• Journal of Electrochemical Science and Technology
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• v.4 no.1
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• pp.34-40
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• 2013

The structural and electrochemical properties of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ ($Fd{\bar{3}}m$, disordered spinel) cathode material were studied and compared with stoichiometric $LiNi_{0.5}Mn_{1.5}O_4$ ($P4_332$, ordered spinel). First cycle discharge capacity of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ was similar to that of $LiNi_{0.5}Mn_{1.5}O_4$ at C/3 and 1C rate, but cycling performance of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ was better than that of $LiNi_{0.5}Mn_{1.5}O_4$ especially at high rate of 1C. This can be explained by performing synchrotron based in-situ XRD and results of GITT measurements. It is considered that faster lithium ion diffusion in the $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ cathode results in the improvement of the rate capability. To study structural changes during cycling, synchrotron in-situ XRD patterns of both the samples were recorded at C/3 and 1C rate. Compared to stoichiometric $LiNi_{0.5}Mn_{1.5}O_4$, disordered $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ spinel sample has pseudo one phase behavior and one step phase transition between two cubic phases. So, $LiNi_{0.5}Mn_{1.5}O_4$ would experience a much greater strain and stress, originating from the two phase transitions between three cubic phases and suffer from capacity loss during cycling especially at high rate.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.4
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• pp.1123-1132
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• 1996

It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.2_2
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• pp.333-340
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• 2023

Environmental regulations are being strengthened worldwide to solve global warming. For this reason, interest in eco-friendly gas fuels such as LNG and hydrogen is continuously increasing. However, when adopting eco-friendly gas fuel, liquefying at a cryogenic temperature is essential to ensure economic feasibility in storage and transportation. Although austenitic stainless steel is typically applied to store cryogenic liquefied gas, structural steel can experience sudden heat shrinkage in the case of leakage in the loading and unloading process of LNG. In severe cases, the phase of the steel may change, so care is required. This study conducted Charpy impact tests on steel material in nine different temperature ranges, from room to cryogenic temperatures, to analyze the effects of cryogenic liquefied gas leaks. As a result of the study, it was not easy to find variations in ductile to brittle transition temperature (DBTT) due to the leakage of cryogenic liquefied gas. Still, the overall impact toughness tended to decrease, and these results were verified through fracture surface analysis. In summary, brittle fracture of the steel plate may occur when a secondary load is applied to steel for hull structural use exposed to a cryogenic environment of -40 ℃ or lower. Therefore, it needs to be considered in the ship design and operating conditions.

• Asian Journal of Innovation and Policy
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• v.1 no.2
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• pp.200-218
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• 2012

Estimating the economic life of a technology is the first important prerequisite step in the feasibility analysis of technology-based business. Many empirical studies have concentrated on patents data to estimate the time period for a technology. However, it is recommended to estimate it along with qualitative considerations of future technological and market conditions. In this regard, little is known about how approaches are applied. This paper aims to establish a structural framework of estimating the lifetime of a technology by integrating the outputs of an analysis of the determinants in each transition of a product life cycle. We describe an illustrative case about a light emitting diode (LED) backlight unit (BLU) technology for the liquid crystal display (LCD) TV. The framework allows valuators and experts to estimate a technology lifetime by using multidimensional factors.

• Structural Engineering and Mechanics
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• v.11 no.3
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• pp.287-299
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• 2001

Columns in multi-storey frames are presently categorised as either braced or unbraced, usually by means of the stability index criterion, for estimating their effective length ratios by design aids such as 'alignment charts'. This procedure, however, ignores the transition in buckling behaviour between the braced condition and the unbraced one. Hence, this results in either an overestimation or an underestimation of effective length estimates of columns in frames that are in fact 'partially braced'. It is shown in this paper that the transitional behaviour is gradual, and can be approximately modelled by means of a 'fuzzy logic' based technique. The proposed technique is simple and intuitively agreeable. It fills the existing gap between the braced and unbraced conditions in present codal provisions.

• Structural Engineering and Mechanics
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• v.14 no.6
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• pp.699-712
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• 2002

In this paper, a new quadrilateral 5-node non-conforming membrane element with drilling degrees of freedom is presented. The main advantage of these elements is the relatively small number of integration points to evaluate a stiffness matrix comparing to the existing transition membrane elements (CLM elements). Moreover, the presented elements pass the patch test by virtue of the Direct Modification Method incorporated into the element formulation. The presented 5-node elements are proved to be very efficient when used in the local mesh refinement for the in-plane structures which have stress concentrations. And some numerical studies also show the good performance of the new element developed in this study.

• Structural Engineering and Mechanics
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• v.66 no.5
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• pp.621-629
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• 2018

By employing the nonlocal continuum field theory of Eringen and Von Karman nonlinear strains, this paper presents an analytical model for linear and nonlinear dynamics analysis of single-walled carbon nanotubes (SWNTs) conveying fluid with different boundary conditions. In the linear analysis the natural frequencies and critical flow velocities of SWNTs are computed. However, in the nonlinear analysis the effect of nonlocal parameter on nonlinear dynamics of cantilevered SWNTs conveying fluid is investigated by using bifurcation diagram, phase plane and Poincare map. Numerical results confirm existence of chaos as well as a period-doubling transition to chaos.

• STI Policy Review
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• v.1 no.4
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• pp.29-39
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• 2010

Science, technology, society and humanities (STSH) fusion research is aimed at creating new research areas and methods that can resolve complicated issues in society that cannot be solved by a single academic discipline. This study identifies initiatives that can promote STSH fusion research in Korea. We review the definition and characteristics of STSH fusion research to analyze the necessity of STSH fusion research with a focus on the structural changes in the S&T environment. The emergence and diffusion of generic technologies, transition to post catch-up innovation mode, and the evolution of policy to the third generation innovation policy are identified as notable changes. This paper briefly reviews the status of fusion research underway and presents initiatives to promote STSH fusion research.

• Journal of Mechanical Science and Technology
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• v.18 no.9
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• pp.1512-1518
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• 2004

Rescaled Simulated Annealing (RSA) has been adapted to solve combinatorial optimization problems in which the available computational resources are limited. Simulated Annealing (SA) is one of the most popular combinatorial optimization algorithms because of its convenience of use and because of the good asymptotic results of convergence to optimal solutions. However, SA is too slow to converge in many problems. RSA was introduced by extending the Metropolis procedure in SA. The extension rescales the state's energy candidate for a transition before applying the Metropolis criterion. The rescaling process accelerates convergence to the optimal solutions by reducing transitions from high energy local minima. In this paper, structural optimization examples using RSA are provided. Truss structures of which design variables are discrete or continuous are optimized with stress and displacement constraints. The optimization results by RSA are compared with the results from classical SA. The comparison shows that the numbers of optimization iterations can be effectively reduced using RSA.

• Economic and Environmental Geology
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• v.53 no.5
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• pp.631-643
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• 2020

The central-western Korean Peninsula contains records of an Early Mesozoic collisional event related to the final amalgamation of the East Asian continent. Here, we present a renewed geologic map of the Deokjeok and Soya islands in the central-western Korean Peninsula and its explanatory note. Our geologic map was based on a detailed investigation of the northeastern area of both islands, which is characterized by a complex fault and shear zone system that accommodated the crustal deformation related to the Mesozoic post-collisional orogenic collapse and the subsequent structural inversion. We suggest future directions of study aiming at addressing issues regarding the deformational responses of crust to the Mesozoic tectonic transition and orogenic cycles.