• 한국재료학회지
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• 제30권1호
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• pp.8-13
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• 2020

Effect of heat treatment on microstructure and mechanical properties of an Fe-6.5Mn-0.08C medium-manganese steel is investigated in this study. Three kinds of medium-manganese steel specimens are fabricated by varying heat treatments of intermediate quenching (IQ), step quenching (SQ), and intercritical annealing (IA). Hardness and tensile tests are performed to examine the correlation of microstructure and mechanical properties for the Fe-6.5Mn-0.08C medium-manganese steel specimens. The IQ and SQ specimens have microstructures of martensite matrix with ferrite, whereas IA specimen exhibits microstructure of acicular ferrite matrix with martensite. The tensile test results show that the SQ specimen with martensite matrix has the highest yield strength and the lowest elongation. On the other hand, the SQ specimen has the highest hardness due to the relatively lower reduction of carbon content in martensite during intercritical annealing. According to the fractography of tensile tested specimens, the SQ specimen exhibits a dimple and quasi-cleavage fracture appearance while the IQ and IA specimens have fully ductile fracture appearance with fine-sized dimples caused by microvoid coalescence at ferrite and martensite interface.

• 대한금속재료학회지
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• 제46권12호
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• pp.800-808
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• 2008

Heat treatment is an important step for tool manufacture, but unavoidably generates dimensional distortion. This study investigated the continuous dimensional change and the anisotropic behavior of STD11 tool steel during austenitizing and tempering heat treatment especially using quenching dilatometer. Dilatometric results represented that the dimensional change along longitudinal direction was larger than that along transverse direction. Anisotropic phase transformation strain was produced in forged STD11 tool steel during heat treatment. Anisotropic dimensional change increased with increasing austenitizing temperature. After tempering, anisotropic distortion was partially reduced. FactSage thermodynamic equilibrium phase simulation and microstructural observation (FE-SEM, TEM) showed that large ($7{\sim}80{\mu}m$) elongated $M_7C_3$ carbides could be formed along rolling direction. The resolution of elongated carbides during austenitizing was found to be related with the change of martensite transformation temperature after heat treatment. Anisotropic size change of STD11 tool steel was mainly attributed to large elongated carbides produced during rolling process. Using dilatometric and metallographic examination, the possible mechanism of the anisotropic size change was also discussed.

• 한국표면공학회지
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• 제47권4호
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• pp.192-197
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• 2014

Red-emitting nitride phosphors recently attracted considerable attention because of their high thermal stability and high color rendering index properties. For excellent phosphor of white light-emitting-diode, ternary nitride phosphor of $Sr/SmSi_5N_8:Eu^{2+}$ with different $Eu^{2+}$ ion concentration were synthesized by solid state reaction method. In this work, red-emitting nitride $Sr/SmSi_5N_8:Eu^{2+}$ phosphor was successfully synthesized by using multi-step high frequency induction heat treatment. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Sr/SmSi_5N_8:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Sr/SmSi_5N_8:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 300 - 550 nm, namely from UV to visible area with distinct enhanced emission peaks. With an increase of $Eu^{2+}$ ion concentration, the peak position of emission in spectra was red-shifted from 613 to 671 nm. After via multi-step heat treatment, prepared phosphor showed excellent luminescence properties, such as high emission intensity and low thermal quenching, better than commercial phosphor of $Y_3Al_5O_{12}:Ce^{3+}$. Using $Eu_2O_3$ as a raw material for $Eu^{2+}$ dopant with nitrogen gas flowing instead of using commercial EuN chemical for $Sr/SmSi_5N_8:Eu^{2+}$ synthesis is one of characteristic of this work.

• 한국재료학회지
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• 제4권5호
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• pp.524-534
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• 1994

소량의 misch metal과 Zr을 함유한 CuZnAI형상기억 합금의 변태온도에 미치는 열사이클 및 기계적 성질 변화에 대하여 고찰하였다. 합금원소 첨가에 따라 결정립에 매우 미세화 되었으며 용체화 처리후 100~$350^{\circ}C$구간에서 경도값 변화를 조사하기 위하여 post quench aging과 step quench aging처리한 결과 $200^{\circ}C$와 $250^{\circ}C$에서 최고의 경도값을 나타냈다. $M_f$온도이하에서 인당시험한 결과 파단강도와 연실율은 결저립이 미세할수록 증가하는 경향을 보였다. 또한 파단강도는 as quenching처리한 경우보다 post quench aging처리한 경우에 보다더 증가하였다. $\beta$-상에서의 시효는 $M_s$온도를 강하시켰으며 마르텐사이트상에서의 시효는 $A_s$ 온도를 증가시켰다. post quench aging 에 따른 $A_s$의 변화는 $\beta$에서의 회복율에 기여하였으며 변태온도 ($A_s-M_s$)히스테리시스는 열사이클에 의하여 증가하는 경향을 보였다.

• Nuclear Engineering and Technology
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• 제24권3호
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• pp.297-310
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• 1992

RELAP5/MOD3 5M5코드의 Apollo version을 이용하여 FLECHT SEASET 강제 재관수 실험을 평가하였다. 이 연구의 주 목적은 출력과 관수율의 초기값이 각기 다른 강제 재관수 조건하에서의 코드치 예측능력을 검사하는 것이 다. 많은 실험 중에서 8가지 경우에 대해 평가하였다. 이 8 가지 경우는 출력과 관수율외의 다른 초기 조건들은 유사한 값들을 갖는 것들이다. 또한 RELAP5/MOD3의 개선된 모델(model)들에 대해 여러 가지 민감도분석을 하였다. 즉 test section의 outlet junction에서의 Counter Current Flow Limit (CCFL) option의 영향과 heat structure와 interfacial drag의 계산에 미치는 grid modelling의 영향과 nodalization의 영향 및 time step size 의 영향등을 분석하였다. 이러한 민감도분석을 통해 코드의 예측능력을 향상시킬 수 있었다. 평가 결과로는 RELAP5/MOD3가 국소최대온도 (turn around temperature)와 그때의 시간 (turn around time)을 일반적으로 낮게 예측하나 관수율이 큰경우에는 국소최대온도를 약간 과대 평가 하였다. 또한 출력이 증가하고 관수율이 감소할수록 RELAP5/MOD3가 quenching을 상대적으로 지연시킴을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.299-305
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• 2003

Physical properties and microstructure of new coumarin 4 doped $SiO_2$-PDMS ORMOSILs, synthesized by one-step (OS, acid-catalysis) and two-step (TS, acid-base catalysis) routes of sol-gel method with varying pH (0.6 to 7) and dye content $(5\;{times}\;10^{-4}\;to\;5{\times}\;10^{-2}\;mole)$, are reported. BET, UV-visible spectroscopy and SEM were used for characterizations. The increase in acid or base concentration increased the size of pores and aggregated silica particles. The samples with pH ≤ 2.5 were transparent and attributed to the small size of pores (~20 Å) and silica particles. The samples with pH > 2.5 were translucent or opaque due to non-uniform pore system formed by voids and large aggregated silica particles. The surface area was found a key factor controlling the interactions between the gel matrix and the dye. The OS samples with the highest dye concentration exhibited the minimal values of pore size, surface area and silica particle size, resulting in the concentration-quenching phenomenon.

• 대한기계학회논문집B
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• 제29권12호
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• pp.1352-1359
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• 2005

Unsteady simulations were performed to investigate the flame structure and the dynamic behavior of a premixed flame exposed to the wall heat loss. A 3-step global reaction mechanism was adopted in this study. Simulations were performed for two tube combustors with inner diameters($d_i$) of 1mm and 4mm. The material of tube combustor was assumed to be a Silicon Nitride($Si_{3}N_4$). The heat loss from the outer tube wall was controlled by adjusting the amount of convective and radiative heat loss. A conical premixed flame could be stabilized inside a tube of $d_i=4mm$. The flame stability inside a tube of $d_i=4mm$ combustor was not much sensitive to the amount of heat loss. In case of a tube of $d_i=1mm$, an oscillating flame was observed in very low heat loss condition and a flame could not be sustained in realistic heat loss condition.

• Nuclear Engineering and Technology
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• 제34권4호
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• pp.344-357
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• 2002

The present paper reports spontaneous steam explosions observed in fuel coolant interaction experiments using prototypic reactor materials. Pure ZrO$_2$ and a mixture of UO$_2$ and ZrO$_2$ are used. A high temperature molten material in the form of a jet is poured into a subcooled water pool located in a pressure vessel. An induction skull melting technique is used for the melting of the reactor material. In both tests using pure ZrO$_2$ and a mixture of UO$_2$ and ZrO$_2$, either a quenching or a spontaneous steam explosion was observed. The morphology of debris and pressure profile clearly indicate the differences between the qunching cases and explosion cases. The dynamic pressure. dynamic impulse, water temperature, melt temperature, and static pressure Inside the containment chamber were measured . As the spontaneous steam explosion for the reactor material is firstly observed in the present experiments, the results of present experiments could be a siginificant step forward the understanding the explosion of the reactor material.

• 한국기계가공학회지
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• 제20권6호
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• pp.10-16
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• 2021

Drilling is a crucial process that takes up a significant amount of weight during machining operations. In addition, drill tip-type tools and related operations have been developed for manufacturing industries to achieve economic efficiency. In this study, SM45C carbon steel, widely used for machine structures, was utilized as the working material after quenching and tempering. Insert-tip types of carbide tools, such as TiN and TiAlN, were used as tool materials. Drilling conditions such as the spindle revolution, feed rate, step of cut, and tool diameter were used to measure roughness, roundness, and straightness using the orthogonal array table statistical method. The surface roughness, roundness, and straightness characteristics based on the conditions were analyzed using ANOVA. The results showed that the spindle speed and feed rate were the main factors influencing carbide insert-tip drilling under the same conditions as the experimental conditions.

• 열처리공학회지
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• 제36권6호
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• pp.367-373
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• 2023

600 MPa-grade deformed bar samples were manufactured by conventional hot rolling and subsequent Tempcore heat treatment processes. Considering the short-time water quenching step of the Tempcore process for hot-rolled steel, it is inevitable that the temperature profile of the deformed bar depends strongly on its position throughout the sample thickness. As a result, its microstructure can be easily divided into two regions, the surface and the core regions. The former is expected to have a fresh martensite microstructure under rapid cooling conditions, but self-tempering occurs due to the intense heat flow from the hot core region after the process. The latter is generally known to exhibit a mixed microstructure of ferrite and pearlite due to its slow cooling rate. In this study, detailed microstructural evolutions were examined through the thickness direction. The large variation of the microstructure through the thickness direction in the deformed bar samples is partly due to the easy carbon diffusion from the limited additions of alloying elements.