• The Journal of Engineering Geology
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• v.20 no.3
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• pp.339-348
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• 2010

As part of preparing for future earthquakes near three LNG receiving terminals located in coastal regions of Korea, acceleration monitoring systems were installed at four free field sites and on a pile foundation beneath a storage tank in a receiving terminal. Several equipments and accessories were devised to successfully install and operate the monitoring system at LNG receiving terminals. Synthetic earthquake-alarming software systems designed for decisionmaking, based on peak ground acceleration computed using the measured data, were developed for rapid response during earthquakes, not only in each local terminal area but also in the central control division. In addition, a framework software linking nationwide data on peak ground accelerations was included in the integrated earthquake alarming system in the central division, for various future applications. The earthquake alarming systems developed in this research for LNG receiving terminals, based on acceleration monitoring, represent a useful framework for industrial facilities located in coastal regions, where geotechnical conditions may show marked spatial variations.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.3
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• pp.122-130
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• 2004

Crude oil is complex mixture of thousands of different organic compound formed from a variety of organic materials that are chemically converted under differing geological conditions over long periods of time. Also oil composition varies according to crude source, refining, processing, handling and storage. The oil fingerprint method is application of specific knowledge of petrochemicals and use of sophisticated analytical equipment and techniques to identify the source(s) of oil pollution. KNMPA currently utilizes three primary analytical techniques: Gas Chromatography (GC), Fluorescence Spectroscopy(FL) and Infrared Spectroscopy(IR). Of all these techniques, GC technique are most widely used. Gas Chromatography is used as a primary analytical method because high reliableness, high separating efficiency and repeatability, but it is timeconsumable. The study results of identification of waterborne spilled oil by Fast Gas Chromatograph method showed that analytical time is cut down to 30minutes in comparison with packed column method and chromatograms represent high resolution and high repeatability.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.182-188
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• 2020

This study aimed to collect the carbon dioxide generated as a by-product from petrochemicals and liquor factories and use it in a crop breeding greenhouse. This was applied mainly to the storage of dry ice and the supply of carbon dioxide to achieve this target. Dry ice has a strong cooling effect because CO₂ becomes a solid or gas at temperatures and pressures below the triple point, and the solid sublimes at -78.5℃ and atmospheric pressure. The consumption of dry ice according to temperature was 0.983kg/day, 2.358kg/day, 5.102kg/day, and 7.035kg/day when the temperature was 5℃, 10℃, 15℃, and 20℃, respectively, which corresponded to 1,102ppm, 1,481ppm, 1,677ppm, and 1,855ppm. Dry ice consumption in the test greenhouse decreased by approximately 0.9kg/h, and the CO₂ concentration in the greenhouse at 9 a.m., before supplying dry ice increased to 517ppm, 1,519ppm at 10 a.m., 1,651ppm at 11 a.m., and 1,651ppm at 12 p.m., before maintaining this level of activity. Overall, this study attempted to contribute to increasing farm income by deriving the supply conditions through an expansion of the supply of carbon dioxide gas for crops.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.9
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• pp.995-1005
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• 2005

The study with laboratory sandbox model has been carried out to address potential use of reclaimed water, as a countermeasure artificially recharging the coastal aquifer, to effectively prevent from seawater intrusion due to overexploitation. It also investigated plausibility for either preserving or recovering the freshwater interface facing with seawater intrusion. To do this, we assessed hydraulic properties in artificial aquifer seawater/freshwater interface) depending upon the variation of extraction, storage and injection of reclaimed water. The variation of interface between freshwater and seawater were visualized by Surfer 8(Golden Software, USA) according to given experimental conditions. The interface between seawater and freshwater has been sensitively influenced by the change of extraction rate, where seawater zone migrated much faster into freshwater zone even though extraction rate became decreased. However, decreasing recharge rate could slow down moving of saline water zone toward freshwater zone. When the recharge was solely introduced into the sand box model, saline water intrusion was retarded than those of recharge and extraction working together. And also, the level of salinity of saline water was diluted by artificial recharge. It finally revealed that the artificial recharge would hydraulically avoid seawater intrusion while the freshwater sources could be conservatively utilized.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.4
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• pp.256-262
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• 2009

The use of hydrodynamic separator is becoming increasingly popular for suspended solids reduction in urban storm runoff. This study is a laboratory investigation of the use of Vortex Screen to reduce the solids concentration of synthesized storm runoff. The synthesized storm runoff was made with water and addition of particles; manhole sediment, road sediment, fly ash, and ployvinyl chloride powder. Vortex Screen was made of acryl resin with 250 mm of diameter and height of 700 mm. To determine the removal efficiency for various influent concentrations of suspended solids (SS) and chemical oxygen demand (COD), tests were performed with different operational conditions. The samples were taken simultaneously at the influent storage tank and effluent tank, and measured SS and COD concentrations. The ranges of surface loading rate were 110 to 1,550 $m^3/m^2$/day, and influent SS concentrations were varied from 141 to 1,986 mg/L. This paper was intended to evaluate the effect of inlet baffle and the ratio of underflow to overflow ($Q_U/Q_O$) on particle separation efficiency for various particle size using Vortex Screen. It was found that when increase of $Q_U/Q_O$ from 10% to 20%, SS removal efficiency was increased about 6%. The range of SS and COD removal efficiencies of road sediment particle size 125<$d_p$<300 ${\mu}m$ were 68.0~81.0%, 53.1~71.9%, respectively. Results showed that SS removal efficiency with inlet baffle improved by about 10~20% compared without inlet baffle.

• Journal of Pharmaceutical Investigation
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• v.35 no.3
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• pp.137-142
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• 2005

A rapid, selective and sensitive reversed-phase HPLC method for the determination of glipizide in human serum was validated and applied to the pharmacokinetic study of glipizide. Glipizide and internal standard, tolbutamide, were extracted from human serum by liquid-liquid extraction with benzene and analyzed on a Nova Pak $C_{18}\;60{\AA}$ column with the mobile phase of acetonitrile-potassium dihydrogen phosphate (10 mM, pH 3.5) (4:6, v/v). Detection wavelength of 275 nm and flow rate of 0.7 ml/min were fixed for the study. The assay robustness for the changes of mobile phase pH, organic solvent content, and flow rate was confirmed by $3^3$ factorial design using a fixed glipizide concentration (500 ng/ ml) with respect to its peak area and retention time. And also, the ruggedness of this method was investigated at three different laboratories using same quality control (QC) samples. This method showed linear response over the concentration range of 10-1000 ng/ml with correlation coefficient greater than 0.999. The lower limit of quantitation using 0.5 ml of serum was 10.0 ng/ml, which was sensitive enough for pharmacokinetic studies. The overall accuracy of the quality control samples ranged from 82.6 to 105.0% for glipizide with overall precision (% C.V.) being 1.13-13.20%. The percent recovery for human serum was in the range of 85.2 93.5%. Stability studies showed that glipizide was stable during storage, or during the assay procedure in human serum. The peak area and retention time of glipizide were not significantly affected by the changes of mobile phase pH, organic solvent content, and flow rate under the conditions studied. This method showed good ruggedness (within 15% C.V.) and was successfully used for the analysis of glipizide in human serum samples for the pharmacokinetic studies at three different laboratories, demonstrating the suitability of the method.

• Journal of Pharmaceutical Investigation
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• v.35 no.4
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• pp.265-271
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• 2005

A rapid, selective and sensitive reversed-phase HPLC method for the determination of etodolac in human serum was developed, validated, and applied to the pharmacokinetic study of etodolac. Etodolac and internal standard, ibuprofen were extracted from human serum by liquid-liquid extraction with hexane/isopropanol (95:5, v/v) and analyzed on a Luna C18(2) column with the mobile phase of 1% aqueous acetic acid-acetonitrile (4:6, v/v). Detection wavelength of 227 nm and flow rate of 1.0 mL/min were fixed for the study. The assay robustness for the changes of mobile phase pH, organic solvent content, and flow rate was confirmed by $3^3$ factorial design using a fixed etodolac concentration $(1\;{\mu}g/mL)$ with respect to its peak area and retention time. And also, the ruggedness of this method was investigated at three different laboratories using same quality control (QC) samples. This method showed linear response over the concentration range of $0.05-40\;{\mu}g/mL$ with correlation coefficients greater than 0.999. The lower limit of quantification using 0.5 mL of serum was 0.05 ${\mu}g/mL$, which was sensitive enough for pharmacokinetic studies. The overall accuracy of the quality control samples ranged from 92.00 to 110.00% for etodolac with overall precision (% C.V.) being 1.08-10.11%. The percent recovery for human serum was in the range of 76.73-115.30%. Stability studies showed that etodolac was stable during storage, or during the assay procedure in human serum. The peak area and retention time of etodolac were not significantly affected by the changes of mobile phase pH, organic solvent content, and flow rate under the conditions studied. This method showed good ruggedness (within 15% C.V.) and was successfully used for the analysis of etodolac in human serum samples for the pharmacokinetic studies of orally administered Lodin XL tablet (400 mg as etodolac) at three different laboratories, demonstrating the suitability of the method.

• Journal of Pharmaceutical Investigation
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• v.35 no.6
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• pp.423-429
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• 2005

A selective and sensitive reversed-phase HPLC method for the determination of fenoprofen in human serum was developed, validated, and applied to the pharmacokinetic study of fenoprofen calcium. Fenoprofen and internal standard, ketoprofen, were extracted from human serum by liquid-liquid extraction with diethyl ether and analyzed on a Luna C18(2) column with the mobile phase of acetonitrile-3 mM potassium dihydrogen phosphate (32:68, v/v, adjusted to pH 6.6 with phosphoric acid). Detection wavelength of 272 nm and flow rate of 0.25 mL/min were fixed for the study. The assay robustness for the changes of mobile phase pH, organic solvent content, and flow rate was confirmed by $3^{3}$ factorial design using a fixed fenoprofen concentration $(2\;{\mu}g/mL)$ with respect to its peak area and retention time. And also, the ruggedness of this method was investigated at three different laboratories using same quality control (QC) samples. This method showed linear response over the concentration range of $0.05-100\;{\mu}g/mL$ with correlation coefficients greater than 0.999. The lower limit of quantification using 1 mL of serum was $0.05\;{\mu}g/mL$, which was sensitive enough for pharmacokinetic studies. The overall accuracy of the quality control samples ranged from 92.27 to 109.20% for fenoprofen with overall precision (% C.V.) being 5.51-11.71 %. The relative mean recovery of fenoprofen for human serum was 81.7%. Stability (freeze-thaw, short and long-term) studies showed that fenoprofen was not stable during storage. But, extracted serum sample and stock solution were allowed to stand at ambient temperature for 12 hr prior to injection without affecting the quantification. The peak area and retention time of fenoprofen were not significantly affected by the changes of mobile phase pH, organic solvent content, and flow rate under the conditions studied. This method showed good ruggedness (within 15% C.V.) and was successfully used for the analysis of fenoprofen in human serum samples for the pharmacokinetic studies of orally administered Fenopron tablet (600 mg as fenoprofen) at three different laboratories, demonstrating the suitability of the method.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.4
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• pp.287-297
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• 2014

For several decades, many countries operating nuclear power plants have been studying the various disposal alternatives to dispose of the spent nuclear fuel or high-level radioactive waste safely. In this paper, as a direct disposal of spent nuclear fuels for deep geological disposal concept, the rod consolidation from spent fuel assembly for the disposal efficiency was considered and analyzed. To do this, a concept of spent fuel rod consolidation was described and the related concepts of disposal canister and disposal system were reviewed. With these concepts, several thermal analyses were carried out to determine whether the most important requirement of the temperature limit for a buffer material was satisfiedin designing an engineered barrier of a deep geological disposal system. Based on the results of thermal analyses, the deposition hole distance, disposal tunnel spacing and heat release area of a disposal canister were reviewed. And the unit disposal areas for each case were calculated and the disposal efficiencies were evaluated. This evaluation showed that the rod consolidation of spent nuclear fuel had no advantages in terms of disposal efficiency. In addition, the cooling time of spent nuclear fuels from nuclear power plant were reviewed. It showed that the disposal efficiency for the consolidated spent fuel rods could be improved in the case that cooling time was 70 years or more. But, the integrity of fuels and other conditions due to the longer term storage before disposal should be analyzed.

• Korean Journal of Agricultural and Forest Meteorology
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• v.13 no.2
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• pp.56-68
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• 2011

Wet canopy evaporation ($E_{WC}$) has been recognized as a significant component of total evapotranspiration, especially in forests and therefore it is critical to accurately assess $E_{WC}$ to understand forest hydrological cycle. In this review, I focused on the measurement methods and evaluating the magnitudes of $E_{WC}$ at diverse forest types (e.g., deciduous, coniferous, mixed, and rain forests). I also present the general issues to be considered for $E_{WC}$ measurements. The commonly used measurement methods for $E_{WC}$ include the water balance, energy balance, and the Penman-Monteith (PM) methods. The magnitudes of $E_{WC}$ ranged from 5 to 54% of precipitation based on the literature review, showing a large variation even for a similar forest type possibly related to canopy structure, rainfall intensity, and other meteorological conditions. Therefore, it is difficult to draw a general conclusion on the contribution of $E_{WC}$ to evapotranspiration from a particular forest type. Errors can arise from the measurements of precipitation (due to varying wind effect) and throughfall (due to spatial variability caused by canopy structure) for water balance method, the measurements of sensible heat flux and heat storage for energy balance method, and the estimation of aerodynamic conductance and unaccounted sensible heat advection for the PM method. For a reliable estimation of $E_{WC}$, the combination of ecohydrological and micrometeorological methods is recommended.