• Title/Summary/Keyword: Strong solution

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Effects of solution, sorbate, and sorbent chemistries on polycyclic aromatic hydrocarbon sorption to hydrated mineral surfaces

  • Yim, Soobin
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.132-135
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    • 2003
  • Solution chemistry, sorbate chemistry, and sorbent chemistry were widely investigated to find important factors that affect PAH sorption on mineral surfaces and to elucidate its microscopic mechanism. The solution chemistry, pH and ionic strength caused measurable change of HOC sorption reaction to minerals. The detectable change of Ka occurred at a pH region crossing the PZC (Point of Zero Charge) of each mineral. The PAH hydrophobicity, one of sorbate chemistry, was observed to have a strong correlation with PAM sorption to mineral. Mineral surface area was not found to be a predominant factor controlling PAH sorption. The mineral type might be more likely to play a crucial role in controlling the PAH sorption behavior. The CEC (Cation Exchange Capacity) of mineral, representing surface charge density, has meaningful correlation with regression slope of sorption coefficients (log $K_{d}$) versus aqueous activity coefficients (log Υ$_{w}$).).).

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Three Dimmensional Turbulent Flow Analysis in a 90° Square Sectioned Duct with Strong Curvature (사각단면을 갖는 90° 급곡관의 3차원 난류유동 해석)

  • Maeng, J.S.;Lee, J.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.1
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    • pp.11-25
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    • 1991
  • The steady, incompressible developing 3-dimensional turblent flow in a square sectioned curved duct has been investigated by using partially-parabolic equation and Finite Analytic Method. The calculation of turbulent flow field is performed using 2-equation K-$\epsilon$ turbulence model, modified wall function, simpler algorithm and numerically generated body fitted coordinates. Iso-mean velocity contours at the various sections are compared with the existing experimental data and elliptic solutions by other authors. In the region of $0^{\circ}<{\theta}<71^{\circ}$, present results agree with the experimental data much better than the elliptic solution for the similar number of grid points. Furthermore, for the same tolerance, the present solution converges four times faster than the elliptic solution.

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Analysis and Optimization of a 2-Class-based Dedicated Storage System (2지역/지정위치 저장시스템의 분석과 최적화)

  • Yang, Moonhee
    • Journal of Korean Institute of Industrial Engineers
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    • v.29 no.3
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    • pp.222-229
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    • 2003
  • In this paper, we address a layout design problem, PTN[2], for determining an appropriate 2-class-based dedicated storage layout in a class of unit load storage systems. Our strong conjecture is that PTNI2] is NP-hard. Restricting PTN[2], we provide three solvable cases of PTN[2] in which an optimal solution to the solvable cases is one of the partitions based on the PAI(product activity index)-nonincreasing ordering. However, we show with a counterexample that a solution based on the PAI-non increasing ordering does not always give an optimal solution to PTN[2]. Utilizing the derived properties, we construct an effective heuristic algorithm for solving PTN[2] based on a PAI-non increasing ordering with performance ratio bound. Our algorithm with O($n^2$) is effective in the sense that it guarantees a better class-based storage layout than a randomized storage layout in terms of the expected single command travel time.

Etch Rate of Oxide Grown on Silicon Implanted with Different Ion Implantation Conditions prior to Oxidation

  • Joung, Yang-Hee;Kang, Seong-Jun
    • Journal of information and communication convergence engineering
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    • v.1 no.2
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    • pp.67-69
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    • 2003
  • The experimental studies for the etch properties of the oxide grown on silicon substrate, which is in diluted hydrogen fluoride (HF) solution, are presented. Using different ion implantation dosages, dopants and energies, silicon substrate was implanted. The wet etching in diluted HF solution is used as a mean of wafer cleaning at various steps of VLSI processing. It is shown that the wet etch rate of oxide grown on various implanted silicon substrates is a strong function of ion implantation dopants, dosages and energies. This phenomenon has never been reported before. This paper shows that the difference of wet etch rate of oxide by ion implantation conditions is attributed to the kinds and volumes of dopants which was diffused out into $SiO_2$ from implanted silicon during thermal oxidation.

Polarographic Behavior of Cadmium-Tartrate Complexes in Weak Acid and Alkaline Media

  • Lee, Kyung-Ae;Choi, Q.-Won;Ha, Young-Gu;Choy, Jin-Ho;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • v.10 no.5
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    • pp.414-418
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    • 1989
  • The electrochemical behavior of cadmium(Ⅱ) in tartrate solution has been studied over the pH range of 6 to 13.6 in order to explain the phenomena of the changes in limiting current depending on the pH. The polarographic limiting current showed a constant value up to pH of 7.8, after which it decreased sharply to show a minimum at pH between 11 and 12. The limiting current, then, increased again with increasing pH. The number of peaks in cyclic voltammogram was 1 to 3 depending on the pH of the solution. Two other voltammetric peaks could be observed when the main reduction peak diminished. The decrease of limiting current at 7.5$Cd(C_4H_3O_6)^-$. The increase of limiting current at strong alkaline solution, however, was due to the complex $Cd(Tart)_2(OH)_2^{4-}$.

Stainless Steel Surface Oxidized in Strong Oxidizing Solution

  • Kyoung-Chul Lee;Kyoung-Hee Ham;Woon-Sun Ahn
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.520-524
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    • 1991
  • Stainless steel 304 2B and BA are oxidized in 2.5 M $CrO_3/$ 5.0 M $H_2SO_4$ solution, and elemental composition and oxidized state of the surface region is analyzed as a function of the surface depth using X-ray photoelectron spectroscopy. It is found that Fe and Cr are preferentially oxidized and diffuse outward following the oxidation. Element Ni, the third major component of the steel is not oxidized and remains deep under the surface. It is also found that the oxidized Fe dissolves considerably into the solution thereby enriching the gas-oxide interface with Cr.

The Spectroscopic Studies on the Aggregation Behavior of Cyanine Dyes

  • 민형식;박정희;유종완;김동호
    • Bulletin of the Korean Chemical Society
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    • v.19 no.6
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    • pp.650-654
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    • 1998
  • Aggregations of 1,1'-diethyl-2,2'-carbocyanine iodide (DCI) and 1,1'-diethyl-2,2'-dicarbocyanine iodide (DDT) in aqueous solution have been investigated by the steady-state absorption spectroscopy. The equilibrium constants for dimerization of DCI and DDT are found to be $(9.8{\pm}0.5){\times}10^4 \;and\; (1.6{\pm}0.5){\times}10^5\; M^{-1}$, respectively, at 293 K. The enthalpy changes for the dimerization of DCI and DDT are -6.7±0.7 and -7.7±0.8 kcal/mol, respectively. The results show that the dispersion force plays an important role in the aggregation of DCI and DDT in aqueous solution. The absorption bandwidth of DCI/ethanol system has been measured as a function of temperature, providing the evidence for no strong interaction between DCI and solvent molecules. The participation of hydrophobic force in driving the aggregation is suggested. For the first time, DCI in aqueous solution is found to form a new aggregate which has both J- and H- bands.

A Novel Design of Cloud-based Management Solution for Android Containers

  • Xuan, Nam Pham Nguyen;Chun, Hojin;Jung, Souhwan
    • Journal of Internet Computing and Services
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    • v.20 no.1
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    • pp.67-75
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    • 2019
  • The Android container is used for various purposes such as Bring Your Own Device (BYOD) solution and Android malware analysis. The strong point of android container than other technologies is it can simulate an android device like a real android phone on a hardware layer. Therefore, automatic management solutions for android container are necessary. This paper introduces a new design of cloud-based management solution for android containers. Through the proposal, android containers are managed automatically from a cloud platform - OpenStack with various tasks like: container configuration, deployment, destroy, android version, hardware device. In addition, the system monitoring and system statistics for android containers and hardware devices are also provided.

Characteristics of Strong Alkaline Electrolyzed Water Produced in All-in-one Electrolytic Cell (일체형 전해조에서 생산된 강알카리성 전해수의 특성)

  • Lee, Ho Il;Rhee, Young Woo;Kang, Kyung Seok
    • Clean Technology
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    • v.18 no.4
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    • pp.446-450
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    • 2012
  • Strong alkaline electrolyzed water which is produced in cathode by electrolyzing the solution where electrolytes (NaCl, $K_2CO_3$ etc.) are added in diaphragm electrolytic cell, is eco-friendly and has cleaning effects. So, it is viewed as a substitution of chemical cleaner. In addition, strong alkaline electrolyzed water is being used by some Japanese automobile and precision parts manufacturing industries. When strong alkaline electrolyzed water is produced by using diaphragm electrolytic cell, it is necessarily produced at the anode side. Since strong acidic electrolyzed water produced is discarded when its utilization cannot be found, production efficiency of electrolyzed water is consequently decreased. Also, there is a weakness electrolytic efficiency is decreasing due to the pollution of diaphragm. In order to overcome this, non-diaphragm all-in-one electrolytic cell integrated with electrode reaction chamber and dilution chamber was applied. Strong alkaline electrolyzed water was produced for different composition of electrolytes, and their properties and characteristics were identified. In comparing the properties between strong alkaline electrolyzed water produced in diaphragm electrolytic cell and that produced in all-in-one electrolytic cell, the differences in ORP and chlorine concentration were found. In emulsification test to confirm surface-active capability, similar results were obtained and strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell was identified to be useable as a cleaner like strong alkaline electrolyzed water produced in diaphragm electrolytic cell. Strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell is thought to have sterilizing power because it has active chlorine which is different from strong alkaline electrolyzed water produced in diaphragm electrolytic cell.

Availability of Carboxylated Magnetic Beads for Extracting Heavy Metals from Aqueous Solution

  • So, Hyung-Suk;Yoo, Yeong-Seok;Schaeffer Andreas
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.98-102
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    • 2006
  • It was examined in this study that magnetic beads, which are assumed to be environmentally functional, could be effective in processing heavy metals that are water pollutants. For the purpose, magnetic beads containing carboxyl groups, which has strong binding force with heavy metals, are mixed with each Cd, Pb, Ni, Cu and Cr(III) solution, then stirred in pH 6. As a results of the process, it was proven that heavy metals bind quickly with magnetic beads through the reaction. In order to analyze heavy metal concentration, magnetic beads bind with heavy metal were collected by external magnetic force and dissolved in acid. The graphite furnace AAS was used to get heavy metal concentration melted in the acid solution. The results showed that heavy metal extractions by magnetic beads were influenced by the type and the concentration of a heavy metal, and over 90% of a heavy metal can be extracted in ppm level save for Cr(III). It was also examined in the study whether heavy metal extraction is influenced when other ions exist in each heavy metal solution. According to experiment, adding other heavy metals to a solution did have little influence on extracting an intended heavy metal. But in case salt or heavy metal chelate was added, Ni extraction changed sensitively although extracting other heavy metals were influenced only when the concentration of an added substance is high. In conclusion, it was shown that magnetic beads could be used to treat wastewater with relatively high heavy metal concentration.