• 한국수소및신에너지학회논문집
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• 제17권4호
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• pp.418-424
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• 2006

In order to improve the activation properties of the $AB_2$ type hydrogen storage alloys for Ni-MH battery, the alloy surface was modified by employing high energy ball milling. The $Zr_{0.54}Ti_{0.45}V_{0.54}Ni_{0.87}Cr_{0.15}Co_{0.21}Mn_{0.24}$ alloy powder was ball milled for various period by using the high energy ball mill. As the ball milling time increased, activation of the $AB_2$ type composite powder electrodes were enhanced regardless of additives. When the ball milling time was small discharge capacities of the $AB_2$ type composite powder electrodes increased with the milling time. On the other hand for large milling time it decreased with increasing milling time. The maximum discharge capacity was obtained by ball milling for 3-4 min.

• Journal of Power Electronics
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• 제15권4호
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• pp.1105-1118
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• 2015

Battery energy storage devices (ESDs) have become more and more commonplace to maintain the stability of islanded power systems. Considering the limitation in inverter capacity and the requirement of flexibility in the ESD, the droop control was implemented in paralleled ESDs for higher capacity and autonomous operation. Under the conventional droop control, state-of-charge (SoC) errors between paralleled ESDs is inevitable in the discharging operation. Thus, some ESDs cease operation earlier than expected. This paper proposes an adaptive accelerating parameter to improve the performance of the SoC error eliminating droop controller under the constraints of a microgrid. The SoC of a battery ESD is employed in the active power droop coefficient, which could eliminate the SoC error during the discharging process. In addition, to expedite the process of SoC error elimination, an adaptive accelerating parameter is dedicated to weaken the adverse effect of the constraints due to the requirement of the system running. Moreover, the stability and feasibility of the proposed control strategy are confirmed by small-signal analysis. The effectiveness of the control scheme is validated by simulation and experiment results.

• 대한금속재료학회지
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• 제49권2호
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• pp.174-179
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• 2011

We investigated the surface morphology changes of a lithium/sulfur battery using multi-walled canbon nanotube added sulfur electrode during charge-discharge cycling. The Li/S cell showed the first discharge capacity of 1286 mAh/g-S, which utilized is 71% of the theoretical value. It decreased to 328 mAh/g-S at the 100th cycle, which corresponds to about 19% utilization of the total sulfur in the cathode. The spherical lumps of the reaction product were observed on the surface of the sulfur electrode. This material was verified as lithium sulfide by X-ray diffraction measurement. The pores in the separator were filled with reaction product. Thus the diffusion of the $Li^+$ ion decreased, which resulted in the decreased capacity of the Li/S cell.

• 전기학회논문지P
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• 제64권1호
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• pp.18-22
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• 2015

When using a secondary battery in energy storage units, if the grid is in light duty the active power is stored so it can be used when the grid is in heavy duty. This makes possible for the load equalize and make the grid optimized. Recently the government is trying to propagate this technology. Depending on its capacity this kind of electric energy storage unit is used in adjusting the frequency, break up the energy peak in summer and winter, stabilize the energy output of renewable energy which can change unstably because of the environment. Which makes it possible to stabilize the grid. It is anticipated that market of 120 trillion won will be developed worldwide in 2030. Currently in Korea a steady supply is in progress. However because of stray electromagnetic waves some other electronics are malfunctioning. This paper covers the research in the method to detect the emission noise in small electric energy storage units using lithium secondary batteries and battery management system, Power conditioning systems with CIPSR standards. And the research of a more efficient method to measure such stray electromagnetic waves.

• Journal of international Conference on Electrical Machines and Systems
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• 제2권4호
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• pp.460-465
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• 2013

Electrical equipments of nuclear power plant are divided into class 1E and non-class 1E. Electrical equipment and systems that are essential to emergency reactor shutdown, containment isolation, reactor core cooling, and containment and reactor heat removal, are classified as class 1E. batteries of nuclear power plant are divided into four channels, which are physically and electrically separate and independent. The battery bank of class 1E DC power system of the nuclear power plant use lead-acid batteries in present. The lead acid battery, which has a high energy density, is the most popular form of energy storage. Kt factor of lead-acid battery is used to determine battery size and it is one of calculatiing coefficient for capacity. this paper analyzes Kt factor of lead-acid battery for the DC power system of nuclear power plant. In addition, correlation between Kt parameter and peukert's exponent of lead-acid battery for nuclear plant are discussed. The analytical results contribute to optimize of determining size Lead-acid battery bank.

• 한국산업융합학회 논문집
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• 제25권3호
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• pp.451-459
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• 2022

Recently, in accordance with the demand for a large capacity of a secondary battery according to an increase in the demand for energy storage devices, a modular series battery configuration is essential. Accordingly, various cell balancing techniques have been proposed to prevent high efficiency and performance degradation of the battery. In this paper, propose a battery voltage balancing topology consisting of a flyback DC/DC converter type of a SIMO (Single-Input-Multiple Output) two-switch configuration for a series battery configuration. The proposed topology shows a structure in which a DC/DC converter connected to each module and a battery cell share one transformer. The topology cell balancing operation is a principle in which the voltage balancing converter of the battery converges to the same value through a transformer that shares a magnetic flux with the cells constituting the module through a single high-frequency transformer. In this paper, the dynamic characteristics analysis of the proposed circuit using PSIM was based and it was verified through experiments on one module.

• Journal of Electrochemical Science and Technology
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• 제12권4호
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• pp.458-464
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• 2021

Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.

• 전기학회논문지
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• 제67권9호
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• pp.1119-1124
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• 2018

So far BESS(Battery Energy storage system) has been widely applied to power systems rapidly. Usually it has been used to regulate the renewable energy output and to adjust the power system frequency. In 2013, EPRI has reported a study of utilizing BESS to replace two black start generators of American Electric Power(AEP) that will be demolished. If the BESS can be used as a self-starting generator, it is possible to shorten the long-distance primary transmission line and shorten the restoration time because BESS is capable of the high-speed start and there is no restriction on the installation position. This paper presents a possibility of using BESS as a self-starting generator by using PSCAD/EMTDC in Korean power systems. Herein, the process to estimated the required capacity of BESS is also presented.

• 한국재료학회지
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• 제29권12호
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• pp.812-817
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• 2019

A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (M_v ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

• 전기학회논문지
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• 제67권9호
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• pp.1174-1180
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• 2018

In December 2017, the government announced plans to increase the current proportion of renewable energy from 7% to 20% by 2030 through a plan called the Renewable Energy 3020 Implementation Plan. Therefore, the demand for installation of photovoltaic(PV), wind turbine(WT) and battery energy storage system(BESS) is expected to increase. In particular, the system combined with energy storage system(ESS) is expected to take up a large portion since PV and WT can receive high renewable energy certificates(REC) weights when combined with ESS. In this study, we calculate the optimal capacity of the power conditioning system(PCS) and the BESS by comparing the economical efficiency and maximize the efficiency of the PV-BESS system in which the PV and the BESS are connected. By analyzing the system marginal price(SMP) and REC, it maximize profits through application of REC weight 5.0 and optimal charge-discharge scheduling according to the SMP changes.