• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.411.1-411.1
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• 2016

In this study, we examined the effects of boron doping on the dielectric reliability of solution processed aluminum oxide ($Al_2O_3$). When boron is doped in aluminum oxide, the hysteresis reliability is improved from 0.5 to 0.4 V in comparison with the undoped aluminum oxide. And the accumulation capacitance is increased when boron was doped, which implying the reduction of the thickness of dielectric film. The improved dielectric reliability of boron-doped aluminum oxide is originated from the small ionic radius of boron ion and the stronger bonding strength between boron and oxygen ions than that of between aluminum and oxygen ions. Strong boron-oxygen ion bonding in aluminum oxide results dielectric film denser and thinner. The leakage current of aluminum oxide also reduced when boron was doped in aluminum oxide.

• 한국세라믹학회지
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• 제40권4호
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• pp.380-384
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• 2003

The effects of the mole concentrations of precursor solution on the microstructure and dielectric properties of sol-gel deposited $Ba_{0.85}$S $r_{0.15}$Ti $O_3$(BST) thin films have been investigated. The films were of single perovskite phase with strong (100) preferred orientation when grown on LaNi0$_3$ buffered Pt/Ti/ $SiO_2$Si substrates using a diluted precursor solution. Variation of the precursor solution concentration resulted in a different microstructure and, in turn, affected the tunability of the sol-gel deposited films. It was observed that leakage currents increased asymmetrically for the negative and positive bias voltage with decreasing thickness. Overall results suggest that those BST films have acceptable properties f3r applications as room-temperature tunable elements.

• 한국전기전자재료학회논문지
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• 제21권7호
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• pp.599-602
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• 2008

Growth of well-aligned ZnO nanostructures on various substrates such as GaN, ITO/glass, and sapphire was realized via a simple aqueous solution method at low temperature of $90^{\circ}C$. Morphology of ZnO nanostructures grown on various substrates as function of substrate was studied. It was found that ZnO nanostructures is a strong function of substrate. It was clearly observed that the morphology of ZnO nanostructures could be varied by change of substrate. Morphology, crystallinity, and crystal characteristics were carried out by FE-SEM, synchrotron x-ray scattering measurements, and high-resolution electron microscopy, respectively.

• 한국의류산업학회지
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• 제7권6호
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• pp.641-649
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• 2005

This study is to make pH 9 reduction by adding NaOH to 1, 3, 5, 7, 9, 11% solution of thioglycollic acid, cysteine, cysteamin, to add it on helically winded natural hair and colored hair and leave them for 20, 40, 60 minutes, to add $NaBrO_3$ oxidant for 15 minutes and to compare and analyze the wave form. This study showed the results of permanent using thioglycollic acid, cysteine, cysteamin. In the permanent wave form according to the kind of reductant, concentration, and processing time, there were a little difference between thioglycollic acid and cysteine. But cysteamine not only showed apparent difference but also formed strong and elastic wave. The permanent wave is affected by the diagonosis of hair, the choice of permanent solution and the processing time. Therefore the scientific diagonosis of hair is to be considered first of all. By choosing the kind of solution, the concentration and the processing time according to the results of hair diagonosis and wave form, we can prevent the lengthening and damage of hair.

• Environmental Engineering Research
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• 제14권1호
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• pp.26-31
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• 2009

Sorption of $Ni^{2+}$ in aqueous solution was studied using montmorillonite. The experimental and equilibrium data fitted well to the Langmuir isotherm model. From the kinetics data for nickel sorption onto montmorillonite, the diffusion of $Ni^{2+}$ inside the clay particles was the dorminant step controlling the sorption rate and as such more important for $Ni^{2+}$ sorption than the external mass transfer. $Ni^{2+}$ was sorbed due to strong interactions with the active sites of the sorbent and the sorption process tends to follow the pseudo second-order kinetics. Thermodynamic parameters (${\Delta}G^{\circ},\;{\Delta}H^{\circ},\;{\Delta}S^{\circ}$) indicated a non spontaneous and endothermic adsorption process while the positive low value of the entropy change suggests low randomness of the solid/solution interface during the uptake of $Ni^{2+}$ by montmorilionite. Heavy metals such as $Ni^{2+}$ in aqueous bodies can effectively be sorbed by montmorillonite.

• 한국경영과학회지
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• 제22권3호
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• pp.11-22
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• 1997

The aim of this paper is to develop the B & B type algorithms for globally minimizing concave function under 0-1 knapsack constraint. The linear convex envelope underestimating the concave object function is introduced for the bounding operations which locate the vertices of the solution set. And the simplex containing the solution set is sequentially partitioned into the subsimplices over which the convex envelopes are calculated in the candidate problems. The adoption of cutting plane method enhances the efficiency of the algorithm. These mean valid inequalities with respect to the integer solution which eliminate the nonintegral points before the bounding operation. The implementations are effectively concretized in connection with the branching stategys.

• 한국연소학회지
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• 제13권1호
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• pp.17-22
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• 2008

A partly implicit/quasi-explicit method is introduced for the solution of detailed chemical kinetics with stiff source terms based on the standard fourth-order Runge-Kutta scheme. Present method solves implicitly only the stiff reaction rate equations, whereas the others explicitly. The stiff equations are selected based on the survey of the chemical Jaconian matrix and its Eigenvalues. As an application of the present method constant pressure combustion was analyzed by a detailed mechanism of hydrogen-air combustion with NOx chemistry. The sensitivity analysis reveals that only the 4 species in NOx chemistry has strong stiffness and should be solved implicitly among the 13 species. The implicit solution of the 4 species successfully predicts the entire process with same accuracy and efficiency at half the price.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3429-3432
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• 2011

Distribution diagram of $FeCl_2$ in HCl solution indicated that $FeCl^+$ was a predominant species in strong HCl solution up to 10 M. Solvent extraction of $FeCl_2$ has been performed in the HCl concentration range from 5 to 9 M by using Alamine336 as an extractant. Interaction parameter of $FeCl^+$ for Bromley equation was estimated from our solvent extraction data. This parameter thus obtained in our study can be employed in calculating the activity coefficient of $FeCl^+$ in high concentration of HCl.

• 대한화학회지
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• 제16권3호
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• pp.149-156
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• 1972

메타놀, N,N-디메칠포름아미드 및 아세토니트릴 속에서 유리전극의 pH 응답성을 여러가지 pH의 완충용액으로 시험한 바 전극을 물속에 보관하는 것보다 측정하고저 하는 용매속에 보관하는 것이 더 빨리 전위가 안정되었다. 같은 용매에서 용액의 염기성에 비례하여 응답속도가 느리고 강염기성 용액에서는 안정한 전위를 얻기 어려웠다. 산성용액에서의 pH 응답성은 보다 빠르나 같은 용액의 pH 측정에서도 전극의 사용한 이력에 따라 응답성과 측정치에 차이가 생겼다.

• 대한화학회지
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• 제7권4호
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• pp.225-229
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• 1963

The nature of the two isomers of 4-nitroazoxybenzenes in strongly acidic solution have been analyzed by U.V. spectrophotometry. Oxygen atom in the azoxy-group of $\alpha$-and $\beta$-4-nitroazoxybenzene in strong acid solution migrates neither to para position nor ortho position of the unsubstituted benzene ring of the compound in contrast with the cases of methyl-and bromo-substituted azoxybenzene, and shown no Wallach rearrangement. Since the $^1A{\rightarrow}^1H$ bands of the spectra shown hyperchromic effect whereas the ${\pi}{\rightarrow}{\pi}^*$ bands of them exhibit extream hypochromic effect, it appears most likely that trans ${\rightarrow}$cis isomerization take place in the media. A mechanism of a triangular transition state by which the transformation might be proceeded, is proposed.