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Effect of Surface Morphology on Dimerization of tert-Butyl Mercaptan on the Surface of Amorphous Aluminosilicate Impregnated with Mn and Cu

  • Kweon, Jeong-Eun;Joo, Hyun-ha;Park, Dong-Gon
    • Bulletin of the Korean Chemical Society
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    • v.27 no.1
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    • pp.53-58
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    • 2006
  • A powder of destructive adsorbent was prepared by impregnating Mn and Cu on the surface of amorphous aluminosilicate. It catalytically dimerized tert-butyl mercaptan into di-tert-butyl disulfide on its surface. Turnover of the dimerization was strongly dependent on the surface morphology of the adsorbent, which could be altered by modification of aluminosilicate support. During the process of impregnation, which involved heat treatment at 500 ${^{\circ}C}$, the shape of the pore was preserved, though large fraction of micropores were eliminated. The reactive sites on the surface were poisoned as dimerization products strongly adhered on them. Therefore, high surface area was not always desirable. When the surface was heavily populated with “inkbottled” pores with a narrow entrance in uniform size, heavy poisoning of the reactive sites turned the destructive adsorbents almost useless.

LASER-INDUCED IGNITION OF REACTIVE SOLIDS WITH ROUGH SURFACE

  • Jae-Ou Chae;Gregory N. Mokhin;Nam-Ki Kim
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1995.05a
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    • pp.157-168
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    • 1995
  • Ignition of a reactive solid with rough surface by constant heat flux is studied. The geometry of surface is represented by a protrusion in shape of cone of infinite length. Ignition time and ignition criterion versus apex angle are determined, with the use of heterogeneous model of ignition. To study the effect of geometry on ignition the results are compared with the known results for the one-dimensional ignition of the semi-infinite body. It is shown, that: a) ignition time depends strongly upon the apex angle and is proportional to the angle to the second power; b) ignition criterion and ignition temperature do not depend strongly on angle. The ignition delay and the energy required for the successful ignition are substantially reduced compared to the one-dimensional case.

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Optimization of a telescope movable support structure by means of Volumetric Displacements

  • Ortega, Nestor F.;Robles, Sandra I.
    • Structural Engineering and Mechanics
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    • v.31 no.4
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    • pp.393-405
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    • 2009
  • The Purpose of this paper is to show the applicability of a methodology, developed by the authors, with which to perform the mechanical optimization of space truss structures strongly restricted. This methodology use a parameter call "Volumetric Displacement", as the Objective Function of the optimization process. This parameter considers altogether the structure weight and deformation whose effects are opposed. The Finite Element Method is employed to calculate the stress/strain state and the natural frequency of the structure through a structural linear static and natural frequency analysis. In order to show the potentially of this simple methodology, its application on a large diameter telescope structure (10 m) considering the strongly restriction that became of its use, is presented. This methodology, applied in previous works on continuous structures, such as shell roof and fluid storage vessels, is applied in this case to a space truss structure, with the purpose of generalize its applicability to different structural topology. This technique could be useful in the morphology design of deployable and retractable roof structures, whose use has extensively spread in the last years.

Inhibition of Calmodulin-Dependent Calcium-ATPase and Phosphodiesterase by Various Cyclopeptides and Peptide Alkaloids from the Zizyphus Species

  • Hwang, Keum-Hee;Han, Yong-Nam;Han, Byung-Hoon
    • Archives of Pharmacal Research
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    • v.24 no.3
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    • pp.202-206
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    • 2001
  • The effects of various sedative cyclopeptides and peptide alkaloids from the Zizyphus species on calmodulin-dependent $Ca^{2+}$ -ATPase and phosphodiesterase were Investigated. Calmodulin-induced activation of $Ca^{2+}$-ATPase was strongly inhibited by sanjoinine-A dialdehyde (IC_{50}$, 2.3$\mu\textrm{m}$), -Ah1 (IC_{50}$, 4.0$\mu\textrm{m}$), -A (IC, 4.6$\mu\textrm{m}$), and -G2 (IC_{50}$, 7.2$\mu\textrm{m}$), while calmodulin-induced activation of phosphodiesterase was strongly inhibited by both deachuine- S10 (IC_{50}$, 4.9$\mu\textrm{m}$) and sanjoinine-D (IC_{50}$, 9.0$\mu\textrm{m}$). The inhibitory activity of the various cyclopeptides and peptide alkaloids on $Ca^{2+}$-ATPase was found to correlate well with their Sedative activity.

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Gas transport properties of alumina composite membranes

  • Lee, Hong-Joo;Hiroyuki Yamauchi;Hiroyuki Suda;Kenji Haraya
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.128-131
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    • 2004
  • The composite mesoporous ceramic membranes were prepared with ${\gamma}$-alumina and poly (2, 6-dimethyl-l, 4-pyphenylene oxide) (PPO) on the surface of the macroporous $\alpha$-alumina ceramic membranes and the permeation results were compared with those of the $\alpha$-alumina membrane for large-scale applications. In the results of the transport experiments, the ceramic membranes gave high gas permeances mainly due to Knudsen diffusion and surface diffusion as an additional mechanism. And, the polymer modification increased the permeances of the strongly adsorbing gas components. In this study the modifications of alumina ceramic membranes could increase the gas permeation performances especially for the strongly absorbing gas components.

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Characteristics of Cadmium-Resistant Bacillus subtilis DT134 (Bacillus subtilis DT134의 카드뮴 저항성)

  • 윤경표
    • KSBB Journal
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    • v.13 no.4
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    • pp.383-390
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    • 1998
  • Bacillus subtilis DT134 was resistant to 50-fold higher concentration of cadmium ions (Cd2+) than cadmium-sensitive B. subtilis BD224 in Luria Broth (LB) medium. Minimal inhibition concentration test in LB agar plates also showed similar results. The elevated cadmium resistance of B. subtilis DT134 strongly suggested a possible existence of cadmium resistance gene in it. Southern blot with Staphylococcus aureus cadA gene fragment (757 bp NlaIV-XmnI cadA DNA fragment) as probe was carried out to test the existence and similarity of the gene. In high stringency condition, there was no detectable signal, but in low stringency, a strong signal specific to the cadA probe could be detected. These results strongly suggested that there was some similarity between total DNA of B. subtilis DT134 and S. aureus pl258 in terms of cadmium resistance gene and the resistance mechanism might be an efflux mechanism. The subsequent efflux experiment showed that the cadmium resistance mechanism of B. subtilis DT134 was also due to the efflux of cadmium.

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A Study on Peanut Spouts Extract as the Anti-oxidant Activity and the Skin Whitening Cosmetic Ingredients (항산화 및 미백화장품 원료로서의 땅콩새싹 추출물에 관한 연구)

  • Yoon, Mi Yun
    • KSBB Journal
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    • v.31 no.1
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    • pp.14-19
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    • 2016
  • To investigate the effect of peanut sprout extract on skin care, we measured anti-oxidant activity and whitening action. As a result of measuring DPPH radical scavenging activity to examine independent anti-oxidation of peanut sprout extract, there was strongly scavenging activity. Fluorescent material DCF-DA was used to measure hydrogen peroxide created in RAW 264.7 cells, and all concentration dependently decreased ROS production. As a result of measuring nitric oxide to examine anti-inflammation of peanut sprout extract, there was strongly inhibited nitric oxide production in RAW 264.7 cells. Tyrosinase activation was found to inhibited dose-dependant. Melanin production was also prevented dose-dependant. Therefore, it is expected to be used effectively in development of functional cosmetic materials.

Effects of Surface Order Parameter on Polar Anchoring Energy in NLC on Weakly Rubbed Polyimide Surface

  • Seo, Dae-Shik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1128-1132
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    • 1998
  • We have investigated the relationship between the polar anchoring energy and the surface order parameter in nematic liquid crystal (NLC), 4-n-pentyl-4-cyanobiphenyl (5CB), on the two kinds of the weakly rubbed polyimide (PI) surfaces. The observed polar anchoring energy of 5CB is approximately 2${\times}10^{-4}(J/m^2$) and then increases with increasing the rubbing strength (RS) on weakly rubbed surface (RS=57mm) with side chain at $30^{\circ}C$; same results are obtained on weakly rubbed PI surface without side chain. The surface order parameter of 5CB on rubbed PI surfaces increases with increasing the RS at a weak rubbing region. The surface order parameter of 5CB is strongly related to the characteristics of PI material. Consequently, we suggest that the polar anchoring energy of NLC is strongly attributed to the surface order parameter on rubbed PI surfaces.

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Magnetization Loss Characteristics of HTS Tapes in AC External Magnetic Fields Applied in Different Orientations (외부자계의 인가방향에 따른 HTS 선재의 자화손실 특성)

  • Park, Myung-Jin;Lim, Hyoung-Woo;Choi, Myeong-Seob;Cha, Guee-Soo;Lee, Ji-Kwang
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.961-963
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    • 2003
  • Magnetization losses of HTS depend strongly on the orientation of external magnetic field because of anisotropy characteristics. For parallel and perpendicular magnetic field, analytical models to calculate the loss are well known but there is no analytical model for magetic fields which are applied to surface of HTS with arbitrary angle. In this paper, magnetization losses are measured for various incidence angles($15^{\circ}$, $35^{\circ}$, $45^{\circ}$, $60^{\circ}$) and compared with parallel and perpendicular loss. As a result, magnetization losses in HTS are strongly affected by perpenducular magnetic field component of external magnetic field.

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Fault Hamiltonicity of Meshes with Two Wraparound Edges (두 개의 랩어라운드 에지를 갖는 메쉬의 고장 해밀톤 성질)

  • 박경욱;이형옥;임형석
    • Journal of KIISE:Computer Systems and Theory
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    • v.30 no.7_8
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    • pp.434-444
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    • 2003
  • In this paper, we consider the hamiltonian properties of m$\times$n (m$\geq$2, n$\geq$3) mesh networks with two wraparound edges on the first row and last row, called M$_2$(m, n), in the presence of a faulty node or link. We prove that M$_2$(m, n) with odd n is hamiltonian-connected and 1-fault hamiltonian. In addition, we prove that M$_2$(m, n) with even n is strongly hamiltonian laceable and 1-vertex fault tolerant strongly hamiltonian laceable.