• Journal of the Korean earth science society
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• v.29 no.5
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• pp.428-436
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• 2008

This study observed the upper tropospheric ozone enhancement in the northern Atlantic for the Aerosols99 campaign in January-February 1999. To find the origin of this air, we have analyzed the horizontal and vertical fields of Isentropic Potential Vorticity (IPV) and Relative Humidity (RH). The arch-shaped IPV is greater than 1.5 pvus indicating stratospheric air stretches equatorward. These arch-shaped regions are connected with regions of RH less than 20%. The vertical fields of IPV and RH show the folding layer penetrating into the upper troposphere. These features support the idea that the upper tropospheric ozone enhancement originated from the stratosphere. Additionally, we have investigated the climatological frequency of stratospheric intrusion over the tropical north Atlantic using IPV and RH. The total frequency between the equator and $30^{\circ}N$ over the tropical north Atlantic exhibits a maximum in northern winter. It suggests that the stratospheric intrusion plays an important role in enhancing ozone in the upper troposphere over the tropical north Atlantic in winter and early spring. Although the tropospheric ozone residual method assumed zonally invariant stratospheric ozone, stratospheric zonal ozone variance could be caused by stratospheric intrusions. This implies that stratospheric intrusion influences ozone variance over the Atlantic in boreal winter and spring, and the intrusion is a possible source for the tropical north Atlantic paradox.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.123-124
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• 2003

Fishman and Larson (1987) derived tropical tropospheric column ozone by subtracting stratospheric column ozone measured by the Stratospheric Aerosol and Gas Experiment (SAGE) from total column ozone obtained by the Total Ozone Mapping Spectrometer (TOMS). Later, the Convective Cloud Differential (CCD) method (Ziemke et al., 1998) indicated stratospheric ozone is invariant with longitude and concluded the zonal variation of total ozone determines the zonal variation of tropospheric ozone. (omitted)

• Korean Journal of Remote Sensing
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• v.22 no.1
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• pp.1-10
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• 2006

During the northern burning season, biomass burning is found north of the equator, while satellite estimates from the residual-type method such as the CCD method show higher ozone south of the equator. This discrepancy is called the tropical Atlantic paradox (Thompson et ai., 2000). We use satellite and ground-based measurements to investigate the paradox. When the background tropospheric ozone over the Pacific Ocean from TOMS measurements is subtracted from the latitudinal total ozone distribution (e.g. TOMS-Pacific method), the results show remarkable agreement with the latitudinal stratospheric ozone distribution using the CCD method. The latitudinal tropospheric ozone distribution using the CCD method, with a persistent maximum over the southern tropical Atlantic, is also seen in the latitudinal tropospheric ozone distribution using the TOMS-Pacific method. It suggests that the complicated CCD method can be replaced by the simple TOMS-Pacific method. However, the tropical Atlantic paradox exists in the results of both the CCD and TOMS-Pacific methods during the northern buming season. In order to investigate this paradox, we compare the latitudinal ozone distributions using the CCD and TOMS-Pacific methods by using the SAGE measurements (e.g. TOMS-SAGE method) and the SHADOZ ozonesoundings (e.g. TOMS-Sonde method) assuming zonally invariant stratospheric ozone, which is the same assumption as of the CCD method. During the northern burning season, the latitudinal distributions in the tropospheric ozone derived from the TOMS-SAGE and TOMS-Sonde methods show higher tropospheric ozone over the northern tropical Atlantic than the southern Atlantic due to a stronger gradient in stratospheric ozone relative to that from the CCD and TOMS-Pacific methods. This indicates that the latitudinal tropospheric ozone distribution can be changed depending on the data that is used to determine the latitudinal stratospheric ozone distribution. Therefore, there is a possibility that the north-south gradient in stratospheric ozone over the Atlantic can be a solution of the paradox.

• Proceedings of the KSRS Conference
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• v.1
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• pp.253-256
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• 2006

When the background tropospheric ozone column over the Pacific Ocean is subtracted from the latitudinal total ozone distribution, the results show remarkable agreement with the latitudinal stratospheric ozone distribution using the CCD. The latitudinal tropospheric ozone distribution using the CCD method, with a persistent maximum over the southern tropical Atlantic, is also seen in the latitudinal tropospheric ozone distribution using the T-P method. It suggests that the CCD method can be replaced by the simple T-P method. However, the tropical Atlantic paradox exists in the results of both the CCD and T-P methods during the northern burning season. In order to investigate this paradox, we compare the latitudinal ozone distributions using the CCD and T-P methods by using the SAGE measurements (e.g. TSA method) and the SHADOZ ozonesoundings (e.g. T-S method) assuming zonally invariant stratospheric ozone, which is the same assumption as of the CCD method. During the northern burning season, the latitudinal distributions in the tropospheric ozone derived from the T-SA and T-S methods show higher tropospheric ozone over the northern tropical Atlantic than the southern Atlantic due to a stronger gradient in stratospheric ozone relative to that from the CCD and T-P methods. This indicates that the latitudinal tropospheric ozone distribution can be changed depending on the data that is used to determine the latitudinal stratospheric ozone distribution. Therefore, there is a possibility that the north-south gradient in stratospheric ozone over the Atlantic can be a solution of the paradox.

• Journal of the Chungcheong Mathematical Society
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• v.33 no.4
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• pp.469-487
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• 2020

In this paper, we investigate the mathematical structures of chemical reactions for stratospheric ozone depletion.

• The Korean Journal of Ecology
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• v.24 no.2
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• pp.117-119
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• 2001

Solar ultraviolet-B (UV-B) irradiances incident on a horizontal surface at Taegu, Korea during 1996-1998 were calculated with 5 minute averages of measurements taken every 30 seconds by a broadband UV-B sensor. The average, maximum and minimum of daily UV-B dose were 11.31, 22.04 and 3.20kJ m$^{-2}$ day$^{-1}$ , respectively, for the measuring period. Variations in stratospheric ozone concentration measured from space explain 85% of changes in the daily UV-B dose. It was expected that decrease of 50 Du in stratospheric ozone cause increase of 24.1% in daily UV-B dose in this study.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.4
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• pp.413-422
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• 2005

The ozone concentration measured by HALOE (Ver 19) from Oct. 1991 to Dec. 2003 is used for analyzing the variation of ozone concentration. The HALOE loaded in UARS is observing several gases in the atmosphere, from 10km to 80km. Fourier analysis of these data in the middle latitude northern hemisphere is reported in this paper. To detect any possible long term trends, the fourier transformed time series was back transformed after removing signals with time periods of less than 6 months. Although the results clearly show the strong annual cycle, it is difficult to show any long term trends from the fourier series. We also compared the ozone volume mixing ratio's from HALOE with that from the ground-based radiometry to evaluate the accuracy of microwave observation at Sookmyung Women's University.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.6
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• pp.650-662
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• 2011

The statistical tools such as empirical orthogonal function (EOF), and singular value decomposition (SVD) have been applied to analyze the characteristic of air pollutant over southeast Asia as well as to evaluate Zimeke's tropospheric column ozone (ZTO) determined by tropospheric residual method. In this study, we found that the EOF and SVD analyses are useful methods to extract the most significant temporal and spatial pattern from enormous amounts of satellite data. The EOF analyses with OMI $NO_2$ and OMI HCHO over southeast Asia revealed that the spatial pattern showed high correlation with fire count (r=0.8) and the EOF analysis of CO (r=0.7). This suggests that biomass burning influences a major seasonal variability on $NO_2$ and HCHO over this region. The EOF analysis of ZTO has indicated that the location of maximum ZTO was considerably shifted westward from the location of maximum of fire count and maximum month of ZTO occurred a month later than maximum month (March) of $NO_2$, HCHO and CO. For further analyses, we have performed the SVD analyses between ZTO and ozone precursor to examine their correlation and to check temporal and spatial consistency between two variables. The spatial pattern of ZTO showed latitudinal gradient that could result from latitudinal gradient of stratospheric ozone and temporal maximum of ZTO in March appears to be associated with stratospheric ozone variability that shows maximum in March. These results suggest that there are some sources of error in the tropospheric residual method associated with cloud height error, low efficiency of tropospheric ozone, and low accuracy in lower stratospheric ozone.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• v.21 no.1
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• pp.31-46
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• 1993

A radiative transfer model with two-stream/delta-Eddington approximation has been developed to calculate the vertical distributions of atmospheric heating rates and radiative fluxes. The performance of the model has been evaluated by comparison with the results of ICRCCM (Intercomparison of radiative codes in climate models). It has been demonstrated that the presented model has a capability to calculate the solar radiation not only accurately but also economically. The characteristics of ultraviolet-B radiation (UV-B; 280-320nm) are examined by comparison of relation between the flux at the top of atmosphere and that at the surface. The relation of UV-B is quadratic due to the strong ozone absorption in this band. Also, the dependence of the UV-B radiation on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption has been tested with various solar zenith angles. The surface UV-B increases as the solar zenith angle increases. The existence of stratospheric aerosols causes an increase in the planetary albedo due to the aerosols' backscattering. The planetary albedo with aerosol's effect has been increases as the solar zenith angle is not sensitive. It may be caused by the fact that the aerosols' scattering effect becomes saturated with the relatively long path length in a large solar zenith angle. Finally, the regional impact of stratospheric aerosols due to volcanic eruption on the intensity of UV-B radiation at the surface has been estimated. A direct effect is that the flux is diminished at the low latitudes, while it is enhanced in the high latitudes by the aerosols' photon trap or twilight effect. In the high latitudes, both aerosols' scattering and ozone absorption have strong and opposite impacts to the surface UV-B radiation is located at the mid-latitudes during spring season in both hemispheres.

• Journal of Astronomy and Space Sciences
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• v.37 no.1
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• pp.69-75
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• 2020

We analyze the observations of temperature and ozone measured by the Microwave Limb Sounder (MLS) during the period of 2005-2016, to investigate the vertical structures of temperature and ozone in the stratosphere and mesosphere during stratospheric sudden warming (SSW). We compute the height profiles of the correlation coefficients between 55 height levels of MLS temperature anomalies and compare them with the results of Whole Atmosphere Community Climate Model simulations for three major SSWs. We also construct the temperature and ozone anomalies for the events to investigate the changes in the temperature and ozone distributions with height. There seems to always be a relatively weak but broad negative correlation between the temperature anomaly at 10 hPa and temperature anomalies over the entire mesosphere during the period before SSW events. However, this pattern gets stronger in the lower mesosphere but becomes a positive correlation in the upper mesosphere and lower thermosphere after the onset of SSW. We also found that the temperatures from the simulations show a similar trend to the observational results but with smaller variations and the transition height from negative to positive correlation in the mesosphere is much lower in the simulation than in the actual observations.