• Title/Summary/Keyword: Structural Transition

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Properties Changes of Cokes and Forming Bodies Derived from Them during Artificial Graphite Manufacturing (인조흑연 제조공정중의 코크스와 그 성형체의 물성변화)

  • Gwon, Yeong-Bae;Kim, Hong
    • 한국기계연구소 소보
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    • s.20
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    • pp.105-114
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    • 1990
  • The relationship between the properties of two kinds of calcined cokes and graphitized forming bodies were examined. The microstructures of the forming bodies are already determined to some degree at the stage of baking. Calcined cokes as well as baked forming bodies using the same coke as filler were heat treated at various temperatures and their structural and properties changes with heat treated temperature were studied. The transition in properties changes with heat treatment in forming bodies were observed around $2000^{\circ}C$. The characteristics of the finial graphite bodies are strongly dependent on the properties of the raw material cokes.

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The Structural Features and Rotational Barriers in Indenyl Allyl Metal Complexes

  • Sungkwon Kang
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.554-559
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    • 1989
  • The electronic structure, conformational preferences, and rotational barriers have been studied for transition metal indenyl allyl complexes by means of extended Huckel calculations. After geometrical optimization the exo conformation of allyl moiety is favored over the endo. The rotational barrier of indenyl ring in (Indenyl)Mo(CO)_2(Allyl)$ is computed to be 3.8 kcal/mol. Population analysis is applied to account for the conformational preferences and rotational barriers. A series of substituted allyl complexes has been also optimized. It shows steric hindrance plays a crucial role in setting the allyl orientation.

Digital Technologies in the Innovative and Structural Transformation of Low- and Middle-Income Economies

  • Tetiana Kulinich;Yuliia Lisnievska;Yuliia Zimbalevska;Tetiana Trubnik;Svitlana Obikhod
    • International Journal of Computer Science & Network Security
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    • v.24 no.1
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    • pp.178-186
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    • 2024
  • While in high-income countries the development of digital technology began in the 1970s, in low- and middle-income countries it began in the 1990s and even after 2005, due to the political regime that constrained economic development and innovation. At the same time, there are no studies of the relationship between technological development and structural changes through innovation in low- and middle-income countries. The article aims to quantify the relationship of the introduction of digital technologies on innovation, structural transformation of low- and middle-income economies. The industrial-agrarian economy of Uzbekistan with an authoritarian regime is in a state of transition to a market economy, while in Ukraine, there are active processes of Europeanization and integration into the EU. Ukraine's economy is commodity-based (the export of raw materials of industries and the agricultural sector in developed countries predominates) and industrial-agrarian. Digital technologies and the service sector are little developed in Uzbekistan. On the other hand, Ukraine has a more developed ICT sector. Uzbekistan is gradually undergoing an innovative and structural transformation of the economy: the productivity of the agricultural, industrial, and service sectors is growing, but the ICT sector is virtually undeveloped. In comparison, in Ukraine, there are no significant structural transformations due to a significant drop in productivity of the industrial sector, with stable growth of productivity of the agricultural sector due to technology and a slight increase in productivity of the service sector. It is revealed that Ukraine and Uzbekistan have undergone structural transformations of the economy in favor of the service sector, while the agricultural and industrial sectors produce less and less. If Uzbekistan remains the industrial-agrarian country with an aggregate share of the added value of these sectors 59% in 2019, Ukraine transits to the post-industrial type of economy where the added value of the service sector in GDP grows (55% compared to agrarian and industrial sectors at 42%).

Periodic Lateralized Epileptiform Discharges Are lctal Phenomena, and Need an Antiepileptic Treatment (주기편측간질모양방전은 발작현상으로서 항경련제 치료가 필요하다)

  • Kim, Jae-Moon
    • Annals of Clinical Neurophysiology
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    • v.13 no.1
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    • pp.21-25
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    • 2011
  • Periodic lateralized epileptiform discharges (PLEDs) had been debated whether it is ictal or non-ictal phenomenon. As most of PLEDs occur in patients with acute structural lesions, some epileptologists prefer PLEDS as a non-ictal phenomenon, rather an obscure epiphenomenon of etiological diseases. But, almost half of the patients with PLEDs do not have acute structural lesions in the brain and metabolic disorders or old CNS lesions may cause PLEDs and even more, no brain lesion was identified in some patients. There are many data supporting PLEDs as ictal phenomena. Occurrence of PLEDs usually accompanied by decreased mentality and is improved as PLEDs disappeared. Current SPECT study showed marked hyperperfusion in the lesion side of PLEDs, that is striking evidence of PLEDs as ictal phenomena. Also careful review of EEG with PLEDs revealed it is a dynamic process rather than a static state. Despite of these evidences, as PLEDs are an end-stage of animal status epilepticus models, it may be a transition of ictal to interictal state.

Free Vibration Analysis of Multi-delaminated Composite Plates (다층간분리된 적층판의 자유진동해석)

  • Taehyo Park;Seokoh Ma;Yunju Byun
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.25-32
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    • 2004
  • In this proposed work new finite element model for multi-delaminated plates is proposed. In the current analysis procedures of multi-delaminated plates, plate element based on Mindlin plate theory is used in order to obtain accurate results of out-of-plane displacement of thick plate. And for delaminated region, plate element based on Kirchhoff plate theory is considered. To satisfy the displacement continuity conditions, displacement vector based on Kirchhoff theory is transformed to displacement of transition element. The numerical results show that the effect of delaminations on the modal parameters of delaminated composites plates is dependent not only on the size, the location and the number of the delaminations but also on the mode number and boundary conditions. Kirchhoff based model have higher natural frequency than Mindlin based model and natural frequency of the presented model is closed to Mindlin based model.

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Combined Extended and Superimposed Finite Element Method for Crack Analysis (균열해석을 위한 겹침확장 유한요소법)

  • 이상호;송정훈;허문석
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.341-348
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    • 2004
  • This paper presents a modeling technique of cracks by combined extended and superposed finite element method (XSFEM) which is a combination of the extended finite element method (XFEM) and the mesh superposition method (sversion FEM). In the proposed method, the near-tip field is modeled by a superimposed patch consisting of quarter point elements and the rest of the discontinuity is treated by the XFEM. The actual crack opening in this method is measured by the sum of the crack openings of XFEM and SFEM in transition region. This method retains the strong point of the XFEM so it can avoid remeshing in crack evolution and trace the crack growth by translation or rotation of the overlaid mesh and the update of the nodes to be enriched by step functions. Moreover, the quadrature of the Galerkin weak form becomes simpler. Numerical experiments are provided to demonstrate the effectiveness and robustness of the proposed method.

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Pressurized Thermal Shock Analyses of Reactor Pressure Vessel for Main Steam Line Break (주증기관 파단사고에 대한 원자로 용기의 가압열충격 해석)

  • 정명조;박윤원;장창희;정일석
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.3
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    • pp.271-279
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    • 1999
  • 본 연구에서는 국내에서 가장 취약할 것으로 예상되는 원자력 발전소에 가압열충격 사고를 유발할 수 있는 주증기관 파단사고를 가정하여 열수력 해석과 파괴역학 해석을 수행하였다. 원전수명관리연구의 일환으로 계통열수력 해석 및 혼합열유동 해석에 의하여 구한 냉각제의 온도와 압력의 이력 및 용기의 재질성분으로부터 용기의 응력확대계수와 파괴인성치를 계산하고 이들을 비교하여 균열의 진전여부를 판단하여 형상계수가 1/6인 표면균열이 견딜 수 있는 최대 기준무연성천이온도를 결정하였다.

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Effective Nonlinear Analysis of Coupled Wall Structures using Multi-Level Substructuring (다중분할구조기법을 이용한 병렬전단벽의 효율적인 비선형 해석)

  • 김호수;홍성목;윤성준
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1994.04a
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    • pp.65-72
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    • 1994
  • This study presents the application of multi-level substructuring for the effective nonlinear analysis of coupled wall structures. Also, the transition elements with 8 or 12 d. o. f, 5-node plane stress elements and concrete nonlinear model are considered as the basic finite elements of substructuring. In particular, the concept of localized nonlinearity is considered for the probable nonlinear zones of the structure, and the effective bottom-up and top-down process are presented through connectivity trees. The nonlinear analysis based on localized nonlinearity and multi-level substructuring, compared with the complete nonlinear analysis of the structure, gives the greater saving effects in computational efforts and cost.

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Some Observations on the Structural Developments of Bubbly Flow : Channel Size Effect

  • Song, Chul-Hwa;Chun, Se-Young;Chung, Moon-Ki;No, Hee-Cheon
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.321-326
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    • 1995
  • The present study provides some experimental observations on the structural developments of bubbly flow and the void wave damping in vertical, circular channel with a large diameter, and discusses the channel size effect on them. It is observed that the developing mode of bubbly flow structures and its transition mechanism are influenced by the channel size as well as the bubble size, and that they are well revealed in the behavior of wave damping.

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Study on nuclear magnetic resonance of superionic conductor NH4HSeO4 in rotating frame

  • Choi, Jae Hun;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.1
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    • pp.41-46
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    • 2014
  • In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.