• Title/Summary/Keyword: Strontium oxide

Search Result 55, Processing Time 0.023 seconds

Study of Properties of High-K Strontium Oxide Alignment Layer Using Solution Process for Low Power Mobile Information Device (저전력 휴대용 통신단말을 위한 Solution Process를 이용한 고 유전율 Strontium Oxide 배향막의 특성 연구)

  • Han, Jeong-Min;Kim, Won-Bae
    • Journal of Satellite, Information and Communications
    • /
    • v.10 no.2
    • /
    • pp.90-94
    • /
    • 2015
  • We stuidied liauid crystal alignment treatment using solution process for making thin oxide layer in liquid crystal display. It is the one of very effient and popular process in making thin oxide layer in electronical industrial fields. Particularly, this process has highly potential value in liquid crystal display industrial fields because it cause automatically induced alignment process without tranditional alignment process in liquid crystal alignment process. We made several different kinds of mol density solutions using strontium oxide solution. And those solutions were treated for solidification layers using annealing process for 2 hours. And we stuided pretilt angle properties of these alignment layers of strontium oxide for clarifying the relationship of liquid crystal molecules and thin strontium oxide layer. And we also tested the existence of strontium oxide thin layer on substrate using XPS measurement. We expected the hig gain of electro-optical properties in liquid crystal display using strontium oxide thin layer because it has high K property material than the other metal-based oxide layers. In this results, we measured 1.447 to 1.613 thresholds volts as 0.1 mol to 0.4 mol density in 0.1 mol density steps. This is significant better characteristics than conventional liquid crystal display as higher than 1.85 thresholds volts. And it make possible to making next-generation liquid crystal display which present low-power consumption and wide gray scale in liquid crystal display.

Adsorption characteristics of strontium onto K2Ti4O9 and PP-g-AA nonwoven fabric

  • Lee, Tae hun;Na, Choon-Ki;Park, Hyunju
    • Environmental Engineering Research
    • /
    • v.23 no.3
    • /
    • pp.330-338
    • /
    • 2018
  • This study investigated the possibility of using potassium titanate oxide ($K_2Ti_4O_9$) and acrylic acid-grafted polypropylene fabric (PP-g-AA) as adsorbents capable of removing strontium from aqueous solutions. $K_2Ti_4O_9$ showed the highest rate of strontium removal in the weak alkaline range, while the PP-g-AA increased strontium removal in the neutral range. Moreover, the adsorption capacity of the $K_2Ti_4O_9$ was not affected by the coexistence of K and Na ions, while the adsorption capacity decreased when Ca and Mg ions were present at the same concentration as that of strontium. When coexisted at the same concentration as strontium, Na, K, Ca, and Mg ions strongly reduced the adsorption capacity of the PP-g-AA. The results also indicated that the adsorption of strontium on $K_2Ti_4O_9$ was consistent with both the Langmuir and Freundlich adsorption isotherms. In contrast, the adsorption of strontium on the PP-g-AA was more consistent with the Langmuir isotherm model. Moreover, the adsorption equilibrium time of $K_2Ti_4O_9$ was generally 12 h, while that of the PP-g-AA was 5 h, indicating that the adsorption rates were consistent with the pseudo-second order kinetics model. $K_2Ti_4O_9$ and the PP-g-AA could be regenerated by simple washing with 0.5 N HCl.

Crystal Defect Chemistry of Strontium Hexaaluminate Magnetoplumbite

  • Park, Jae-Gwan;A.N. Cormack
    • Korean Journal of Crystallography
    • /
    • v.11 no.3
    • /
    • pp.176-181
    • /
    • 2000
  • Computer-based atomistic simulation methods are applied to address quantitatively the crystal defect chemistry of strontium hexaaluminate, SrAl/sub 12/O/sub 19/. Our calculations show that oxygen Frenkel disorder is the dominant intrinsic defect mode to be expected in the multi-component oxide, though Schottky disorder may also exist. When La and Mg enter into SrAl/sub 12/O/sub 19/. Mg prefers to occupy Al(3)4f tetrahedral sites in the magnetoplumbite structure. Our calculations also indicate that O/sub Sr/ defect is improbable in the structure.

  • PDF

Thermodynamic Calculations on the Chemical Behavior of SrO During Electrolytic Oxide Reduction

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.18 no.3
    • /
    • pp.415-420
    • /
    • 2020
  • Strontium is known as a salt-soluble element during the electrolytic oxide reduction (EOR) process. The chemical behavior of SrO during EOR was investigated via thermodynamic calculations to provide quantitative data on the chemical status of Sr. To achieve this, thermodynamic calculations were conducted using HSC chemistry software for various EOR conditions. It was revealed that SrO reacts with LiCl salt to produce SrCl2, even in the presence of Li2O, and that the ratio of SrCl2 depends on the initial concentration of Li2O dissolved in LiCl. It was found that SrO reacts with Li to produce Sr during EOR and that the reduced Sr reacts with LiCl salt to produce SrCl2. As a result, the proportions of metallic forms were lower in Sr than in La and Nd under various EOR conditions. The thermodynamic calculations indicated that the three chemical forms of SrO, SrCl2, and Sr co-exist in the EOR system under an equilibrium with Li, Li2O, and LiCl.

Sintering Behavior and Electrical Properties of Strontium Titanate-Based Ceramic Interconnect Materials for Solid Oxide Fuel Cells (고체산화물 연료전지용 Strontium Titanate 세라믹 접속자 소재의 소결 거동 및 전기적 특성)

  • Park, Beom-Kyeong;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.11a
    • /
    • pp.80.1-80.1
    • /
    • 2010
  • A strontium titanate ($SrTiO_3$)-based material with a perovskite structure is considered to be one of the promising alternatives to $LaCrO_3$-based materials since $SrTiO_3$ perovskite shows a high chemical stability under both oxidizing and reducing atmospheres at high temperatures. $SrTiO_3$ materials exhibit an n-type semiconducting behavior when it is donor-doped and/or exposed to a reducing atmosphere. In this work, $Sr_{1-x}La_xTi_{1-y}M_yO_3$ materials doped with $La^{3+}$ in A-sites and aliovalent transition metal ions ($M^{n+}$) in B-sites were synthesized by the modified Pechini method. The X-ray diffraction analysis indicated that the materials synthesized by the Pechini process exhibited a single curbic perovskite-type structure without any impurity phases, and are tolerant, to some extent, to cation doping. The sintering behaviors of $Sr_{1-x}La_xTi_{1-y}M_yO_3$ in $H_2/N_2$ and air were characterized by dilatometry and microstructural observations. The electrical conduction mechanism and the dopant effect are discussed based on the defect structures and the electrical conductivities measured at various oxygen partial pressures and temperatures.

  • PDF

Low temperature sintering and dielectric properties of $Sr_2(Ta_{1-x}Nb_x)_2O_7$ ceramics by the flux method (용융염합성법에 의한 $Sr_2(Ta_{1-x}Nb_x)_2O_7$ 세라믹스의 저온소성과 유전특성)

  • 남효덕
    • Electrical & Electronic Materials
    • /
    • v.8 no.2
    • /
    • pp.158-164
    • /
    • 1995
  • Solid solutions Sr$_{2}$(Ta$_{1-x}$ Nb$_{x}$)$_{2}$O$_{7}$, (x=0.0-1.0), composed of strontium tantalate(Tc=-107.deg. C) and strontium-niobate(Tc=1342.deg. C) were prepared by the conventional mixed oxide method and the flux method(molten salt synthesis method). Phase relation, sintering temperature, grain-orientation and dielectric properties for sintered ceramic samples were investigated with different compositions. Both Curie temperature and dielectric constant at Curie temperature were increased, and sintering behavior and the degree of grain-orientation were improved with the increase of Nb content. The single phase Sr$_{2}$(Ta/sib 1-x/Nb$_{x}$)$_{2}$O$_{7}$ powder was synthesized by using the flux method at lower temperatures, and sintering temperature was also reduced by using the flux method-derived powder than using the mixed oxide-derived powder. Sintering characteristics and dielectric properties of the specimens prepared by the flux method were better than those derived through the conventional mixed oxide method.thod.hod.

  • PDF

Characterization and Electrochemical Performance of Composite BSCF Cathode for Intermediate-temperature Solid Oxide Fuel Cell

  • Kim, Yu-Mi;Kim-Lohsoontorn, Pattaraporn;Bae, Joong-Myeon
    • Journal of Electrochemical Science and Technology
    • /
    • v.2 no.1
    • /
    • pp.32-38
    • /
    • 2011
  • The composite barium strontium cobalt ferrite (BSCF) cathodes were investigated in the intermediate temperature range of solid oxide fuel cells (SOFCs). The characteristics and electrochemical performances of composited BSCF/samarium doped ceria (SDC); BSCF/gadolinium doped ceria (GDC); and BSCF/SDC/GDC were compared to single BSCF cathode. The BSCF used in this study were synthesized using glycine nitrate process and mechanically mixing was used to fabricate a composite cathode. Using a composite form, the thermal expansion coefficient (TEC) could be reduced and BSCF/SDC/GDC exhibited the lowest TEC value at $18.95{\times}10^{-6}K^{-1}$. The electrochemical performance from half cells and single cells exhibited nearly the same trend. All the composite cathodes gave higher electrochemical performance than the single BSCF cathode (0.22 $Wcm^{-2}$); however, when two kinds of electrolyte were used (BSCF/SDC/GDC, 0.36$Wcm^{-2}$), the electrochemical performance was lower than when the BSCF/SDC (0.45 $Wcm^{-2}$) or BSCF/GDC (0.45 $Wcm^{-2}$) was applied as cathode ($650^{\circ}C$, 97%$H_2$/3%$H_2O$ to the anode and ambient air to the cathode).

Low Temperature Sintering and Dielectric Properties of $Sr_2$($Ta_{1-x}$$Nb_{x}$)$_2$$O_{7}$ Ceramics ($Sr_2$($Ta_{1-x}$$Nb_{x}$)$_2$$O_{7}$ 세라믹스의 저온소성과 유전특성)

  • 남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1994.11a
    • /
    • pp.8-12
    • /
    • 1994
  • Solid solutions $Sr_2$($Ta_{1-x}$$Nb_{x}$)$_2$$O_{7}$ (x = 0.0 - 1.0) composed of strontium-tantalate (low Curie temperature) and strontium-niobate (high Curie temperature) were prepared by the conventional mixed oxide method and the molten salt synthesis method (flux method). Phase relation, sintering temperature, grain-orientation and dielectric properties were investigated for sintered ceramic samples with different compositions. Both Curie temperature and dielectric constant at Curie temperature were increased, and sintering behavior and the degree of grain-orientation were improved with the increase of Nb content. Single phase $Sr_2$$Nb_2$$O_{7}$ powder was synthesized by using flux method at lower temperatures, and sintering temperature was also reduced by using flux method derived powder than using mixed-oxide derived powder. Sintering characteristics and dielectric properties of specimens prepared by flux method were better than those derived through the conventional method.

Recent Advances in the Removal of Radioactive Wastes Containing 58Co and 90Sr from Aqueous Solutions Using Adsorption Technology

  • Alagumalai, Krishnapandi;Ha, Jeong Hyub;Choi, Suk Soon
    • Applied Chemistry for Engineering
    • /
    • v.33 no.4
    • /
    • pp.352-366
    • /
    • 2022
  • Nuclear power plant operations for electricity generation, rare-earth mining, nuclear medical research, and nuclear weapons reprocessing considerably increase radioactive waste, necessitating massive efforts to eradicate radioactive waste from aquatic environments. Cobalt (58Co) and strontium (90Sr) radioactive elements have been extensively employed in energy generation, nuclear weapon testing, and the manufacture of healthcare products. The erroneous discharge of these elements as pollutants into the aquatic system, radiation emissions, and long-term disposal is extremely detrimental to humans and aquatic biota. Numerous methods for treating radioactive waste-contaminated water have emerged, among which the adsorption process has been promoted for its efficacy in eliminating radioactive waste from aquatic habitats. The current review discusses the adsorptive removal of radioactive waste from aqueous solutions using low-cost adsorbents, such as graphene oxide, metal-organic frameworks, and inorganic metal oxides, as well as their composites. The chemical modification of adsorbents to increase their removal efficiency is also discussed. Finally, the current state of 58Co and 90Sr removal performances is summarized and the efficiencies of various adsorbents are compared.