• Resources Recycling
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• v.12 no.3
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• pp.31-37
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• 2003

A study on the characteristics of ammonia desorption from aqueous solutions has been performed by air stripping as the first stage of ammonia recycling for the preparation of ammonium sulfate from it. For air stripping experiments, a stripping column made with acrylic tube of 40 mm diameter was employed and compressed air was injected into solutions through air sparger equipped at the bottom of stripping column. As a result of experiments, the stripping efficiency was increased with the aqueous pH and it was found that the appropriate pH for air stripping of ammonia was between pH 10 and 12. As far as the effect of air flow rate on ammonia stripping was concerned, ammonia stripping was not proportional to the air flow rate although it was affected by the air flow rate to some extent. Moreover, when more than 20 cm of water height was maintained, total ammonia desorbed from solution was not varied with the water height. Stripping temperature was also found to play an important role in ammonia desorption and about 90fo of initial ammonia was desorbed in 14 hours at pH 12.8 and at $60^{\circ}C$ Finally, it was believed that stripping temperature as well as the aqueous pH was one of the most important factors in air stripping of ammonia.

• Resources Recycling
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• v.30 no.2
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• pp.39-45
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• 2021

Spent photovoltaic module is one of the important resource of silver, while related research concerning silver recovery remains limited. In our previous research, HNO3 was utilized to dissolve Ag(I) and Al(III) from the spent silicon solar cells. In order to recover Ag(I) from the leachate of a silicon solar cell, the present study made use of a nitrate solution containing Ag(I) and Al(III), which was subjected to a solvent extraction process with 5,8-diethyl-7-hydroxydodecan-6-oxime (LIX63). Ag(I) was selectively extracted with LIX63 over Al(III) from the nitrate leach solution. Subsequently, quantitative stripping of Ag(I) from the loaded LIX63 was performed by using 20% ammonia water. The McCabe-Thiele plots for the extraction and stripping isotherms of Ag(I) were also constructed. Extraction and stripping simulation tests confirmed an Ag(I) extraction and stripping efficiency of >99.99% and 98.9%, respectively with high purity Ag (99.998%) and Al (99.99%) solution. A process flow sheet for Ag(I) recovery from the nitrate leach solution was proposed.

• Resources Recycling
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• v.23 no.5
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• pp.21-27
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• 2014

A study on the solvent extraction for the recovery of Li from lithium-containing waste solution was investigated using $D_2EHPA$ as an extractant. The experimental parameters, such as the pH of the aqueous solution, concentration of extractant and phase ratio were observed. Experimental results showed that the extraction percentage of Li was increased with increasing the equilibrium pH. More than 50% of Li was extracted in eq. pH 6.0 by 20% $D_2EHPA$. From the analysis of McCabe-Thiele diagram, 95% of Li was extracted by four extraction stage at phase ratio(O/A) of 3.0. Stripping of Li from the loaded organic phases can be accomplished by sulfuric acid as a stripping reagent and 90 ~ 120 g/L of $H_2SO_4$ was effective for the stripping of Li. Finially, Li was concentrated about 11.85 g/L by continuous stripping process, and then lithium carbonate was prepared by precipitation method.

• Bulletin of the Korean Chemical Society
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• v.24 no.7
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• pp.948-952
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• 2003

New approach for the determination of Ag(I) ion was performed by using a carbon paste electrode (CPE) containing N,N'-Diphenyl oxamide (DPO) with anodic stripping voltammetry. The CMEs have been prepared by making carbon paste mixtures containing an appropriate amount of DPO salt coated onto graphite particles to analyze trace metal ions via complexation followed by stripping voltammetry. Various experimental parameters affecting the response, such as pH, deposition time, temperature, and electrode composition, were carefully optimized. Using differential pulse anodic stripping voltammetry, the logarithmic linear response range for the Ag(I) ion was 1.0 × $10^{-7}$ - 5.0 × $10^{-9}$ M at the deposition time of 10 min, with the detection limit was 7.0 × $10^{-10}$ M. The detection limit adopted from anodic stripping differential pulse voltammetry was 7.0 × $10^{-10}$ M for silver and the relative standard deviation was ± 3.2% at a 5.0 × $10^{-8}$ M of Ag(I) ion (n = 7). The proposed electrode shows a very good selectivity for Ag(I) in a standard solution containing several metals at optimized conditions.

• Resources Recycling
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• v.22 no.4
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• pp.81-90
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• 2013

Since the 1990s, the rapid development of information and communication industry, the demand for semiconductor and LCD continues to increase. Therefore in the formation of fine circuit patterns, which are the cores of sensitizer and the most expensive thinner and stripper liquor used to remove photoresist and its dilution, the amount in demand are dramatically increasing, emerging need for recycling of waste thinner and stripper liquor. Recently, recycling technologies of stripping process waste solution has been widely studied by economic aspects and environmental aspects, in terms of efficiency of the stripping process. In this study, analyzed paper and patent for recycling technologies of waste solution from stripping process. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1981 to 2010. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.3
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• pp.163-170
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• 2008

The reductive stripping of Np using a n-butyraldehyde (NBA) from loaded organic solution containing Np, which was oxidative-extracted in a system of a 30 % TBP/NDD-2M $HNO_3$ and O/A=2 containing 0.005 M $K_2Cr_2O_7$ as an oxidant of Np, was studied. The stripping yields of Np was increased with an increasing the NBA concentration, with a decreasing the nitric acid concentration of stripping solution and with a decreasing the reaction temperature. The apparent reductive stripping rate equation was shown by the following equation : $-d[Np]_{Org.}/dt$ = 1,524 exp(-2,906/T) $[NBA]^{0.91}\;[H^+]^{-0.92}[Np]_{Org.}$. At 1.04 M NBA and 2 M $NHO_3$, the stripping yield of Np and U was 70.1 %, and 7.1 %, respectively, and the separation factor of U over Np ($=D_U/D_{Mp}$) was about 30.4. Therefore, it was found that U and Np co-extracted in a system of TBP-$HNO_3$ could be effectively mutual-separated by the NBA.

• Clean Technology
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• v.24 no.3
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• pp.175-182
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• 2018

In this research, we investigated the cleanliness by optimizing the water content of the aqueous stripper in fluidic strip process. The stripping properties of the photoresist with optimized aqueous stripper were compared with the commercial organic stripper. The stripping performance was evaluated by electrical and optical characteristics on the surface of the transparent electrode that compare with stripped the transparent electrode surface and the rare surface before patterning by the photoresist. As a result of the photoresist stripping process of the organic stripper and the aqueous stripper optimized for water content, the aqueous stripper exhibited better electrical and optical characteristics than the organic stripper. In the case of the fluidic strip process with organic stripper, the photoresist dissolves in the stripper solution during stripping which can cause re-adsorption by contamination. Whereas that the aqueous stripper under development seems to decrease the photoresist dissolution in the stripper solution. Because the cyclodextrin contained in the stripper captures organic photoresist into hall of cyclodextrin which stripped through swelling and tearing. The photoresist residue captured by the cyclodextrin can be filtered. After the fluidic stripping process by different chemical stripping mechanism, the cleanliness of the organic stripper and aqueous stripper was compared and analyzed.

• Journal of the Korean Society of Food Science and Nutrition
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• v.19 no.2
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• pp.175-179
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• 1990

Investigations of skin stripping freezing and thawing conditions of common-European squid (Loigo vulgaris) were carried out. The most effective method of skin stripping was to immerse the sample at 5$0^{\circ}C$ for 10-15 minutes in fresh water or salt solution(5-10% w/v) Contact freezing and fresh water thawing method was found to be effective. The muscle structure of the sample thawed after contact freezing was almost the sample after contact freezing was almost the same as that of raw sample.

• Analytical Science and Technology
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• v.14 no.6
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• pp.540-544
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• 2001

Determination of cyanide ion has been studied by adsorptive stripping voltammetry using hanging mercury electrode. Cyanide ion complexed with copper ion is adsorpbed on the electrode and oxidised at the positive potential scan. Optimal conditions of CN determination were found to be ; supporting electrolyte solution ; 0.1 M NaCl of ammonium buffer at pH 10, accumulation potential; -800 mV vs Ag/AgCl, accumulation time ; 300 s, scan rate ; 50mV/s. The linear concentration of cyanide ion was observed in the range $1{\times}10^{-8}$, $1{\times}10^{-7}M$. The detection limit(n/s=3) was $0.13{\mu}g/L$($5{\times}10^{-9}M$) with 3.5% RSD.

• Analytical Science and Technology
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• v.7 no.4
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• pp.461-469
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• 1994

Trace vanadium was determined by Adsorptive stripping voltammetry with HMDE in PIPES buffer solution. N-Benzoylphenylhydroxylamine was used as a ligand. The calibration curve of vanadium was linear over the range of $10{\sim}70{\mu}g/L$ on accumulation potential of +0.15V and on accumulation time of 10 sec. The various metal ions did not interfere with the determination of vanadium(V) in this case.