• Bulletin of the Korean Chemical Society
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• 제16권7호
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• pp.634-641
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• 1995

The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

• 전기전자학회논문지
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• 제23권2호
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• pp.534-537
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• 2019

광학적 손실은 태양전지 표면에 조사되는 빛이 태양전지 내부로 흡수되지 않고 표면에서 반사되어 발생하는 손실이다. 이러한 빛의 반사로 인한 광학적 손실을 줄이고 태양전지의 변환 효율을 높이기 위한 연구가 활발하게 진행되고 있다. 본 논문에서는 유리기판 표면을 습식 식각을 사용하여 표면을 거칠게 형성해 식각된 표면의 구조적 특성을 평가하였고, 분광기를 통해 식각된 표면의 광학적 특성을 분석하였다. 식각을 통해 형성되는 분화구 모양의 거친 표면은 입사되는 빛을 태양전지 내부로 재흡수하여 빛의 반사를 줄어들었고, 이에 따라 투과되는 빛이 증가하였음을 확인하였다.

• 센서학회지
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• 제28권1호
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• pp.36-40
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• 2019

Energy harvesting is an advantageous technology for wireless sensor networks (WSNs) that dispenses with the need for periodic replacement of batteries. WSNs are composed of numerous sensors for the collection of data and communication; hence, they are important in the Internet of Things (IoT). However, due to low power generation and energy conversion efficiency, harvesting technologies have so far been utilized in limited applications. In this study, a piezoelectric energy harvester was modeled in a vibration environment. This harvester has an oval-shaped configuration as compared to the conventional cantilever-type piezoelectric energy harvester. An analytical model based on an equivalent circuit was developed to appraise the advantages of the oval-shaped piezoelectric energy harvester in which several structural parameters were optimized for higher output performance in given vibration environments. As a result, an oval-shaped energy harvester with an average output power of 2.58 mW at 0.5 g and 60 Hz vibration conditions was developed. These technical approaches provided an opportunity to appreciate the significance of autonomous sensor networks.

• Nuclear Engineering and Technology
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• 제53권3호
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• pp.967-973
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• 2021

In 2011, an earthquake and subsequent tsunami hit the Fukushima Daiichi Nuclear Power Plant, causing simultaneous accidents in several reactors. This accident shows us that if there are several reactors on site, the seismic risk to multiple units is important to consider, in addition to that to single units in isolation. When a seismic event occurs, a seismic-failure correlation exists between the nuclear power plant's structures, systems, and components (SSCs) due to their seismic-response and seismic-capacity correlations. Therefore, it is necessary to evaluate the multi-unit seismic risk by considering the SSCs' seismic-failure-correlation effect. In this study, a methodology is proposed to obtain the seismic-response-correlation coefficient between SSCs to calculate the risk to multi-unit facilities. This coefficient is calculated from a probabilistic multi-unit seismic-response analysis. The seismic-response and seismic-failure-correlation coefficients of the emergency diesel generators installed within the units are successfully derived via the proposed method. In addition, the distribution of the seismic-response-correlation coefficient was observed as a function of the distance between SSCs of various dynamic characteristics. It is demonstrated that the proposed methodology can reasonably derive the seismic-response-correlation coefficient between SSCs, which is the input data for multi-unit seismic probabilistic safety assessment.

• 한국표면공학회지
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• 제55권2호
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• pp.63-69
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• 2022

Preparing various types of thin films of oxide semiconductors is a promising approach to fabricate efficient photoanodes and photocathodes for hydrogen production via photoelectrochemical (PEC) water splitting. In this work, we investigate the feasibility of an efficient photocathode for PEC water reduction of a p-type oxide semiconductor cupric oxide (CuO) thin film prepared via a facile method combined with sputtering Cu metallic film on fluorine-doped thin oxide (FTO) coated glass substrate and subsequent thermal oxidation of the sputtered Cu metallic film in dry air. Characterization of the structural, optical, and PEC properties of the CuO thin film prepared at various Cu sputtering powers reveals that we can obtain an optimum CuO thin film as an efficient PEC photocathode at a Cu sputtering power of 60 W. The photocurrent density and the optimal photocurrent conversion efficiency for the optimum CuO thin film photocathode are found to be -0.3 mA/cm² and 0.09% at 0.35 V vs. RHE, respectively. These results provide a promising route to fabricating earth-abundant copper-oxide-based photoelectrode for sunlight-driven hydrogen generation using a facile method.

• Smart Structures and Systems
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• 제32권6호
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• pp.383-391
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• 2023

Energy harvesting in trams may become a prevalent source of passive energy generation due to the high density of vibrational energy, and this may help power structural health monitoring systems for the trams. This paper presents a broadband vibrational energy harvesting device design that utilizes a varied frequency from a tram vehicle using a 2 DOF vibrational system combined with electromagnetic energy conversion. This paper will demonstrate stepwise optimization processes to determine mechanical parameters for frequency tuning to adjust to the trams' operational conditions, and electromagnetic parameters for the whole system design to maximize power output. The initial optimization will determine 5 important design parameters in a 2 DOF vibrational system, namely the masses (m₁, m₂ (and spring constants (k₁, k₂, k₃). The second step will use these parameters as initial guesses for the second optimization which will maintain the ratios of these parameters and present electrical parameters to maximize the power output from this system. The obtained values indicated a successful demonstration of design optimization as the average power generated increased from 1.475 mW to 17.44 mW (around 12 times).

• Current Photovoltaic Research
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• 제11권4호
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• pp.103-107
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• 2023

A Nickel oxide (NiO_x) thin films were prepared via sol-gel process on a transparent conductive oxide glass substrate. The NiO_x thin films were spin-coated in ambient air and subsequently annealed for 30 minutes at temperatures ranging from 150℃ to 450℃. The structural and optical characteristics of the NiO_x thin films annealed at various temperatures were measured using X-ray diffraction, field emission scanning electron microscopy, and ultraviolet-visible spectroscopy. After optimizing the NiO_x coating conditions, perovskite solar cells were fabricated with p-i-n inverted structure, and its photovoltaic performance was evaluated. NiO_x thin films annealed at 350℃ exhibited the most favorable characteristics as a hole transport layer, resulting in the highest power conversion efficiency of 17.88 % when fabricating inverted perovskite solar cells using this film.

• Smart Structures and Systems
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• 제33권1호
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• pp.41-53
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• 2024

Grouting sleeves are an essential connecting component of prefabricated components, and the quality of grouting has a significant influence on structural integrity and seismic performance. The embedded grouting sleeve (EGS)'s grouting defects are highly undetectable and random, and no effective monitoring method exists. This paper proposes an ultrasonic guided wave method and provides a set of guidelines for selecting the optimal frequency and suitable period for the EGS. The optimal frequency was determined by considering the group velocity, wave structure, and wave attenuation of the selected mode. Guided waves are prone to multi-modality, modal conversion, energy leakage, and dispersion in the EGS, which is a multi-layer structure. Therefore, a time-reversal (TR)-based multi-mode focusing and dispersion automatic compensation technology is introduced to eliminate the multi-mode phase difference in the EGS. First, the influence of defects on guided waves is analyzed according to the TR coefficient. Second, two major types of damage indicators, namely, the time domain and the wavelet packet energy, are constructed according to the influence method. The constructed wavelet packet energy indicator is more sensitive to the changes of defecting than the conventional time-domain similarity indicator. Both numerical and experimental results show that the proposed method is feasible and beneficial for the detection and quantitative estimation of the grouting defects of the EGS.

• 한국지식정보기술학회논문지
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• 제13권1호
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• pp.11-23
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• 2018

본 연구에서는 스마트폰의 확산에 가장 주요한 요인이며 다양한 기능성 편의를 제공하는 앱을 구매하는 채널인 앱 마켓을 선택하는 요인을 합리적인 선택 이론 관점을 도입하여 실증적으로 밝혀내었다. 281건의 설문 결과 분석을 통해, 이익의 관점에서 사용편의성과 구조적 보장이 앱 마켓 선택에 유의미한 영향을 주는 것으로 검증 되었다. 반면, 고객신뢰, 정보 품질, 마켓 이미지는 앱마켓 선택에 유의미한 영향을 주지 못하는 것으로 파악되었다. 특히, 국내 앱마켓 플랫폼 제공자(KT, LG U+)의 경우, 해외 앱마켓 플랫폼사업자(구글)에 비해, 고객센터 운용, 피해보상 규정 등 구조적 보장 측면에서 우위에 있는 것으로 보인다. 하지만, 구글 앱 마켓의 경우는 모든 안드로이드 폰에 사전 설치되어 통신사 별로 타 앱마켓을 이용하기 위해 추가적으로 설치해야하는 불편함이 없어 국내 제공자보다 사용자 편의성에서 우위에 있다고 판단된다. 이는 국내 앱마켓 플랫폼사업자에게만 불리하게 작용하고 있어, 정책적 해결점 마련이 필요하다. 사업자비용의 관점에서는 금전적인 전환 비용과 비금전적인 전환 비용 모두 앱 마켓 선택에 유의미한 영향을 주는 것으로 나타났다. 특히, 비금전적인 전환 비용은 국내 앱마켓 플랫폼사업자에게 부정적인 영향을 주는 것으로 나타났다. 이는 국내 앱마켓의 서비스 기대 수준이 낮다고 인식되어 있고, 신규 사용자가 사용하기 위해 회원 가입 등 소요되는 시간적 비용요소가 크다고 인지되어 있다고 설명될 수 있다. 국내 앱 마켓 사업의 활성화를 위해 개선이 필요한 항목으로 보인다. 본 연구를 통해 기존 대부분의 연구들이 앱 선택 요인에만 집중되었다는 한계를 극복하고 앱 마켓 선택 요인을 밝혀내었다는데 본 연구의 의의가 있다고 볼 수 있겠다.

• 한국콘텐츠학회:학술대회논문집
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• 한국콘텐츠학회 2006년도 추계 종합학술대회 논문집
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• pp.555-559
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• 2006

본 논문은 HWP, DOC와 같은 워드 문서를 대상으로 사용자가 작성한 구조적인 규칙과 XML 기반 워드 문서 변환 기법을 이용함으로써, 사용자의 관심 영역에 해당하는 다양한 형태(표, 리스트 등)의 정보를 효과적으로 추출(변환)하여 저장하기 위한 방법에 관한 것이다. 본 논문에서 제시한 시스템은 3가지의 중요한 요소들로 구성되어 있는데, 1)워드문서의 원시 XML문서로의 변환방법, 2)XML 기반 구조적인 규칙 작성과 규칙을 이용하여 원시 XML 문서에서 정보를 추출(변환)하는 방법, 3)추출 된 정보에서 최종 XML을 생성하거나 DB에 저장하는 방법이 그것이다. 워드문서의 변환을 위해서 독립적으로 동작하는 OCX 기반의 워드문서 변환 데몬(daemon)을 개발하였고, 사용자의 정보 추출(변환)과정을 돕기 위해서 XSLT를 확장한 형태의 스크립트 언어를 개발하였다. 스크립트 언어는 비교적 간단한 문법 구조를 가지고 있고, 데이터 처리를 위한 자체 정의 함수와 변수를 사용한다. 추출된 정보는 원하는 형태의 구조적인 문서로 생성하거나 DB에 저장할 수 있다. 개발한 시스템(PPE)은 워드 문서 원문 정보에 대한 데이터베이스 구축 및 서비스의 제공, 혹은 구축된 데이터베이스를 이용하여 다양한 처리를 하거나 현황 통계를 제공하는 분야에서 유용하게 사용할 수 있다. 실제로 연구과제관리 시스템과 성과정보시스템에 시범 적용하였다.