• 제목/요약/키워드: Stress corrosion cracking (SCC)

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고로 열풍로에서의 응력부식발생 및 방지대책 (Mechanism of Stress Corrosion Cracking of Hot Stove Shells and Preventive Measures)

  • 안강훈;박태조
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.279-284
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    • 2002
  • The expected life of the hot stove equipments for #2 blast furnaces in Gwangyang Steel Works is about 40 years. However, the stress corrosion cracking(SCC) are founded in heat affected zone only 10 years operation. In this paper, the mechanism of SCC are investigated and the preventive measures are recommended.

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Effect of Dissolved Oxygen on the Stress Cor rosion Cracking Behavior of 3.5NiCrMoV Steels in High Temperature Water

  • Lee, J.H.;Maeng, W.Y.;Kim, U.C.
    • Corrosion Science and Technology
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    • 제2권4호
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    • pp.178-182
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    • 2003
  • Slow Strain Rate Tests (SSRT) were carried out to investigate the effect of environmental factors on the Stress Corrosion Cracking (SCC) susceptibility of 3.5NiCrMoV steels used in discs for Low-Pressure (LP) steam turbines in electric power generating plants. The influences of dissolved oxygen on the stress corrosion cracking of turbine steel were studied, For this purpose, specimens were strained at variously oxygenated conditions at $150^{\circ}C$ in pure water. When the specimen was strained with $1{\times}10^{-7}s^{-1}$ at $150^{\circ}C$ in pure water, increasing concentration of dissolved oxygen decreased the elongation and the UTS. The corrosion potential and the corrosion rare increased as the amounts of dissolved oxygen increased. The increase of the SCC susceptibility of the turbine steel in a highly dissolved oxygen environment is due to the non protectiveness of the oxide layer on the turbine steel surface and the increase of the corrosion current. These results clearly indicate that oxygen concentration increases Stress Corrosion Cracking susceptibility in turbine steel at $150^{\circ}C$.

Consideration of Methods Evaluating the Growing Process of Stress Corrosion Cracking of the Sensitized 18-8 Austenitic Stainless Steel in High Temperature Water Based on Electric Circuit Theory: The Effects of Stress Factors

  • Tsukaue, Yasoji
    • Corrosion Science and Technology
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    • 제6권3호
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    • pp.103-111
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    • 2007
  • The effect of stress factors on the growing process of stress corrosion cracking (SCC) of the sensitized 18-8 stainless steel in high temperature water was investigated using equations of crack growth rate derived from applying electric circuits to SCC corrosion paths. Three kinds of cross sections have to be considered when electric circuit is constructed using total current. The first is ion flow passage area, $S_{sol}$, of solution in crack, the second is total dissolving surface area, $S_{dis}$, of metal on electrode of crack tip and the third is dissolving cross section, $S_{met}$, of metal on grain boundary or in base metal or in welding metal. Stress may affect each area. $S_{sol}$ may depend on applied stress, $\sigma_{\infty}$, related with crack depth. $S_{dis}$ is expressed using a factor of $\varepsilon(K)$ and may depend on stress intensity factor, K only. SCC crack growth rate is ordinarily estimated using a variable of K only as stress factor. However it may be expected that SCC crack growth rate depends on both applied stress $\sigma_{\infty}$ and K or both crack depth and K from this consideration.$\varepsilon(K)$ is expressed as ${\varepsilon}(K)=h_2{\cdot}K^2+h_3{\cdot}K^3$ when $h_{2}$ and $h_{3}$ are coefficients. Also, relationships between SCC crack growth rate, da/dt and K were simulated and compared with the literature data of JBWR-VIP-04, NRC NUREG-0313 Rev.2 and SKIFS Draft. It was pointed out in CT test that the difference of distance between a point of application of force and the end of starter notch (starting point of fatigue crack) may be important to estimate SCC crack growth rate. An anode dissolution current density was quantitatively evaluated using a derived equation.

고온수중에서 STS 304 스테인리스강의 응력부식균열 성장속도 (Stress Corrosion Crack Rate of STS 304 Stainless Steel in High Temperature Water)

  • 김정기
    • 대한기계학회논문집A
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    • 제24권1호
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    • pp.156-162
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    • 2000
  • Sensitized STS 304 stainless steel crack growth rate(CGR) in high temperature water was investigated under trapezoidal wave loading test using fracture mechanics techniques. The CGR, due to stress corrosion cracking(SCC), were systematically measured as a function of the stress intensity factor and stress. holding time under trapezoidal wave loading. In high temperature water, CGR was enhanced by a synergistic effects in combination with an aggressive environment and mechanical damage. The CGR, $(da/dN)_{env}$ was basically described as a summation of the environmentally assisted crack growth rate $(da/dN)_{SCC}$, $(da/dN)_{CF}$ and fatigue crack growth rate in air $(da/dN)air,. The CGR, $(da/dN)_{env}$, increased linearly with increasing stress holding time. The CGR, $(da/dN)_{SCC}$ decreased linearly with increasing stress holding time. Fracture surface mode varied from trans-granular cracking to inter-granular cracking with increasing stress holding time.

오스테나이트 304 스테인레스 강의 응력부식균열에 미치는 냉간가공의 영향 (Effect of Cold Work on the Stress Corrosion Cracking in Austenitic 304 Stainless Steel)

  • 강계명;최종운
    • 한국안전학회지
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    • 제12권1호
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    • pp.19-28
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    • 1997
  • This study was made of the effect of cold working on the stress corrosion cracking(SCC) of austenitlc 304 stainless steel in boiling 42% $MgCl_2$ solution. For this experiment, specimens cold-worked of 0%, 10%, 20%, 30%, 40% were fabricated respectively, and then experiments of mechanical properties and stress corrosion cracking(SCC) of these specimens were carried out. The results of these experiments indicate that the maximum resistance to SCC showed at 20% of cold working degree and that the SCC susceptibility depended on the volume fraction of deformation-induced martensite by cold working and the work hardening of matrix. On the other hand, the fracture mode was changed. This phenomenon was considered that deformation-induced martensite was grown from transgranular fracture mode to intergranular fracture mode and caused by increased of dislocation density along the slip planes.

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Stress Corrosion Cracking of Alloys 600, 690, and 800 in a Tetrathionate Solution at $340^{\circ}C$

  • Lee, Eun-Hee;Kim, Kyung-Mo
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.587-588
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    • 2006
  • The stress corrosion cracking (SCC) susceptibility of Alloy 600 MA, Alloy 600 TT, Alloy 800, and Alloy 690 TT were investigated in a deaerated 0.01 M solution of sodium tetrathionate using reverse u-bend test samples at $340^{\circ}C$. The results showed that SCC occurred in all alloys, excluding Alloy 690 TT. The SCC susceptibility decreased with an increase in the chromium content of the alloys. The results of the deposits and spectra taken from an energy dispersive X-ray system confirmed the existence of a reduced sulfur causing SCC.

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선박용 Al-황동세관의 SCC에 미치는 부식환경의 영향 (Effect of corrosion environment on the SCC of Al-brass tube for vessel)

  • 임우조;정해규
    • 수산해양기술연구
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    • 제39권4호
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    • pp.291-297
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    • 2003
  • Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows:(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.

산성안개하에서 기계·구조용강의 응력부식균열 거동 (Behavior of Stress Corrosion Cracking in Structural Steel under Acid Fog Environment)

  • 임용호;김민건
    • 산업기술연구
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    • 제17권
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    • pp.291-295
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    • 1997
  • The tests of stress corrosion cracking in structural carbon steel were carried out under the conditions of acid fog and general water. As the result of measurement SCC rupture time under acid fog was observed to be much shorter than that of general water at the same stress level. Therefore, acid fog drops the SCC strength in structural carbon steel due to strong corrosion. In the SCC process by acid fog, crack initiation was caused by pit corrosion and local stress concentration, and distinctive feature of crack growth shows branching since crack grows to the corrosion direction. Moreover, corrosion products were observed by clevage corrosion on the crack surfaces.

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오스테나이트 스테인리스강 용접부의 응력부식 거동에 미치는 용접 방법의 영향 (The effect of welding methods on the stress corrosion behavior of the welded austenitic stainless steel)

  • 백신영
    • Journal of Advanced Marine Engineering and Technology
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    • 제19권4호
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    • pp.42-50
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    • 1995
  • To study the effect of welding methods on the Stress Corrosion Cracking (SCC) behavior of welded AISI type 316L and 304 austenitic stainless steel, the Slow Strain Rate Technique(SSRT) has been adopted in the boiling 45 wt% $MgCl_2$ solution. The results are as follows. 1) Welded sections are more susceptible than base metal in SCC, and the rank of SCC, and the rasistance in welding method is TIG, MIG, $CO_2$ and ARC. 2) The Ultimate tensile strength(UTS) and the strain of both base metal and welded joint are reduced as decreasing extension rate. 3) The SCC resistance of 316L base metal and welded sections are superior than that of 304. 4) The tendency of pitting and the SCC suseptibility are agreed well, and the SCC site is welded deposit section in 316L whereas HAZ in 304.

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A review of chloride induced stress corrosion cracking characterization in austenitic stainless steels using acoustic emission technique

  • Suresh Nuthalapati;K.E. Kee;Srinivasa Rao Pedapati;Khairulazhar Jumbri
    • Nuclear Engineering and Technology
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    • 제56권2호
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    • pp.688-706
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    • 2024
  • Austenitic stainless steels (ASS) are extensively employed in various sectors such as nuclear, power, petrochemical, oil and gas because of their excellent structural strength and resistance to corrosion. SS304 and SS316 are the predominant choices for piping, pressure vessels, heat exchangers, nuclear reactor core components and support structures, but they are susceptible to stress corrosion cracking (SCC) in chloride-rich environments. Over the course of several decades, extensive research efforts have been directed towards evaluating SCC using diverse methodologies and models, albeit some uncertainties persist regarding the precise progression of cracks. This review paper focuses on the application of Acoustic Emission Technique (AET) for assessing SCC damage mechanism by monitoring the dynamic acoustic emissions or inelastic stress waves generated during the initiation and propagation of cracks. AET serves as a valuable non-destructive technique (NDT) for in-service evaluation of the structural integrity within operational conditions and early detection of critical flaws. By leveraging the time domain and time-frequency domain techniques, various Acoustic Emission (AE) parameters can be characterized and correlated with the multi-stage crack damage phenomena. Further theories of the SCC mechanisms are elucidated, with a focus on both the dissolution-based and cleavage-based damage models. Through the comprehensive insights provided here, this review stands to contribute to an enhanced understanding of SCC damage in stainless steels and the potential AET application in nuclear industry.