation of hullweight is shown with the number of tank, the number of web and the location of longitudinal bulkhead. For the application of actual design alternative designs of tank arrangement which satisfy MARPOL regulation are determined. And several minimum weight designs of whole ship structures are carried out to obtain the tank arrangement which gives minimum weight and then the hullweight is compared with that of existing ship.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3335-3339
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• 2013

Boron-doped ZnO (BZO) nanorods were grown on quartz substrates using hydrothermal synthesis, and the temperature-dependence of their photoluminescence (PL) was measured in order to investigate the origins of their PL properties. In the UV range, near-band-edge emission (NBE) was observed from 3.1 to 3.4 eV; this was attributed to various transitions including recombination of free excitons and their longitudinal optical (LO) phonon replicas, and donor-acceptor pair (DAP) recombination, depending on the local lattice configuration and the presence of defects. At a temperature of 12 K, the NBE produces seven peaks at 3.386, 3.368, 3.337, 3.296, 3.258, 3.184, and 3.106 eV. These peaks are, respectively, assigned to free excitons (FX), neutral-donor bound excitons ($D^{\circ}X$), and the first LO phonon replicas of $D^{\circ}X$, DAP, DAP-1LO, DAP-2LO, and DAP-3LO. The peak position of the FX and DAP were also fitted to Varshni's empirical formula for the variation in the band gap energy with temperature. The activation energy of FX was about ~70 meV, while that of DAP was about ~38 meV. We also discuss the low temperature PL near 2.251 eV, related to structural defects.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1356-1364
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• 1990

This paper deals with the preliminary design conditions of Stirling Engines based on an adiabatic analysis with regenerator effectiveness. The investigation of thermal regeneration process results that the definition of effectiveness proposed by Urieli et al. is appropriate for the present model. Then, it is applied to the already existing approximate analytic solution for the adiabatic model in order to optimize thermal efficiency as well as work parameter. Results show that thermal efficiency is less sensitive to the variation in design parameters than work. Phase angle for the maximum work is also the most efficient at high values of the effectiveness. Swept volume ratio should be chosen with care. The optimum value of dead volume ratio is at least less than the maximum efficiency condition. The feasible design range in compression ratio lies between the maximum efficiency condition and the structural limit of Stilring Engines, where the higher its value, the better. Changes in the temperature ratio do not alter the design conditions. Working fluids with the specific heat ratio 1.67 are more efficient that those with 1.4.

• Journal of the Korean Wood Science and Technology
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• v.37 no.4
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• pp.320-329
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• 2009

The purpose of this study was reducing the moisture accumulation in a wall, which can threaten the structural safety of light-frame wall and make residential environment poor. For the purpose, the laboratory test was carried out with different wall assemblies. Vapor retarder and air gap for ventilation were added to the typical wall. The improved performance of the proposed walls was examined through the test with distinct difference of temperature and relative humidity between outdoor and indoor air conditions. Increased dampproofing performance of additional vapor retarder was effective on reduction of moisture transmission from inside the house into the wall. However, unexpected high relative humidity was shown in the wall with two additional vapor retarder because of excessive dampproofing performance or inadequate location of vapor retarder. And, the open air gap induced the moisture transfer from inside the wall into outdoor air by ventilation. If the alternative to the induction of moisture transmission from inside the house into the wall with open air gap can be found, moisture reduction effect of that will be increased obviously.

• The Korean Journal of Pain
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• v.27 no.3
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• pp.253-259
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• 2014

Background: Caudal block is a common technique in children for reducing postoperative pain, and there have been several reports on the variations of the sacral canal in children. However, previous studies have mainly focused on the needle trajectory for caudal block, and there is limited information on the structural variations of the sacrum in children. The purpose of this study was to analyze the anatomic variations of sacral canals in children. Methods: Three-dimensional computed tomographic images were analyzed. The data from the images included (1) fusion of the sacral vertebral laminae and the sacral intervertebral space (2) existence of the sacral cornua and (3) the types of sacral hiatus. The types of sacral hiatus were classified into 3 groups: group I (fusion of S3 or S4 vertebral laminae), group II (unfused vertebral arch with the distance of the S3 and S4 vertebral laminae < 50% of the distance between the cornua), and group III (unfused vertebral arch with the distance of the S3 or S4 vertebral laminae ${\geq}50%$ of the distance between the cornua). Results: A total of 143 children were included in this study. All of the sacral vertebral arches were not fused in 22 children (15.4%). Cornua were not identified bilaterally in 5 (3.5%) and unilaterally in 6 (4.2%) children. In the sacral hiatus, group II and group III were identified in 22 (15.4%) and 31 (21.7%) children, respectively. Conclusions: The sacral canal has various anatomical variations in children. Careful attention must be paid to identify the correct anatomic landmark.

• Environmental Engineering Research
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• v.24 no.4
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• pp.670-679
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• 2019

Lignin complexity molecule makes its biodegradation difficult during lignocellulosic wastes composting. So, the improvement of its biodegradation has usually been considered as an objective. This study aimed to determine the impact of Trametes trogii inoculation on organic matter and particularly on lignin and cellulose during green wastes co-composting with olive mill waste water sludge and coffee grounds. Three types of heaps (H1, H2 and H3) were investigated during 180 d. H3 and H2 were inoculated at the beginning of the process (t₀) and 120 d later (t₁₂₀), respectively while H1 was the control. Results showed the absence of pH stabilization in H3 during the first month. Also, in this period we observed a faster degradation of some easily available organic matter in H3 than in the other heaps. After 120 d, a better cellulose decomposition (25.28%) was noticed in H3 than in H1 and H2 (16%). Inoculation during the second fermentation phase induced supplementary lignin degradation in H2 with a percentage of 35% against 23 and 26% for H1 and H3, respectively. For all the runs, a Fourier Transform Infrared analysis showed aliphatic groups' decrease, OH groups' increase and lignin structural modification.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.6
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• pp.705-712
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• 2001

It is of great importance to represent the directional ocean waves in a laboratory basin for hydraulic model tests. The directional ocean waves can be expressed as a linear superposition of a large number of component waves with different frequencies and propagating directions. The aim of the study is to check the wave generating characteristics by serpent-type wave generating system in PKNU (Pukyong National University) which is composed of 10 piston-type wave generators. In the experiment, spatial variation of irregular wave heights and propagating angles are measured in the multi-directional wave maker basin. Target wave directional spectrum is reproduced in the area of multi-directional wave maker basin. The directional spreading of the generated waves varied spacially in the basin. They differed from target spectrum as the measurement point becomes far from the center line normal to the generator face, The effective generation area where that target can be reproduced is limited to the triangular area attached the generator face. According to the results, it is emphasized that the effective experiment area in the basin considered wave generator characteristics should be determined in consideration of experimental conditions including structural shapes, water depth, wave directionality etc.

• Korean Journal of Food Science and Technology
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• v.27 no.4
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• pp.571-575
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• 1995

Transition temperature$(T_m)$ and $enthalpy({\Delta}H)$ were examined by means of DSC to obtain basic information on heat stability of skin tissue collagen. From DSC properties of insoluble collagen on hydration time and moisture content, it was found that moisture content had more effect on structural stability of collagen than hydration time. As moisture content increased, $({\Delta}H)$ increased while $(T_m)$ decreased. DSC properties of acetone dried skin on the variation of age and sex showed higher heat stability in case of male rat and heat stability seemed to be connected with age, as $(T_m)$ and $({\Delta}H)$increased with age. Meanwhile, DSC properties of salt soluble collagen showed higher values in female rat than in male rat, and the $(T_m)$ and $({\Delta}H)$ decreased significantly with age in female rat. These results seemed to suggest indirectly that collagen structure varied with age or sex in the same tissue.