• Corrosion Science and Technology
• /
• v.14 no.3
• /
• pp.127-131
• /
• 2015

Model alloys Fe-9Cr, Fe-20Cr and Fe-20Cr-20Ni (wt. %) with 0.1 and 0.2 % Si were exposed to $Ar-20CO_2-20H_2O$ gas at $818^{\circ}C$. The undoped alloys formed a thick iron-rich oxide scale. The additions of Si reduced scaling rates of Fe-9Cr to some extent but significantly suppressed the formation of iron oxide scales on Fe-20Cr and Fe-20Cr-20Ni. Carburisation also occurred in all undoped alloys, but not in Si-containing Fe-20Cr and Fe-20Cr-20Ni. Protection against carburisation was a result of the formation of an inner scale layer of silica.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2002.05a
• /
• pp.844-847
• /
• 2002

This paper is to investigate the wear behavior of submerged-arc clad materials by the wear test with a ball-on-disk type wear testing machine in air. The specimens were clad with Stoody105 alloy wire on a carbon steel (SM45C) substrate by submerged-arc cladding process under different welding parameters. The wear behavior of the cladding through ball-en-disk test has been studied under the wear load from 5N to 16N and sliding speed from 8cm/s to 35cm/s. The weight of the specimen loss was measured. Scanning electron micrographs of the worn surface show a layer of oxide film formed on the worn surface. Oxidation wear mechanism controls the wear process. The spalling of the oxide is caused by the repeated rubbing fatigue mechanism.

• Journal of the Korean Society for Precision Engineering
• /
• v.20 no.1
• /
• pp.179-186
• /
• 2003

This paper is to investigate the wear behavior of submerged-arc claddings by the wear test with a ball-on-disk type wear testing machine in air. The specimens were clad with Stoody105 alloy wire on a medium carbon steel (SM45C) substrate by submerged-arc cladding process under different welding parameters. The wear behavior of the cladding through ball-on-disk test has been studied under the wear load from 5 to 16 N and the sliding speed from 8 to 35 cm/s. The weight loss of the specimen was measured. Scanning electron micrographs of the worn surface show a layer of oxide film formed on the worn surface. Oxidation wear mechanism controls the wear process. The spatting of the oxide is caused by the repeated rubbing fatigue mechanism.

• Journal of the Korean Ceramic Society
• /
• v.31 no.7
• /
• pp.767-771
• /
• 1994

In a salb-preheating furnace of steel-making industry, the oxidation/degradation behavior of Cr3C2 ceramic composited dkid button reaction with scale in Fe-oxide system occurs and was thermodynamically examined. The reaction of scale with Cr3C2 skid button produces Cr3C2(s) and C(s), and Co gas is then evolved from the reaction of C(s) with Fe-scale. Cr3C2(s) from oxidation of Cr3C2(s) reacted with Fe-oxide(s) becomes high-melting chromite. The chromite acts as protection layer against further oxidation and improves resistance of the reaction of Cr3C2 skid button with Fe-scale.

• Corrosion Science and Technology
• /
• v.15 no.2
• /
• pp.92-107
• /
• 2016

Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.

• Journal of the Korean Society for Heat Treatment
• /
• v.19 no.2
• /
• pp.90-95
• /
• 2006

Nitriding or carburizing of carbon steels results in good mechanical properties such as high surface hardness and wear resistance but it has no affection on the corrosion resistance. Corrosion properties of nitriding and carburizing steels could be deteriorated. So, recently, there have been great demand for oxi-nitriding to enhance both mechanical properties and corrosion resistance. In this study, the corrosion resistance of carbon steel, S35C, and free cutting steel, SUM222, are prepared by vacuum nitriding and vacuum post-oxidation were compared with those treated by nitriding. After vacuum post-oxidation, $5{\mu}m$ oxide layer was formed on the nitride layer with $20{\sim}30{\mu}m$ depth. Potentio-dynamic polarization curve in corrosion test showed that the corrosion potential after post oxidation was increased from 200 mV to 800 mV in S35C and from 600 mV to 1200 mV in SUM222. SEM analyses showed that pores was increased and surface roughness became rougher with post oxidation. However, the formation of $Fe_3O_4$ resulted in the enhanced corrosion resistance of steels.

• Nuclear Engineering and Technology
• /
• v.52 no.5
• /
• pp.908-917
• /
• 2020

Corrosion of structural materials presents a critical challenge in the use of lead-bismuth eutectic (LBE) as a nuclear coolant in an accelerator-driven system. By forming a protective layer on the steel surfaces, corrosion of steels in LBE cooled reactors can be mitigated. The amount of oxygen concentration required to create a continuous and stable oxide layer on steel surfaces is related to the oxidation process. So far, there is no oxidation experiment in fuel assemblies (FA), let alone specific oxidation detail information. This information can be, however, obtained by numerical simulation. In the present study, a new coupling method is developed to implement a coupling between the oxygen mass transfer model and the commercial computational fluid dynamics (CFD) software ANSYS-CFX. The coupling approach is verified. Using the coupling tool, we study the oxidation process of the FA and investigate the effects of different inlet parameters, such as temperature, flow rate on the mass transfer process.

• Metals and materials international
• /
• v.24 no.6
• /
• pp.1232-1240
• /
• 2018

Corrosion properties of dissimilar friction stir welded 6061 aluminum and HT590 steel were investigated to understand effects of galvanic corrosion. As cathode when coupled, HT590 was cathodically protected. However, the passivation of AA6061 made the aluminum alloy cathode temporarily, which leaded to corrosion of HT590. From the EIS analysis showing Warburg diffusion plot in Nyquist plots, it can be inferred that the stable passivation layer was formed on AA6061. However, the weld as well as HT590 did not show Warburg diffusion plot in Nyquist plots, suggesting that there was no barrier for corrosion or even if it exists, the barrier had no function for preventing and/or retarding charge transport through the passivation layer. The open circuit potential measurements showed that the potential of the weld was similar to that of HT590, which lied in the pitting region for AA6061, making the aluminum alloy part of the weld keep corrosion state. That resulted in the cracked oxide film on AA6061 of the weld, which could not play a role of corrosion barrier.

• Progress in Superconductivity and Cryogenics
• /
• v.8 no.3
• /
• pp.23-26
• /
• 2006

For mechanical and electrical stability and environment protection. Cu and stainless steel stabilizers are laminated to a Ag layer to produce a composite neutral-axis(N-A) architecture in which the YBCO layer is centered between the oxide buffered metallic substrate and stabilizer strip lamination. This architecture allows the wire to meet operational requirements including stresses at cryogenic temperature. winding tensions as well as mechanical bending requirements including thermal and electrical stability under fault current conditions. We have experimentally studied mechanical properties of the laminated stainless steel and Cu stabilizers on YBCO coated conductors. We have laminated YBCO coated conductors by continuous dipping soldering process. We have investigated lamination interface between solder and stabilizer of the YBCO coated conductor. We evaluated bonding properties. tensile / shear bonding strength. and peeling strength laminated YBCO coated conductors.

• Journal of Welding and Joining
• /
• v.23 no.1
• /
• pp.69-76
• /
• 2005

Recently, application of arc welding to galvanized carbon steel sheet is on the increasing Ould in the fields of automobile and construction industries. In arc welding process, zinc is evaporated in weld pool, even under the appropriate welding condition and produce blowhole and/or pit. Zinc gas cause instability of arc and increase spatter and fume. This research is purposed to minimize the heat-input and the formation of porosities in the welded joint of the galvanized carbon steel sheet using variable polarity AC wave pulse MIG welding system. An appropriate welding condition which showed low spatter and good bead appearance was acquired by applying the AC pulse MIG welding machine to DC duplicated MIG welding with the solid wire. When oxygen gas was added to shield gas of MIG welding for galvanized steel sheet, arc length was increased and arc stability was improved. In the AC duplicated welding, the loss of galvanized layer was decreased as the amount of heat-input was decreased when the EN ratio was increased under the condition that average welding current was evenly set.