• Journal of the Korean Society of Combustion
• /
• v.16 no.3
• /
• pp.1-11
• /
• 2011

The main objective of this paper is to investigate characteristic of steam reformer at various geometries and operating conditions. In this paper, the steam reforming is studied by a numerical method and three dimensional simulations were used for effective analytical study. User - Defined Function (UDF) was used to simultaneously calculate reforming and combustion reaction. And the numerical model is validated with experimental results at the same operating conditions. In order to understand the relationship between operating conditions such as gas hourly space velocity(GHSV), mass flow rate of combustor inlet, various numerical investigations are carries out for various geometries. Numerical results show that cylindrical geometry is more effective than rectangular geometry for heat transfer to reactors and reforming efficiency. As mass flow rate of combustor inlet increase, reaction occurs more faster and temperature increase with each geometry. On the other hand, reaction and hydrogen conversion decrease as mass flow rate of reactor decreases.

• Nuclear Engineering and Technology
• /
• v.47 no.7
• /
• pp.907-914
• /
• 2015

The energetic steam explosion caused by contact between the high temperature molten core and water is one of the phenomena that may threaten the integrity of the containment vessel during severe accidents of light water reactors (LWRs). We examined the dependence of steam explosion loads in a typical reactor cavity geometry on selected model parameters and initial/boundary conditions by using a steam explosion simulation code, JASMINE, developed at Japan Atomic Energy Agency (JAEA). Among the parameters, we put an emphasis on the water pool depth that has significance in terms of accident mitigation strategies including cavity flooding. The results showed a strong correlation between the load and the premixed mass, defined as the mass of the molten material in low void zones (void fraction < 0.75). The jet diameter and velocity that comprise the flow rate were the primary factors to determine the premixed mass and the load. The water pool depth also showed a significant impact. The energy conversion ratio based on the enthalpy in the premixed mass was in a narrow range ~4%. Based on this observation, we proposed a simplified method for evaluation of the steam explosion load. The results showed fair agreement with JASMINE.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.39 no.3
• /
• pp.261-269
• /
• 2015

In this study, numerical analysis of curved channel steam-methanol reformer was conducted using the computational fluid dynamics (CFD) commercial code STAR-CCM. A pre-numerical analysis of reference model with a cylindrical channel reactor was performed to validate the combustion model of the CFD commercial code. The result of advance validation was in agreement with reference model over 95%. After completing the validation, a curved channel reactor was designed to determine the effects of shape and length of flow path on methanol conversion efficiency and generation of hydrogen. Numerical analysis of the curved-channel reformer was conducted under various flow rate ($10/15/20{\mu}l/min$). As a result, the characteristics of flow and mass transfer were confirmed in the cylindrical channel and curved channel reactor, and useful information about methanol conversion efficiency and hydrogen generation was obtained for various flow rate.

• Clean Technology
• /
• v.19 no.4
• /
• pp.379-387
• /
• 2013

Ethanol steam reforming reaction considered as a clean hydrogen production method is introduced in this paper. Reactivity and reaction rate equation of ethanol steam reforming reaction using various catalysts, reaction temperature, and molar ratio of ethanol and water will be discussed. In addition to introducing a membrane reactor combining a reactor and a separator, the effect of the use of a membrane reactor on an ethanol conversion and hydrogen yield will be compared to those from a conventional packed-bed reactor.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.113-116
• /
• 2007

Performance of a steam reformer can be improved by using a coaxial cylindrical reactor, because the design can enhance the heat transfer for the steam reforming reaction, which is the one of main rate-determining steps of overall reactions. The objective of this study is to investigate the coaxial cylindrical reactor numerically. Pseudo-homogeneous model and one medium approach are incorporated for the chemical reactions, and models are validated with experimental results. The catalyst of the coaxial cylindrical reactor is 67% for one of the cylindrical reactor, but fuel conversion of the coaxial cylindrical reactor is increased by 10%. Heat flux profiles are investigated by modified Nusselt number and heat flux which is transported from the product gas to the catalyst bed affecting performance of the steam reformer.

• Asian-Australasian Journal of Animal Sciences
• /
• v.15 no.9
• /
• pp.1354-1358
• /
• 2002

Two hundred and ten post-larvae (PL) of Macrobrachium rosenbergii (14.5-14.9 mg) were equally distributed in two experimental groups and fed with either steam cooked or extruded pellet for a period of 60 days. Physical evaluation and growth promoting effect of both the pellets were assessed. Significantly higher (p<0.05) water stability, absorption and protein efficiency ratio (PER) were recorded in extruded pellet than the steam cooked pellet. Nutrient loss was minimum in the extruded pellet for which lower feed conversion ratio (FCR) (p<0.05) was recorded in this group. However, weight gain, relative growth and specific growth rate (SGR) in both the groups were not significantly different (p>0.05). Although insignificant (p>0.05) but higher amylase activity was recorded in steam pellet fed group. Survival was not affected by feeding either of the diets.

• Clean Technology
• /
• v.28 no.1
• /
• pp.1-8
• /
• 2022

To confirm the applicability of the water gas shift reaction for the production of high purity hydrogen for petroleum cokes, an unutilized low grade resource, Cu/ZnO/MgO/Al₂O₃ (CZMA), catalyst was prepared using the co-precipitation method. The prepared catalyst was analyzed using BET and H₂-TPR. Catalyst reactivity tests were compared and analyzed in two cases: a single LTS reaction from syngas containing a high concentration of CO, and an LTS reaction immediately after the syngas passed through a HTS reaction without condensation of steam. Reaction characteristics in accordance with steam/CO ratio, flow rate, and temperature were confirmed under both conditions. When the converted low concentration of CO and steam were immediately injected into the LTS, the CO conversion was rather low in most conditions despite the presence of large amounts of steam. In addition, because the influence of the steam/CO ratio, temperature, and flow rate was significant, additional analysis was required to determine the optimal operating conditions. Meanwhile, carbon deposition or activity degradation of the catalyst did not appear under high CO concentration, and high CO conversion was exhibited in most cases. In conclusion, it was confirmed that when the Cu/ZnO/MgO/Al₂O₃ catalyst and the appropriate operating conditions were applied to the syngas composition containing a high concentration of CO, the high concentration of CO could be converted in sufficient amounts into CO₂ by applying a single LTS reaction.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.33 no.11
• /
• pp.869-875
• /
• 2009

The purpose of this paper is to investigate the optimal condition of the syngas production by reforming of propane using Gliding arc plasma reformer. The gliding arc plasma reformer in 3 phases has been newly designed and developed with a quick starting and fast response time. It can be applicable to the various types of fuels (Hydrocarbons $C_xH_y$), and it has a high conversion rate of fuels and high production of hydrogen. The parametric screening studies were carried out according to the changes of a steam feed amount i.e., steam/carbon ratio, total gas flow rate and input electric power. The optimum operating conditions were S/C ratio 2.8, total gas flow rate of 14 L/min and input electric power of 2.4 kW. The result of optimum operating conditions showed the 55 % $H_2$, 14 % CO, 15 % $CO_2$, 10 % $C_3H_8$ and 4 % $CH_4$. Also, $C_3H_8$ conversion, $H_2$ yield and $H_2$ selectivity were 90 %, 42 %, 15 %, respectively. The energy efficiency and specific energy requirements were 37 % and 334 kJ/mol respectively.

• Applied Chemistry for Engineering
• /
• v.23 no.2
• /
• pp.204-209
• /
• 2012

In this study, kinetics data was obtained for steam reforming reaction of ethane over the commercial ruthenium catalyst. The variables of ethane steam reforming were the reaction temperature, partial pressure of ethane, and steam/ethane mole ratio. Parameters for the power rate law kinetic model and the Langmuir-Hinshelwood model were obtained from the kinetic data. Also, sizing of steam reforming reactor was performed by using PRO/II simulator. The reactor size calculated by the power rate law kinetic model was bigger than that of using the Langmuir-Hinshelwood model for the same conversion of ethane. Reactor size calculated by the Langmuir-Hinshelwood model seems to be more suitable for the reactor design because the Langmuir-Hinshelwood model was more consistent with the experimental results.

• Journal of the Korean Society of Combustion
• /
• v.16 no.1
• /
• pp.36-45
• /
• 2011

The heat-flow characteristics and reforming efficiency of steam reformer with combustor are numerically investigated at various operating conditions. SCR(Steam to Carbon Ratio) and GHSV(Gas Hourly Space Velocity) are adopted as important operating conditions. User-Defined-Function(UDF) was used to simultaneously calculate reforming and combustion reaction. Numerical results show that hot burned gas rise by a buoyant force and heat exchange between reforming reactors and cocurrent flow occurs in the combustion region. The results also indicate that an increase of SCR leads to decrease the mole fraction of hydrogen at the reactor outlet. As GHSV increases, conversion rate decreases.