• Journal of the Korean Magnetic Resonance Society
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• v.19 no.3
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• pp.119-123
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• 2015

The thermodynamic properties and structural geometry of $KMgCl_3{\cdot}6H_2O$ were investigated using thermogravimetric analysis, differential scanning calorimetry, and nuclear magnetic resonance. The initial mass loss occurs around 351 K ($=T_d$), which is interpreted as the onset of partial thermal decomposition. Phase transition temperatures were found at 435 K ($=T_{C1}$) and 481 K ($=T_{C2}$). The temperature dependences of the spin-lattice relaxation time $T_1$ for the $^1H$ nucleus changes abruptly near $T_{C1}$. These changes are associated with changes in the geometry of the arrangement of octahedral water molecules.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.441-446
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• 2001

In the integral type reactor, SMART, all the major components such as steam generators, pressurizer and pumps are located inside the single reactor pressure vessel. The objective of this study is to evaluate the structural integrity for RPV of SMART under the postulated pressurized thermal shock by applying the finite element analysis. Input data for the finite element analysis were generated using the commercial code I-DEAS, and the fracture mechanics analysis was performed using the ABAQUS. The crack configurations, the crack aspect ratio and the clad thickness were considered in the parametric study. The effects of these parameters on the reference nil-ductility transition temperature were also investigated.

• Journal of Sericultural and Entomological Science
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• v.42 no.2
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• pp.114-119
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• 2000

Effects of ethanlo treatment on the structural and thermal characteristics of regenerated Antheraea pernyi silk fibroin (RSF) were investigated. Infrared spectroscopy and X-ray diffractometry showed that the conformational transition of RSF might be affected by concentration of ethanol and its treatment time. The structure of RSF was rapidly changed from random coil to $\beta$-sheet conformation when RSF was treated with les than 75% ethanol concentration. However, RSF treated with ethanol(100%) did not show conformational change. Differential scanning calorimetry showed that exotherm at 232$\^{C}$ disappeared and the intensity of endotherm at 228$\^{C}$ decreased with treatment of 75% ethanol. Dynamic thermal analysis showed that loss modulus (E") and tan $\delta$$\_$E/ of RSF treated with aqueous ethanol was broaden and shifted to higher temperature in comparison with those of untreated RSF.

• Computational Structural Engineering
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• v.11 no.1
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• pp.153-160
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• 1998

A small break loss of coolant accident is postulated as a pressurized thermal shock accident in this study. From the temperature and pressure histories of coolant, distributions of the temperature and stress in a vessel wall are analytically calculated. The stress intensity factor and fracture toughness of the vessel wall are determined at the crack tip using the ASME code method and they are compared to check if cracking is expected to occur during the transient postulated. The maximum allowable reference nil-ductility transition temperatures are determined for various crack sizes and the results are discussed.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2003.10a
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• pp.37-44
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• 2003

In this proposed work, computational, finite element model far multi-delaminated plates will be developed. In the current analysis procedures of multi-delaminated plates, different elements are used at delaminated and undelaminated region separately. In the undelaminated region, plate element based on Mindlin plate theory is used in order to obtain accurate results of out-of-plane displacement of thick plate. And for delaminated region, plate element based on Kirchhoff plate theory is considered. To satisfy the displacement continuity conditions, displacement vector based on Kirchhoff theory is transformed to displacement of transition element. Element mass and stiffness matrices of each region (delaminated, undelaminated and transition region) will be assembled for global matrix.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.461-461
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• 2000

We have investigated electronic structuresof antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site Coulomb interaction. Co^{2+} and Co^{3+} ions are found to be in the high spin (HS) and intermediate spin (IS) state, respectively. The tetragonal to orthorhombic structural transition is responsible for the ordering phenomena and the spin states of Co ions. The large contribution of the orbital moment to the total magnetic moment indicates that the effect of the spin-orbit coupling is very important in YBaCo_2O_5.

• Journal of the Korean Vacuum Society
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• v.5 no.1
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• pp.48-53
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• 1996

We present a microscopic description for generation of 1/f noise in interfaces between cobalt thin film and silicon substrate. Along with surface resistance measurements and transmission electron diffraction observations. 1/f noise power spectral density has been measured for the interfacial structures at the liquid nitrogen temperature . The cobalt films have been deposited by the electron-beam evaporation technique onto p-type (100) silicon in the high vacuum condition. The measured noise power spectral density shows highest magnitude near the structural transition and metallization transition region. The noise magnitude rapidly decreased after the cobalt silicide nucleation. The noise parameter is concluded to be originated form the structural fluctuations.

• Bulletin of the Korean Chemical Society
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• v.14 no.2
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• pp.255-258
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• 1993

Molecular dynamics (MD) calculations were carried out in order to investigate the effect of MD cell size to predict the melting phenomena of A-type zeolite. We studied two model systems: a pseudocell of $(T_2O_4Na)_n$, (L= 12.264 $^{\AA}$, N= 84) and a true-cell of (SiAlO$_4Na)_n$. (L= 24.528 $^{\AA}$, N= 672), where T is Si or Al. The radial and bond angle distribution functions of T(Si, Al)-O-T(Si, Al) and diffusion coefficients of T and O were reported at various temperatures. For the true-cell model, the melting temperature is below 1500 K and probably around 1000 K, which is about 600-700 K lower than the pseudocell model. Although it took more time (about 30 times longer) to obtain the molecular trajectories of the true-cell model than those of the pseudocell model, the true-cell model gave more realistic structural transition for the A-type zeolite, which agrees with experiment.

• Journal of Ceramic Processing Research
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• v.23 no.3
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• pp.243-246
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• 2022

We report the synthesis of Sn-modified LiNi0.9Co0.05Mn0.05O2 cathode via a co-precipitation method. The key factor to enhancethe electrochemical performances of lithium ion batteries is to suppress the structural reconstruction because of the irreversibilityof the H2-H3 phase transition, resulting in rapid performance decay. The as-prepared Sn-modified LiNi0.9Co0.05Mn0.05O2 cathodedelivers an initial discharge capacity of 221.4 mAh g-1 with a high coulombic efficiency of 88.5 %. Moreover, it shows betterpolarization of 0.33 V and superior cycle stability of 98.8% after 58 cycles. These values are obviously higher than those ofpristine LiNi0.9Co0.05Mn0.05O2 cathode. Therefore, we can believe that Sn-modified LiNi0.9Co0.05Mn0.05O2 cathode is one of theeffective way for high-performance cathode material in lithium ion batteries.

• Tribology and Lubricants
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• v.5 no.2
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• pp.83-86
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• 1989

A wear transition mechanism during sliding in glass has been observed. Disk specimens of sodalime-silicate glass were slid against AISI 52100 steel with paraffin oil as lubricant. Observations of the micrrx structural change on the worn surface showed that semi-circular cone cracks (SCCCs) were suddenly produced after a certain critical sliding time. These SCCCs brought about the severe damage in the form of extensive microchipping during further sliding. It was shown that the abrupt appearance of the SCCCs is attributable to the grooves formed during sliding, which act as surface flaws.