• Bulletin of the Korean Chemical Society
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• v.22 no.1
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• pp.63-67
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• 2001

The photophysical properties and the singlet oxygen generation efficiency of tetrathiarubyrin have been investigated to elucidate the possibility of its use as a photodynamic therapy (PDT) photosensitizer by steady-state and time-resolved spectroscopic methods. The observed photophysical properties were affected by various molecular aspects, such as extended ${\pi}conjugation$, structural distortion, and internal heavy atom. The steady-state electronic absorption spectrum was red-shifted due to the extended $\pi-conjugation$, and the spin orbital coupling was enhanced by the structural distortion and the internal heavy atom effect. As a result of the enhanced spin orbital coupling, the triplet quantum yield increased to 0.90 $\pm$ 0.10 and the triplet state lifetime was shortened to 7.0 $\pm$ 1.2 ${\mu}s$. Since the triplet state decays at a relatively faster rate, the efficiency of the oxygen quenching of the triplet state decreases. The singlet oxygen quantum yield was estimated to be 0.52 $\pm$ 0.02, which is somewhat lower than expected. On the other hand, the efficiency of singlet oxygen generation during the oxygen quenching of triplet state, $f{\Delta}^T$, is near unity. Such high efficiency of singlet oxygen generation can be explained by the following two possible factors: The hydrogen bonding of ethanol which impedes the deactivation pathway of the charge transfer complex with oxygen to the ground state, the less probability of the aggregation formation.

• International Journal of Aeronautical and Space Sciences
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• v.16 no.2
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• pp.223-246
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• 2015

Structural vibration control using a piezoelectric shunt is an established control technique. This technique involves connecting a piezoelectric patch, which is bonded onto or embedded into the vibrating structure, to an electric shunt circuit. Thus, vibration energy is converted into electrical energy and is dissipated through a network of electrical components. Different configurations of shunt have been researched, among which the negative capacitance-inductance shunt has gained prominence recently. It is basically an analog, active circuit consisting of operational amplifiers and passive elements to introduce real and imaginary impedance on the vibrating structure. The present study attempts to model the behavior of a negative capacitance-inductance shunt in terms of power output and efficiency using circuit modeling software. The shunt model is validated experimentally and is used to control the structural vibration of an aluminum beam, connected to a pair of piezoelectric patches, under broadband excitation. The model is also used to determine the optimal parameters of a negative capacitance-inductance shunt to increase the efficiency and predict the voltage output limit of op-amp against the supply voltage.

• Structural Monitoring and Maintenance
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• v.7 no.3
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• pp.261-281
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• 2020

Civil structures may experience progressive deterioration and damage under environmental and operational conditions over their service life. Finite element (FE) model updating method is one of the most important approaches for damage identification in structures due to its capabilities in structural health monitoring. Although various damage detection approaches have been investigated on structures, there are limited studies on large-sized space structures. Thus, this paper aims to investigate the applicability and efficiency of sensitivity-based FE model updating framework for damage identification in large space structures from a distinct point of view. This framework facilitates modeling and model updating in large and geometric complicated space structures. Considering sensitivity-based FE model updating and vibration measurements, the discrepancy between acceleration response data in real damaged structure and hypothetical damaged structure have been minimized through adjusting the updating parameters. The feasibility and efficiency of the above-mentioned approach for damage identification has finally been demonstrated with two numerical examples: a flat double layer grid and a double layer diamatic dome. According to the results, this method can detect, localize, and quantify damages in large-scaled space structures very accurately which is robust to noisy data. Also, requiring a remarkably small number of iterations to converge, typically less than four, demonstrates the computational efficiency of this method.

• Steel and Composite Structures
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• v.10 no.3
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• pp.261-279
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• 2010

Generally, a box tube, which is used for an existing square CFT structure, is made by welding four plates. The manufacturing efficiency of this steel tube is poor, and it also needs special welding technology to weld its internal diaphragm and the through diaphragm. Therefore, an interior-anchor-type square steel tube was developed using the method of cold-forming thin plates to prevent welding of the stress concentration position, and to maximize the section efficiency. And, considering of the flow of beam flange load, the efficiency of erection and the weldability of the diaphragm to thin walled steel column, the external diaphragm connection was selected as the suitable type for the welded built-up square CFT column to beam connection. And, an analytical study and tests were conducted to evaluate the structural performance of the suggested connection details and to verify the suggested equations for the connection details. Through this study, the composite effect of the internal anchor to concrete, the resistance and stress distribution of the connections before and after the existing column is welded to the beam, the effective location of welding in connection were analyzed.

• Archives of Pharmacal Research
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• v.14 no.4
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• pp.336-341
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• 1991

The effect of bovine serum albumin (BSA) on the encapsulation efficiency and stability of liposomes containing methotrexate (MTX) having different surface charges and cholesterol contents were investigated. The encapsulation efficiency of MTX was lower and the release of MTX was faster by the addition of BSA. The leaking of MTX from lipid bilayer depends upon the BSA concentrations. These results may be derived from the interaction of BSA with lipid bilayers. The dynamic structural changes of BSA were monitored indirectly using circular dichroism spectra. Observed dynamic structural changes of BSA with liposomes are presumed to reflect the interaction of BSA with liposomes. Negatively charged liposomes have more strong interaction with BSA than neutral and positively charged liposomes. BSA attacks lipid bilayers whether it is at the inner or at the outer phase of lipid bilayer and induces leakage of entrapped MTX. Especially, negatively charged liposomes are more sensitive than others. The inclusion of cholesterol in the lipid layers inhibits the interaction of BSA with liposomes and shows protective effect against BSA-induced leakage of MTX. To endure the attacking of BSA liposomes as drug carriers should be made using cholesterol.

• Journal of Aerospace System Engineering
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• v.6 no.4
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• pp.7-11
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• 2012

Recently, the renewable energy has been widely used as a wind energy and solar energy resource due to lack and environmental issues of the mostly used fossil fuel. In this situation, the interest in wind power has been risen as an important energy source. For this blade a high efficiency wind turbine blade was designed with the proposing aerodynamic design procedure, and a light and low cost composite structure blade was designed considering fatigue life. Structural analyses including load case study, stress, deformation, buckling, fatigue life and vibration analysis were performed using the Finite Element Method.

• Proceedings of the KSR Conference
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• 2010.06a
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• pp.432-436
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• 2010

This paper investigates the productivity growth in Korean railway lines. The productivity growth is calculated by a process of measuring of pure efficiency change index(PECI), scale efficiency change index(SECI), and technical change index(TCI), using Data envelopment analysis (DEA) method. The data cover the period 1990~2007; 1990~2003 are the pre-structural reform years and the post-structural reform years are 2005~2007. The framework for the analysis is Malmquist Productivity Index (MPI) of the to investigate the impacts of structural reform on productivity growth, respectively. The inputs considered are the length of operating line, the number of staff, the number of coach and wagon, and the outputs are the trains movement of passenger and freight, and the traffic of passenger and freight.

• Structural Engineering and Mechanics
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• v.81 no.3
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• pp.367-378
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• 2022

In this study, combined size and shape optimization of spatial truss tower structures are presented by using new optimization algorithms named Rao-1, and Rao-2. The nodal displacements, allowable stress and buckling for compressive members are taken into account as structural constraints for truss towers. The discrete and continuous design variables are used as design variables for size and shape optimization. To show the efficiency of the proposed optimization algorithm, 25-bar, and 39-bar 3D truss towers are solved for combined size and shape optimization. The 72-bar, and 160-bar 3D truss towers are solved only by size optimization. The optimal results obtained from this study are compared to those given in the literature to illustrate the efficiency and robustness of the proposed algorithm. The structural analysis and the optimization process are coded in MATLAB programming.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1998.10a
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• pp.53-60
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• 1998

Efficiency of design process for large scale structures highly depends on the development of efficient structural analysis and structural response control algorithms because a successful design involves a number of structural analysis based on iterative structural response control process. In this paper, distributed structural analysis model on multiple personal computers connected by ethernet network is presented. To reduce communication cost required in the process of analysis, substructuring techniques are adopted to evenly distribute computational loads on each processor. With its applications on structural analysis of plane frame structures, performance of the proposed computational model are presented in detail.

• Structural Engineering and Mechanics
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• v.91 no.4
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• pp.393-401
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• 2024

This study explores the integration of the generative AI, specifically ChatGPT (GPT-4o), into the field of structural analysis and design using the finite element method (FEM). The research is conducted in two main parts: structural analysis and structural design. For structural analysis, two scenarios are examined: one where the FEM source code is provided to ChatGPT and one where it is not. The AI's ability to understand, process, and accurately perform finite element analysis in both scenarios is evaluated. Additionally, the application of ChatGPT in structural design is investigated, including design modifications and parameter sensitivity analysis. The results demonstrate the potential of the generative AI to assist in complex engineering tasks, suggesting a future where AI significantly enhances efficiency and innovation in structural engineering. However, the study also highlights the importance of ensuring the accuracy and reliability of AI-generated results, particularly in safety-critical applications.