• Ocean and Polar Research
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• v.29 no.2
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• pp.135-153
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• 2007

Temporal (seasonal) and spatial distributions and variations of various physico-chemical factors (salinity, temperature, pH, DO, COD, SPM, POC, silicate, DIP, DIN) in surface and bottom waters were studied in the coastal environment with typical macro-tidal range and monsoonal weather condition, Gyeonggi Bay, west coast of Korea. Spacial distribution patterns of these factors were generally similar to each other, and appeared to be inversely related to the distribution pattern of salinity, suggesting that water quality of the study area was primarily controlled by the physical mixing process of Han-River freshwater with nearby coastal seawater. During flooding season, silicate- and nitrogen-rich Han River water directly flowed into offshore as far as $20\sim30\;km$ from the river mouth, probably causing serious environmental problems such as eutrophication and unusual and/or noxious algal bloom, etc. Except the surface water during summer flooding season, high concentrations of nutrients appeared generally in dry season, whereas low values in spring, possibly because of the occurrence of spring phytoplankton bloom. On the other hand, nutrient flux through the estuary seems to be primarily depending on river discharge, sewage discharge and agricultural activities, especially during the rainy season. Also, nutrients in this coastal waters are considered to be supplied from the sediments of tidal-flats, which developed extensively around the Han-River mouth, especially during fall and winter of dry and low discharge seasons, possibly due to the stirring of tidal flat sediments with highly enriched pore-water nutrients by storm. And also, COD and DIN concentrations in the study area consistently increased during the last 20 years, probably because of agricultural activities and increasing discharge of industrial and domestic wastes.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.167-175
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• 2018

Natural gas is a clean fuel that discharges almost no air-contaminating substances. This study examined the simultaneous reduction of $CH_4$ and NOx of NGOC/LNT catalysts for CNG buses related to the improvement of the $de-CH_4/NOx$ performance, focusing mainly on identifying the additive catalysts, loading of the washcoat, stirring time, and types of substrates. The 3wt. % Ni-loaded NGOC generally exhibited superior $CH_4$ reduction performance through $CH_4$ conversion, because Ni is an alkaline, toxic oxide, and exerts a reducing effect on $CH_4$. A excessively small loading resulted in insufficient adsorption capacity of harmful gases, whereasa too high loading of washcoat caused clogging of the substrate cells. In addition, with the economic feasibility of catalysts considered, the appropriate amount of catalyst washcoat loading was estimated to be 124g/L. The NOx conversion rate of the NGOC/LNT catalysts stirred from $200^{\circ}C$ to $550^{\circ}C$ for 5 hours showed 10-15% better performance than the NGOC/LNT catalysts mixed for 2 hours over the entire temperature range. The NGOC/LNT catalysts exhibitedapproximately 20% higher $de-CH_4$ performance on the ceramic substrates than on the metal substrates.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.8
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• pp.706-713
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• 2016

In this study, the welding characteristics of friction stir welding were investigated in accordance with the tool plunge position and cooling to the base materials for the joining of dissimilar materials (A6005-AZ61). Other different welding conditions, such as the tool rotation speed and welding speed, were fixed to 500rpm-30mm/min, respectively, and welding was then carried out by placing the Mg alloy (AZ61) on the advancing side and Al alloy(A6005) on the retreating side. Welding was conducted under six different conditions. To investigate the welding characteristic, tensile test and microstructure observations using an optical microscope were carried out. As the tensile test result, the maximum strength appeared under the condition in which the tool is moved 1 mm to the Mg alloy direction and cooling to the base materials. Under the same welding conditions, the strength with cooling was approximately two times higher than that without cooling. The tool was located in each direction of 1.7 mm from the weld line. Therefore, in the excessive off-set of tool position, the welding integrity was in an extremely poor condition due to the lack of stirring. This study was confirmed by the A6005-AZ61 dissimilar friction stir welding the welding speed and the tool rotation speed. In addition, the temperature control and tool plunge position are important welding parameters.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.86-92
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• 2012

A characteristic study of chlorine dioxide generation by the electrolysis system was performed after chlorite ($ClO_2^-$) is adsorbed from sodium chlorite by a polymer ion exchange resin. A strongly basic anion exchange resin was used and a Ti plate coated with Ru and Ir was used as an electrode. Various parameters such as reaction stirring velocity, reaction temperature, chlorine dioxide product concentration, ion exchange resin content and product maker type for the adsorption quantity in the chlorite adsorption of ion exchange resin were investigated and found the ion exchange resin with the maximum adsorption quantity. A generation trend of chlorine dioxide was observed by the electrolysis system and optimum conditions on the desired value were found using response surface design of DOE (Design of Experiments). The strongly basic anion exchange resin with the maximum adsorption quantity was SAR-20 (TRILITE Gel type II) and the adsorption quantity was around 110 mg/IER (g). Observed generation optimum conditions of chlorine dioxide were constant-current (electrode area base; $A/dm^2$) and flow rate of $N_2$ gas (4.7 L/min) at the desired value of sterilization (900~1000 ppm, 1 h).

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.87-92
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• 2006

The steam reforming of methane over Ru-promoted $Ni/Al_2O_3$ was carried out. Compared with $Ni/Al_2O_3$, which needs pre-reduction by $H_2$, $Ru/Ni/Al_2O_3$ catalysts exhibited relatively higher activity than conventional $Ni/Al_2O_3$. According to $H_2-TPR$ of reduced or used catalysts and $CH_4-TPR$, it was revealed that the reduction of $RuO_x$ by $CH_4$ decomposition begins at a lower temperature ($220^{\circ}C$) and the reduced Ru facilitates the reduction of NiO, and leads to self-activation. To improve metal dispersion, the catalyst was soaked in 7 M aqueous $NH_4OH$ for 2 h at $45^{\circ}C$ while stirring. As a result, $Ru/Ni/Al_2O_3$ catalysts with aqueous $NH_4OH$ treatment have higher activity, larger metal surface area (by $H_2$-chemisorption), and small particle size (by XRD and XPS). It is noted that the amount of noble metal could be reduced by aqueous $NH_4OH$ treatment.

• Journal of the Korean Chemical Society
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• v.48 no.6
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• pp.590-598
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• 2004

The preconcentration and determination of trace Cu(II) and Pb(II) on calcium alginate beads in aqueous solution were studied. A calcium alginate beads were prepared by adding an alginic acid to sample solution contained Ca(II). Some following conditions were optimized: the pH of sample solution, amount of alginic acid, and stirring time for effective adsorption; the type and concentration of acid, and sonication time in an ultrasonic vibrator for the perfect de-sorption. A sample solution was prepared with Cu(II) and Pb(II) in DI water. And Ca(II) and ethanol was added into the sample solution. The pH of the final sample solution was controlled with buffer solution. The alginic acid were dispersed in the sample solution by a magnetic stirrer. This mixture was stored in room temperature for 30 min to form a calcium alginate. After the beads were filtered and washed on a membrane filter, the analytes were redissolved from the beads by an ultrasonic vibration of 10 minutes in 1.0M $HNO_3$ solution. The effect of diverse ions on the adsorption of analytes were studied. This procedure was applied for the analysis of two real samples. The recoveries in spiked samples were $90.4{\sim}104.3%$ for analytes.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.2
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• pp.115-122
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• 2010

In this study, the removal of Cs and Tc from a simulated fission products (FP) solution which were co-dissolved with U during the oxidative-dissolution of spent fuel in a mixed carbonate solution of $(Na_2CO_3-NaHCO_3)-H_2O_2$ was investigated by using a selective precipitation method. As Cs and Tc might cause an unstable behavior due to the high decay heat emission of Cs as well as the fast migration of Tc when disposed of underground, it is one of the important issues to removal them in views of the increase of disposal safety. The precipitation of Cs and Re (as a surrogate for Tc) was examined by introducing sodium tetraphenylborate (NaTPB) and tetraphenylphosponium chloride (TPPCl), respectively. Precipitation of Cs by NaTPB and that of Re by TPPCl were completed within 5 minutes. Their precipitation rates were not influenced so much by the temperature and stirring speed even if they were increased by up to $50^{\circ}C$ and 1,000 rpm. However, the pH of the solution was found to have a great influence on the precipitation with NaTPB and TPPCl. Since Mo tends to co-precipitate with Re at a lower pH, especially, it was effective that a selective precipitation of Re by TPPCl was carried out at pH of above 9 without co-precipitation of Mo and Re. Over 99% of Cs was precipitated when the ratio of [NaTPB]/[Cs]>1 and more than 99% of Re, likewise, was precipitated when the ratio of [TPPCl]/[Re]>1.

• Polymer(Korea)
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• v.37 no.6
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• pp.702-710
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• 2013

Zaltoprofen loaded polyoxalate (POX) microspheres were prepared by an emulsion solvent-evaporation/extraction method like oil-in-water (O/W) for sustained release of zaltoprofen. The influence of several preparation parameters such as fabrication temperature, stirring speed, intensity of the sonication, initial drug ratio, molecular weight ($M_w$) of POX, concentration of POX and concentration of emulsifier has been investigated on the zaltoprofen release profiles. Physicochemical properties and morphology of zaltoprofen loaded POX microspheres were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimeter (DSC) and Fourier transform infrared (FTIR). Through the analyzed results, it was demonstrated that the characteristics of the microspheres greatly affected by the prepared condition. The releases behavior of zaltoprofen was investigated for 10 days in vitro. It was confirmed that the release behavior of zaltoprofen can be controlled by the manufacturing factor of solvent-evaporation/extraction method.

• Food Science and Preservation
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• v.30 no.3
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• pp.472-482
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• 2023

This study used gas chromatography combined with the microelectron capture detection method to determine the most effective washing and cooking methods for removing isoprothiolane from rice. The initial isoprothiolane concentrations in brown and polished rice, before washing, were 17.03 mg/kg and 1.67 mg/kg, respectively. Residual concentrations declined with more washing cycles (19.3-59.3% for brown rice; 43.1-66.5% for polished rice); and by increasing the temperature of the washing water from 5℃ to 40℃ (56.6-63.1% for brown rice; 67.1-74.9% for polished rice). Hand-washing samples using gentle stirring or harsh rubbing reduced pesticide concentrations by 63.1-71.6% for brown rice, versus 75.4-87.4% for polished rice. Reduction in isoprothiolane concentrations varied based on the rice cooker type and whether the rice was pre-soaked. Immediate cooking using an electric- or pressure-cooker showed 78.5% and 78.4% reduction in brown rice, compared with 94.0% and 94.0% for polished rice, respectively. Pre-cooking immersion for 30 min showed similar reductions of 83.4% and 83.4% in brown rice, versus 95.8% and 95.8% in polished rice. The results of this study suggest that the most effective method for removing residual isoprothiolane from both brown rice and polished rice was to wash six times (with vigorous rubbing during the 2nd and 3rd washing) in 7-fold water at 40℃, followed by immersion for 30 min before cooking. Regardless of the type of rice cooker, heating is sufficient to remove an average of 83.4% and 95.8% of isoprothiolane from brown rice and polished rice, respectively.

• Journal of agriculture & life science
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• v.53 no.5
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• pp.137-143
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• 2019

To manufacturing of solid fuel by reuse of the wastes, the drying unit which have 500 kg/hr of drying capacity was developed and experimentally evaluate the performance. The spinach grown in Nam-hae island were used for the experiments and investigated of the heated-air drying characteristics as the inlet amount of raw materials, raw material stirring status, conveying type and drying time. The drying air heated by the energy derived from the steam which is supplied from the incineration plant. The moisture contents of raw materials were measured 85.65%. The inlet flow rate of drying air made a difference as the depth of the raw materials loaded on the drying unit and temperature has showed 108~144℃. The drying speed of the mixed drying more than doubled as that of non mixed drying under the same drying type, inlet amount, drying time and drying air temperature. In each experiment, the drying capacity have showed over 500 kg/hr. A drying efficiency of the ratio of drying consumption energy to input energy was 33.46%, lower than the average of 57.76% for the 157 conventional dryers. Because developed dryer must have a drying time of less than one hour, it is considered that the dry efficiency has been reduced due to the loss of wind volume during drying. If waste heat from incineration plant is used as a direct heat source, the dry air temperature is expected to be at least 160℃, greatly improving the drying capacity.