• Title/Summary/Keyword: Structural variation

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The Effects of Deposition Conditions on Deposition Rate and Crystallinity of ZnO Thin Films Deposited by PECVD (PECVD를 이용한 ZnO박막 증착시 증착 변수가 증착속도 및 결정 구조에 미치는 영향)

  • Kim, Yeong-Jin;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.90-96
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    • 1994
  • ZnO thin films were deposited using Diethylzinc and $N_{2}O$ gas by plasma enhanced CVD (PECVD) at low substrate temperatures below $300^{\circ}C$. The effect of deposition parameters on the growth rate and the structural properties was determined at various deposition conditions. Crystallized ZnO thin films were successfully deposited even at $150^{\circ}C$ of substrate temperature. Above $200^{\circ}C$ c-axis oriented ZnO thin films, of which a standard deviation of X-ray rocking curve was less than $6^{\circ}$. were deposited on glass substrates. The variation of deposition rate showed different trends depending on substrate temperature and rf-input power. According to the deposition rate behavior as a function of substrate temperature, the transition points were observed resulting from crystallization of ZnO thin films. The activation energies for the deposition of ZnO thin films were 3.1KJ/mol and 1.9KJ/mol for the rf powers of 200W and 250W, respectively.

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Structures and Formation Energies of LixC6 (x=1-3) and its Homologues for Lithium Rechargeable Batteries

  • Doh, Chil-Hoon;Han, Byung-Chan;Jin, Bong-Soo;Gu, Hal-Bon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.2045-2050
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    • 2011
  • Using first principles density functional theory the formation energies of various binary compounds of lithium graphite and its homologues were calculated. Lithium and graphite react to form $Li_1C_6$ (+141 mV) but not form $LiC_4$ (-143 mV), $LiC_3$ (-247 mV) and $LiC_2$ (-529 mV) because they are less stable than lithium metal itself. Properties of structure and reaction potentials of $C_5B$, $C_5N$ and $B_3N_3$ materials as iso-structural graphite were studied. Boron and nitrogen substituted graphite and boron-nitrogen material as a iso-electronic structured graphitic material have longer graphene layer spacing than that of graphite. The layer spacing of $Li_xC_6$, $Li_xC_5B$, $Li_xC_5N$ materials increased until to x=1, and then decreased until to x=2 and 3. Nevertheless $Li_xB_3N_3$ has opposite tendency of layer spacing variation. Among various lithium compositions of $Li_xC_5B$, $Li_xC_5N$ and $Li_xB_3N_3$, reaction potentials of $Li_xC_5B$ (x=1-3) and $Li_xC_5$ (x=1) from total energy analyses have positive values against lithium deposition.

DLC Structure Layer for Piezoelectric MEMS Switch (압전 MEMS 스위치 구현을 위한 DLC 구조층에 관한 연구)

  • Hwang, Hyun-Suk;Lee, Kyong-Gun;Yu, Young-Sik;Lim, Yun-Sik;Song, Woo-Chang
    • Journal of Satellite, Information and Communications
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    • v.6 no.1
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    • pp.28-31
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    • 2011
  • In this paper, a new set of structural and sacrificial material that is diamond like carbon (DLC)/photoresist for high performance piezoelectric RF-MEMS switches which are actuated in d33 mode is suggested. To avoid curing problem of photoresist sacrificial layer, DLC structure layer is deposited at room temperature by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) method. And lead zirconate titanate (PZT) piezoelectric layer is deposited on structure layer directly at room temperature by rf magnetron sputtering system and crystallized by rapid thermal annealing (RTA) equipment. Particular attention is paid to the annealing of PZT film in order to crystallize into perovskite and the variation of mechanical properties of DLC layer as a function of annealing temperature. The DLC layer shows good performance for structure layer in aspect to Young's modulus and hardness. The fabrication becomes much simpler and cheaper with use of a photoresist.

An Experimental Study on Structural Behaviour of Asymmetric H Beam Slim floor under Load Condition in Fire (내화 피복된 비대칭 H형강을 적용한 슬림플로어 보의 재하가열조건 화재거동에 관한 실험적 연구)

  • Kim, Hyung-Jun;Kim, Hyung-Jun;Min, Byung-Youl;Lee, Jae-Sung;Park, Soo-Yong
    • Fire Science and Engineering
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    • v.25 no.1
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    • pp.63-71
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    • 2011
  • When it comes to slim floor using asymmetric H-beam, it was designed that the steel member is embedded in concrete with relatively low thermal conductivity so as to minimize the deterioration of rigidity of steel member in fire. But given the bottom flange of asymmetric H-beam is directly exposed to the fire, the measure of applying the fireproof coating to improve the fire rate performance of slim floor beam was sought. The test was aimed at comparing the fireproof performance by adjusting the load ratio of 0.4 and 0.3, and The test was carried out to identify the 3-hour fire performance by reinforcing the beam as well as applying the fireproof coat, In the wake of comparing the specimen depending on variation of load ratio, lowering load ratio by 0.1 resulted in difference of 12 minutes and deflection was 39 mm. It was able to improve 12 minutes by reinforcing the beam and up to 102.4 mm in deflection.

Fabrication and Electrical Properties of Anodic Aluminum Oxide Membrane with Various Anodizing Temperatures for Biosensor (바이오센서로 응용을 위한 양극산화알루미늄의 양극산화 온도에 따른 제작 및 전기적 특성)

  • Yeo, Jin-Ho;Lee, Sung-Gap;Kim, Yong-Jun;Lee, Young-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.394-398
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    • 2014
  • We fabricated the electrolyte-dielectric-metal (EDM) sensor on the base of AAO (anodic aluminum oxide) template with variation of the anodizing temperature. When a surface is immersed or created in an aqueous solution, a discontinuity is formed at the interface where such physicochemical variables as electrical potential and electrolyte concentration change significantly from the aqueous phase to another phase. Because of the different chemical potentials between the two phases, charge separation often occurs at the interfacial region [1]. This interfacial region, togeter with the charged surface, is usually known as the electrical double layer (EDL) [2]. The structural and electrochemical properties of AAO sensor were investigated for applications in capacitive pH sensors. To change the thickness of the AAO template, the anodizing temperature was varied from $5^{\circ}C$ to $20^{\circ}C$, the thickness of the AAO template invreased from 300 nm to 477 nm. The pH sensitivity of sensors with the anodizing temperature of $20^{\circ}C$ showed the highest value of 56.4 mV/pH in the pH range of 3 to 11. The EDM sensor with the anodizing temperature of $20^{\circ}C$ exhibited the best long-term stability of 0.037 mV/h.

Study on the deposition Characteristics of Bi Thin Film (Bi 박막의 성막 특성에 관한 연구)

  • 최철호;임중관;박용필;이화갑
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.05a
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    • pp.615-618
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    • 2003
  • This paper presents Bi thin films have been fabricated by atomic layer-by-layer deposition and co-deposition at an IBS method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(l00) was used as a substrate. In order to appreciate stable existing region of Bi 2212 phase with temperature and ozone pressure, the substrate temperature was varied between 655 and 820 $^{\circ}C$ and the highly condensed ozone gas pressure(PO$_3$) in vacuum chamber was varied between 2.0$\times$10$^{-6}$ and 2.3$\times$10$^{-5}$ Torr. Bi 2212 phase appeared in the temperature range of 750 and 795$^{\circ}C$ and single phase of Bi 2201 existed in the lower region than 785 $^{\circ}C$. Whereas, PO$_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with T$_{c}$(onset) of about 90 K and T$_{c}$(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as CaCuO$_2$ was observed in all of the obtained films.lms.

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Current Control of Switched Reluctance Motor Using Self-tuning Fuzzy Controller (자기동조 퍼지 제어기를 이용한 스위치드 릴럭턴스 모터의 전류제어)

  • Lee, Young-Soo;Kim, Jaehyuck;Oh, Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.473-479
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    • 2016
  • This paper describes an accurate and stable current control method of switched reluctance motors(SRMs), which have recently attracted considerable wide attention owing to their favorable features, such as high performance, high durability, structural simplicity, low cost, etc. In most cases, the PI controllers(PICC) have been used mostly for the current control of electric motors because their algorithm and selection of controller gain are relatively simpler compared to other controllers. On the other hand, the PI controller requires an adjustment of the controller gains for each operating point when nonlinear system parameters change rapidly. This paper presents a stable current control method of an SRM using self-tuning fuzzy current controller(STFCC) under nonlinear parameter variation. The performance of the considered method is validated via a dynamic simulation of the current controlled SRM drive using Matlab/Simulink program.

A Study on Freezing Characteristics of Pavements Using Data of Test Road (시험도로 자료를 이용한 포장의 동결특성 연구)

  • Jeong, Jin-Hoon;Bae, Sung-Ho;Kwon, Soon-Min
    • International Journal of Highway Engineering
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    • v.7 no.2 s.24
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    • pp.87-95
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    • 2005
  • To prevent the lowering of structural capability due to freezing and thawing in cold winter, numerous researches on frost heaving have been performed. As the result, the freezing index contour map of the Korea peninsula has been made for the design of the anti-freezing layer of pavements. However, the validity of the anti-freezing layer needs to be evaluated because systematic investigations on the variation of freezing depth with the thickness and material types of pavement layers and the configuration of the ground have been rarely performed. The freezing index of the Korea Highway Corporation test road site was calculated and the freezing depths of the concrete and asphalt pavements of the test road were investigated using the ambient and pavement temperature and water content. In addition, the investigated freezing depths were compared to the values estimated by existing freezing depth models. This is the preliminary study on the freezing-related data measured at the test road. The results with higher reliability will be produced by the long-term accumulation of the data and the analysis on it.

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The Incremental Cost Matrix Procedure for Locating Repair Service Centers in Multinational Reverse Logistics

  • Chen, Hsin Min;Hsieh, Chih Kuang;Wu, Ming Cheng;Luo, Shin Wei
    • Industrial Engineering and Management Systems
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    • v.8 no.3
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    • pp.194-200
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    • 2009
  • This study provides a heuristic algorithm to solve the locating problem of repair service centers (RSCs). To enhance the customer service level with more satisfaction and quicker responsiveness, the locating problem of RSCs has become one of the important issues in reverse supply chain management. This problem is formulated as a zero-one mixed integer programming in which an exiting distributor will be considered to be an un-capacitated repair service center for the objective of cost-minimizing. Since logistical costs are highly interrelated with the multinational location of distributors and RSCs, the fixed cost for setting a repair service center, variable cost, transportation cost, and exchange rates are considered in this study. Recognizing the selection of un-capacitated RSCs' locations is a combinatorial optimization problem and is a zero-one mixed integer programming with NP-hard complexity, we provide a heuristic algorithm named as incremental cost matrix procedure (ICMP) to simplify the solving procedure. By using the concise and structural cost matrix, ICMP can efficiently screen the potential location with cost advantage and effectively decide which distributor should be a RSC. Results obtained from the numerical experiments conducted in small scale problem have shown the fact that ICMP is an effective and efficient heuristic algorithm for solving the RSCs locating problem. In the future, using the extended ICMP to solve problems with larger industrial scale or problems with congestion effects caused by the variation of customer demand and the restriction of the RSC capacity is worth a further investigation.

Impact Characteristics of CFRP Structural Member according to the Variation of Stacking Condition and Impact Energy (적층구성과 충돌에너지의 변화에 따른 CFRP 구조부재의 충격특성)

  • Yeo, In-Goo;Choi, Ju-Ho;Choi, Yeong-Min;Yang, Yong-Jun;Hwang, Woo-Chae;Yang, In-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.6
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    • pp.976-981
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    • 2013
  • This aims to examine experimentally the absorption behavior and strength of circular CFRP members with different stacking configurations on exposure to a separate impact velocity. In addition, considered the dynamic characteristics. Circular and square CFRP members were prepared from 8-ply unidirectional prepreg sheets stacked at different angles ($0^{\circ}/90^{\circ}$ and $90^{\circ}/0^{\circ}$, where the $0^{\circ}$ direction coincides with the axis of the member) and interface numbers (2, 4, and 6). Based on the collapse characteristics of the circular CFRP members. In this study, for the circular members, the impact energies at crosshead speeds of 5.52 m/s, 5.14 m/s, and 4.57 m/s are 611.52 J, 529.2 J, and 419.44 J (at circular members), respectively. Likewise, for the square members, the impact energies at crosshead speeds of 2.16 m/s, 1.85 m/s, and 1.67 m/s are 372.4 J, 274.4 J, and 223.44 J (at square members).