• Title/Summary/Keyword: State transition

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Transition Rates in a Bistable System Driven by Singular External Forces

  • Cheol-Ju Kim;Dong Jae Lee
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.95-100
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    • 1993
  • A noise-induced transition is presented for a bistable system subjected to a multiplicative random force, which is singular at the unstable state. The stationary probability distribution is obtained from the Fokker-Planck equation and the effects of the singularity is analyzed. On the basis of noise-induced phase transition with Gaussian white noise, the relaxation time and the transition rate of the system are evaluated up to the first order correction of D. In the parameter region v < l, the transition rates decrease as the exponent v goes to 1 and as the coefficient of the linear term of the kinetic equation increases.

Finding Top-k Answers in Node Proximity Search Using Distribution State Transition Graph

  • Park, Jaehui;Lee, Sang-Goo
    • ETRI Journal
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    • v.38 no.4
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    • pp.714-723
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    • 2016
  • Considerable attention has been given to processing graph data in recent years. An efficient method for computing the node proximity is one of the most challenging problems for many applications such as recommendation systems and social networks. Regarding large-scale, mutable datasets and user queries, top-k query processing has gained significant interest. This paper presents a novel method to find top-k answers in a node proximity search based on the well-known measure, Personalized PageRank (PPR). First, we introduce a distribution state transition graph (DSTG) to depict iterative steps for solving the PPR equation. Second, we propose a weight distribution model of a DSTG to capture the states of intermediate PPR scores and their distribution. Using a DSTG, we can selectively follow and compare multiple random paths with different lengths to find the most promising nodes. Moreover, we prove that the results of our method are equivalent to the PPR results. Comparative performance studies using two real datasets clearly show that our method is practical and accurate.

Quantum Mechanical Studies for Proton Transfer in HOCl + HCl and H2O + ClONO2 on Water Clusters

  • Kim, Yong-Ho;Park, Chea-Yong;Kim, Kyung-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.1953-1961
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    • 2005
  • We have performed high-level quantum mechanical calculation for multiple proton transfer in HOCl + HCl and $H_2O$ + $ClONO_2$ on water clusters, which can be used as a model of the reactions on ice surface in stratospheric clouds. Multiple proton transfer on ice surface plays crucial role in these reactions. The structures of the clusters with 0-3 water molecules and the transition state structures for the multiple proton transfer have been calculated. The energies and barrier heights of the proton transfer were calculated at various levels of theory including multi-coefficient correlated quantum mechanical methods (MCCM) that have recently been developed. The transition state structures and the predicted reaction mechanism depend very much on the level of theory. In particular, the HF level can not correctly predict the TS structure and barrier heights, so the electron correlation should be considered appropriately.

Analytic Solution to the Spatial Propagation of the Flexible Structures (유연한 구조물의 공간전파에 관한 해석적 해법)

  • Seok, Jin-Yeong;Jeong, Eun-Tae;Kim, Yu-Dan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.12
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    • pp.2040-2047
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    • 2001
  • In this paper, a singularity problem of the state transition matrix is investigated in the spatial propagation when the spatial matrix differential equation is constructed via time finite element analysis. A parametric study shows that the degree of singularity of the state transition matrix depends on the degree of flexibility of the structures. As an alternative to avoid the numerical problems due to the singularity, an analytic solution fur spatial propagation of the flexible structures is proposed. In the proposed method, the spatial properties of the structure are analytically expressed by a combination of transcendental functions. The analytic solution serves fast and accurate results by eliminating the possibility of the error accumulation caused by the boundary condition. Several numerical examples are shown to validate the effectiveness of the proposed methods.

A Method of Interna State reduction in the Synthesis of Multipul-Input asynchronous Sequential circuits Using Transition-Sensitive Flip-Fops (다입력변화 천이응동비동기순서논리회로의 내부상태 감소법에 관한 연구)

  • 임재탁;이근영
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.2
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    • pp.22-26
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    • 1974
  • To synthesize transition-sensitive asynchronous sequential circuits, D-type transition-sensitive flip-flop is used.4 new concept, a pair of input state is introduced and used to reduce the number of internal states. We proposed an algorithm to synthesize multiple-input change asynchronous sequential circuits directly from a primitive state table an6 demonstrated the method is better than the one which is due to Bredeson and Hulina and Others.

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Estimating the Glass Transition of Oligosaccharides Mixtures through the State Diagram

  • Auh, Joong-Hyuck;Park, Kwan-Hwa
    • Food Science and Biotechnology
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    • v.14 no.2
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    • pp.301-303
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    • 2005
  • State diagram of highly concentrated branched oligosaccharides (HBOS) was constructed to better understand phase behavior of mixtures with different size of oligosaccharides. It showed dramatic plasticizing effect on glass transition, which was successfully described based on Couchman-Karasz equation model. $T_g$' estimated from state diagram corresponded well with previous empirical data measured by maximum ice formation through isothermal holding (annealing) process. Estimated $T_g$' and $C_g$' values were $-36.3^{\circ}C$ and 79.99%, respectively. $T_g$' value of HBOS was approximately $10^{\circ}C$ higher than that of sucrose, while $C_g$' value was similar to those of general carbohydrate materials, which could be useful for applications in frozen system.

Tracking Object Movement via Two Stage Median Operation and State Transition Diagram under Various Light Conditions

  • Park, Goo-Man
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.4
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    • pp.11-18
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    • 2007
  • A moving object detection algorithm for surveillance video is here proposed which employs background initialization based on two-stage median filtering and a background updating method based on state transition diagram. In the background initialization, the spatiotemporal similarity is measured in the subinterval. From the accumulated difference between the base frame and the other frames in a subinterval, the regions affected by moving objects are located. The median is applied over the subsequence in the subinterval in which regions share similarity. The outputs from each subinterval are filtered by a two-stage median filter. The background of every frame is updated by the suggested state transition diagram The object is detected by the difference between the current frame and the updated background. The proposed method showed good results even for busy, crowded sequences which included moving objects from the first frame.

Addition Reaction of Cyclopropane with Magnesium Dihydride (MgH2): A Theoretical Study

  • Singh, Satya Prakash;Meena, Jay Singh;Thankachan, Pompozhi Protasis
    • Journal of the Korean Chemical Society
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    • v.57 no.6
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    • pp.697-702
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    • 2013
  • The addition reaction of cyclopropane with $MgH_2$ has been investigated using the B3LYP density functional method employing several split-valence basis sets. Both along the and perpendicular to the cyclopropane ring approach has been reported. It is shown that the reaction proceeds via a four-centered transition state. Calculations at higher levels of theory were also performed at the geometries optimized at the B3LYP level, but only slight changes in the barriers were observed. Structural parameters for the transition state are also reported.

Correlation between the Reactant Complex or Transition State Conformations and the Reactivity of 4-Nitrophenyl Benzoate and Its Sulfur Analoguew with Anoinic Nucleophiles by Comparative Molecular Field Analysis (CoMFA)

  • 유성은;차옥자
    • Bulletin of the Korean Chemical Society
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    • v.17 no.7
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    • pp.653-655
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    • 1996
  • A comparative molecular field analysis (CoMFA) was carried out for the correlation of the transition state structures and the reaction rates for the SN2 reaction of 4-nitrophenyl benzoate and its sulfur analogs with anionic nucleophiles. The CoMFA analysis showed that both steric and electrostatic effects are important, and the steric contribution increased when nucleophiles are alkoxides or arylsulfides. In this study, we have demonstrated that the CoMFA analysis can be expanded beyond the scope of dealing with reactants and products. The reactant complex and transition state conformations generated along the reaction path can be more appropriately used for the correlation of structures and reaction rates.

An Artificial Intelligence Evaluation on FSM-Based Game NPC (FSM 기반의 게임 NPC 인공 지능 평가)

  • Lee, MyounJae
    • Journal of Korea Game Society
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    • v.14 no.5
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    • pp.127-136
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    • 2014
  • NPC in game is an important factor to increase the fun of the game by cooperating with player or confrontation with player. NPC's behavior patterns in the previous games are limited. Also, there is not much difference in NPC's ability among the existing games because it's designed to FSM. Therefore, players who have matched with NPCs which have the characteristics may have difficulty to play. This paper is for improving the problem and production and evaluation of the game NPC behavior model based on wolves hunting model in real life. To achieve it, first, the research surveys and studies behavior states for wolves to capture prey in the real world. Secondly, it is implemented using the Unity3D engine. Third, this paper compares the implemented state transition probability to state transition probability in real world, state transition probability in general game. The comparison shows that the number of state transitions of NPCs increases, proportions of implemented NPC behavior patterns converges to probabilities of state transition in real-world. This means that the aggressive behavior pattern of NPC implemented is similar to the wolf hunting behavior pattern of the real world, and it can thereby provide more player experience.