• Journal of the Society of Cosmetic Scientists of Korea
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• v.21 no.2
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• pp.94-111
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• 1995

In this study, the relationship between partition coefficients(Kw) of oils and antimicrobial effects Ivas investigated. The antimicrobial activity of paraben has been known to be controlled by the concentration of the paraben in the aqueous phase. The concentration of paraben in the aqueous phase was measured by the UV/VIS spectrophotometer at the wavelength of 256nm. It was found that the hydrocarbon oils and silicone oils had the lowest Kw value(<1.0) among the tested oils. Also, the emulsions which were made of oils having low Kw values had a good antimicrobial effects. Thus, the cosmetic safety against microorganisms could be improved by using the oils which have low Kw values.

• Proceedings of the Korean Fiber Society Conference
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• 1990.06b
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• pp.8-8
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• 1990

A new method for the graft polymerization of acrylonitrile onto starch is presented. Graft polymerization of acrylonitrile onto starch and the subsequent hydrolysis in sodium hydroxide solution to prepare absorbents is well known. This process has been utilized to produce the commercial product, Super Slurper. In a typical batch process, ~5% starch in water mixture is gelatinized at $95^{\circ}C$ under stirring for 1 hour then cooled to room temperature. The graft polymerization itself is carried out for approximately 2 hours at $25~30^{\circ}C$ on the gelatinized starch by eerie ion initiation. In this study, graft polymerization of acrylonitrile onto starch via a reactive extrusion process which is a continuous, efficient process is described. Initial concentration of starch in water is 35% and the reaction temperatures are between $50~80^{\circ}C$. However, the most significant difference in the reactive extrusion process is the short time in which the graft polymerization takes place. Preliminary results on the properties of graft polymerization products obtained from the reactive extrusion process are compared to those obtained from the batch process as well as the absorbency of the hydrolyzed samples. Absorbent material has also been prepared by sequential grafting and saponification in the extruder followed by a 2 hour heat treatment of the extrudate in an air circulated oven at $100^{\circ}C$.

• Carbon letters
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• v.8 no.3
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• pp.191-198
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• 2007

Recent studies have revealed the poisonous nature of aluminum(III) species to aquatic and terrestrial organisms. Therefore, this investigation aims to develop batch adsorption experiments in the laboratory, aiming to the removal of aluminum(III) from aqueous solutions onto powdered activated carbon (PAC). The latter (which is an effective and inexpensive sorbent) was prepared from olive stones generated as plant wastes and modified with an aqueous modifying oxidizing agent, viz. $HNO_3$. The main parameters (i.e. initial solution pH, sorbent and $Al^{3+}$ ions concentrations, stirring times and temperature) influencing the sorption process were examined. The results obtained revealed that the sorption of $Al^{3+}$ ions onto PAC is endothermic in nature and follows first-order kinetics. The adsorption data were well described by the Langmuir, Freundlich and Dubinin-Radushkevich (D-R) adsorption models over the concentration range studied. Under the optimum experimental conditions employed, the removal of ca. 100% $Al^{3+}$ ions in the concentration range $1.35-2.75\;mg{\cdot}l^{-1}$ was attained. Moreover, the procedure was successfully applied to the recovery of aluminum spiked to some environmental water samples with an RSD (%), does not exceed 1.22%.

• Journal of Radiation Industry
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• v.4 no.3
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• pp.265-269
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• 2010

Silicon-based non-oxide ceramic carbide fiber is one of the leading candidate ceramic materials for engineering applications because of its excellent mechanical properties at high temperature and good chemical resistance. In this study, polycarbosilane(PCS) and zirconium butoxide were used as a precursor to prepare polyzirconocarbosilane (PZC) fibers. A polymer solution was prepared by dissolving PCS in zirconium butoxide (50/50 wt%). This solution was heated at $250^{\circ}C$ in a nitrogen atmosphere for 2 hour with stirring, and then dried in a vacuum oven for 48 hour. PZC fibers were fabricated using an electrospinning technique. The fibers were irradiated with an electron beam to induce structural crosslinking. Crosslinked PZC fibers were heat treated at $1,300^{\circ}C$ in a nitrogen atmosphere. The microstructures of PZC fibers were examined by SEM. Chemical structures of PZC fibers were examined by FT-IR and XRD. Thermal stability of PZC fibers was investigated by TGA.

• Korean Journal of Materials Research
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• v.29 no.10
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• pp.603-608
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• 2019

Plastic waste is becoming a problem in various countries because of the difficulty of natural decomposition. One type is PET plastic(Polyethylene Terephthalate), which is often used as a bottle for soft drink packaging, and LDPE(Low Density Polyethylene), which is also widely used as a food or beverage packaging material. The use of these two types of plastic continuously, without good recycling, will have a negative impact on the environment. Building material waste is also becoming a serious environmental problem. This study aims to provide a solution to the problem of the above plastic waste and building material waste by making them into a mixture to be used as bricks. Research is carried out by mixing both materials, namely plastic heated at a temperature of $180-220^{\circ}C$ and building material waste that had been crushed and sized to 30-40 mesh with homogeneous stirring. The ratios of PET and LDPE plastic to building material waste are 9 : 1, 8 : 2, 7 : 3, 6 : 4 and 5 : 5. After heating and printing, density, water absorption and compressive strength tests are carried out. Addition of PET and LDPE plastic can increase compressive strength, and reduce water absorption, porosity and density. A maximum compressive strength of 10.5 MPa is obtained at the ratio of 6 : 4.

• Journal of Apiculture
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• v.32 no.4
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• pp.391-394
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• 2017

Propolis is made by bees collecting protective material or essence of plants and mixing with saliva and enzymes produced by the salivary glands. It is used to repair the inside of the honeycomb, keep it sterile, and adjust the temperature and humidity. Propolis is a natural antibiotic substance that it is used to make a clean room by coating the cell before the queen bee lay eggs, and preventing the bacteria from invading by using with wax when sealing the nursery room. Propolis extract is a health functional food with antioxidant and oral antimicrobial effects. In order to use propolis in food, its active ingredients are extracted with ethanol. Water-soluble propolis was prepared by mixing and stirring honey and ethanol extracted propolis (EEP) solution. When 1kg of honey and 100ml of ethanol extracted propolis solution were mixed and stirred, the total flavonoid content of water-soluble propolis was $6.6{\pm}1.1mg/10g$, and the free radical scavenging effects of water-soluble propolis were 54 to 74%.

• Textile Coloration and Finishing
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• v.30 no.4
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• pp.275-287
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• 2018

In recent years, research on the development of eco-friendly synthetic suede based on water-dispersed polyurethane resin and non-fluorine water repellent has been conducted. Synthetic suede has a problem that the fastness to dyeing is greatly lowered after the water-repellent processing at a high temperature of $160^{\circ}C$ because the polyester is dyed with a disperse dye. Therefore, in this study, silica was added to water-dispersed polyurethane resin to improve dye fastness. To distribute the $PUD-SiO_2$ mixture evenly in the water-dispersed polyurethane resin, sufficient stirring was done for a period of time. When the $PUD-SiO_2$ mixture(PUD 1-5%) is applied to the substrate, it is confirmed through SEM that the mixture is uniformly applied without particle condensation. The results showed that silica with a diameter of 4~12nm and BET of $200{\sim}380g/m^2$ had the ability to improve dispersibility and fastness.

• Journal of the Korean Society for Heat Treatment
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• v.32 no.3
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• pp.124-130
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• 2019

Friction stir welding is one of the interesting welding methods for titanium and its alloy which proceeds with plastic flow due to thermo-mechanical stirring and friction heat. Solid-state welding can solve severe problems such as high-temperature oxidation, interstitial oxygen diffusion and grain coarsening by liquid-state welding. Dynamic recrystallization and grain refinement can vary significantly with the plunging load and rotational speed of tool during friction stir welding, and suitable process conditions must be optimized to obtain microstructure and better mechanical characteristics. Suitable FSW conditions were 1000 kg of plunging load and 200 rpm of rotational speed and it showed YS 270 MPa, UTS 332.1 MPa, and El 17.3%, which were very similar to those of wrought titanium sheet.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.423-432
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• 2022

Magnetic biochar produced from pyrolysis of dairy cattle manure was used to develop an effective sorbent for arsenic purification from aqueous solution. Biomass and magnetized biomass were pyrolyzed in a tube furnace with 10 ℃/min heating rate at 450 ℃ under nitrogen flow of 100 cm³/min for 2 h. Biochars were characterized by SEM-EDX, BET, XDR, FTIR, TGA, zeta potential analysis. The resultant biochar and magnetic biochar were opposed to 50-100-500 ppm As(V) laden aqueous solution. Adsorption experiments were performed by using ASTM 4646-03 batch method. The effects of concentration, pH, temperature and stirring rate on adsorption were evaluated. As(V) was successfully removed from aqueous solution by magnetic biochar due to its highly porous structure, high aromaticity and polarity. The results suggest dairy cattle manure pyrolysis is a promising route for managing animal manure and producing a cost effective biosorbent for efficient immobilization of arsenic in aqueous solutions.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.28 no.1
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• pp.7-14
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• 1995

As a part of the multidisciplinary oceanographic study for the productivity enhancement in Deukryang Bay, temperature and salinity were observed from 1992 through 1993. From the results, only the data in summer of two years are compared. Owing to the contrary meteorolgical conditions in both summers both of temperature and salinity had the patterns of horizontal distributions quite different from each other. In 1992 with low precipitation, there was a tendency of temperature increase and salinity decrease from the bay mouth towards the bay head. In 1993 when the air temperature was abnormally low, isotherms and isotherms tended to be parallel to the local u3s of the bay where the warmer and less saline water distributed along the western coast. Reduced solar radiation and increase in the relative importance of the distribution of properties along the current that was parallel to the axis of the bay could be responsible for this result. Vertical structures of both temperature and salinity were dependent on the stirring effect of tidal current. Stratification was destroyed during the spring tide while it was formed during the neap tide.