• 제목/요약/키워드: State transition

검색결과 1,895건 처리시간 0.025초

950℃ 불순물을 포함한 헬륨 환경에서 CVD β-SiC의 산화 (Oxidation of CVD β-SiC in Impurity-Controlled Helium Environment at 950℃)

  • 김대종;김원주;장지은;윤순길;김동진;박지연
    • 한국세라믹학회지
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    • 제48권5호
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    • pp.426-432
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    • 2011
  • The oxidation behavior of CVD ${\beta}$-SiC was investigated for Very High Temperature Gas-Cooled Reactor (VHTR) applications. This study focused on the surface analysis of the oxidized CVD ${\beta}$-SiC to observe the effect of impurity gases on active/passive oxidation. Oxidation test was carried out at $950^{\circ}C$ in the impurity-controlled helium environment that contained $H_2$, $H_2O$, CO, and $CH_4$ in order to simulate VHTR coolant chemistry. For 250 h of exposure to the helium, weight changes were barely measurable when $H_2O$ in the bulk gas was carefully controlled between 0.02 and 0.1 Pa. Surface morphology also did not change based on AFM observation. However, XPS analysis results indicated that a very small amount of $SiO_2$ was formed by the reaction of SiC with $H_2O$ at the initial stage of oxidation when $H_2O$ partial pressure in the CVD ${\beta}$-SiC surface placed on the passive oxidation region. As the oxidation progressed, $H_2O$ consumed and its partial pressure in the surface decreased to the active/passive oxidation transition region. At the steady state, more oxidation did not observable up to 250 h of exposure.

0.8 이상의 전기기계결합계수(k33)를 가지는 고효율 무연 압전 Ba(Ti0.94Zr0.06)O3 단결정 ("Lead-free" Piezoelectric Ba(Ti0.94Zr0.06)O3 Single Crystals with Electromechanical Coupling Factor (k33) Higher Than 0.8)

  • 이종엽;오현택;이호용
    • 한국세라믹학회지
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    • 제51권6호
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    • pp.623-628
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    • 2014
  • Orthorhombic $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals are fabricated using the cost-effective solid-state single crystal growth (SSCG) method; their dielectric and piezoelectric properties are also characterized. Measurements show that (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals have an electromechanical coupling factor ($k_{33}$) higher than 0.83, piezoelectric charge constant ($d_{33}$) of about 400 [pC/N], and piezoelectric voltage constant ($g_{33}$) higher than 50 [${\times}10^{-3}Vm/N$]. The transition temperature ($T_{OT}$) of the (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals between orthorhombic and tetragonal phases is also observed to be about $61^{\circ}C$. Because their electromechanical coupling factor ($k_{33}$) and piezoelectric voltage constant ($g_{33}$) are higher than those of soft PZT ceramics, it is expected that (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals can be used as "lead-free" piezoelectric materials in many piezoelectric applications.

복수 크레인을 활용한 블록 내 컨테이너 이적 계획 (A Heuristic Approach to Scheduling Multiple Cranes for Intra-Block Remarshalling)

  • 오명섭;강재호;류광렬;김갑환
    • 한국항해항만학회지
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    • 제29권5호
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    • pp.447-455
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    • 2005
  • 블록 내 이적이란 컨테이너를 선박에 싣는 적하 작업을 효율적으로 수행하기 위하여 유휴 시간에 여기저기에 흩어져 있는 대상 컨테이너들을 적하 순서에 맞춰 몇 개의 베이로 모으는 작업이다. 이적 작업을 가능한 일찍 완료하기 위해서는 블록 내의 설치된 여러 대의 트랜스퍼 크레인들을 모두 활용하는 것이 유리하지만, 이적 계획 수립 시 크레인들 간의 간섭을 효과적으로 고려하지 못하면 상당한 작업 지연이 발생할 수 있다. 특히, 상호 교차가 불가능한 크레인들을 이용하여 이적을 수행하고자 하는 경우에는 이러한 간섭에 의한 지연이 보다 빈번히 발생한다. 본 논문에서는 교차가 불가능한 크레인들 간의 간섭을 고려하여 개별 컨테이너를 취급할 크레인을 선정하고 작업 순서를 결정하는 휴리스틱을 제안한다. 시뮬레이션 실험 결과 본 제안 방안이 다양한 환경에서 간섭에 의한 지연을 효과적으로 줄일 수 있음을 확인하였다.

Boost Type ZVS-PWM Chopper-Fed DC-DC Power Converter with Load-Side Auxiliary Resonant Snubber and Its Performance Evaluations

  • Ogura, Koki;Chandhaket, Srawouth;Ahmed, Tarek;Nakaoka, Mutsuo
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • 제3B권3호
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    • pp.147-154
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    • 2003
  • This paper presents a high-frequency boost type ZVS-PWM chopper-fed DC-DC power converter with a single active auxiliary edge-resonant snubber at the load stage which can be designed for power conditioners such as solar photovoltaic generation, fuel cell generation, battery and super capacitor energy storages. Its principle operation in steady-state is described in addition to a prototype setup. The experimental results of boost type ZVS-PWM chopper proposed here, are evaluated and verified with a practical design model in terms of its switching voltage and current waveforms, the switching v-i trajectory and the temperature performance of IGBT module, the actual power conversion efficiency, and the EMI of radiated and conducted emissions, and then discussed and compared with the hard switching scheme from an experimental point of view. Finally, this paper proposes a practical method to suppress parasitic oscillation due to the active auxiliary resonant switch at ZCS turn-off mode transition with the aid of an additional lossless clamping diode loop, and can be reduced the EMI conducted emission.

로소나이트(Lawsonite)의 압력에 따른 등방성 압축거동 연구 (Isotropic Compression Behavior of Lawsonite Under High-pressure Conditions)

  • 임준혁;이용재
    • 자원환경지질
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    • 제49권1호
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    • pp.23-30
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    • 2016
  • 자연산 로소나이트(Ca-Lawsonite, $CaAl_2Si_2O_7(OH)_2{\cdot}H_2O$) 분말의 압력증가에 따른 변화와 구조적 특성을 소형 압력 발생장치인 다이아몬드 앤빌셀과 실시간 싱크로트론 X-선 회절실험을 통하여 확인하였다. 본 연구에서 시료에 적용한 압력은 1 기압에서 8 GPa 까지였으며 메탄올, 에탄올, 물의 혼합 용액을 압력 매개체로 하여 상온조건에서 실험하였고, 특이한 상전이나 압력하 부피변화의 이상현상은 발견되지 않은 가역적 압축특성을 관찰하였다. 최고압력까지 로소나이트는 결정성을 잃지 않는 것으로 확인되었고 압력증가에 따른 체적감소를 통해 체적탄성률($B_0$)을 계산해 본 결과 146(6) GPa로 도출되었다. 체적탄성률과 함께 계산된 선형압축률은 a-, b-, c-축에서 각각 0.0022, 0.0024, $0.0020GPa^{-1}$로 압력에 의한 부피감소는 대체적으로 3축이 같은 비율로 감소하는 것을 확인하였다.

Study on Environmental Changes of River in the Suburban Area and Transition of Relations between Residents and River

  • Hiroyuki Kaga;Kumi Kawano;Yasuhiko Shimomura;Noboru Masuda
    • Journal of the Korean Institute of Landscape Architecture International Edition
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    • 제2호
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    • pp.185-191
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    • 2004
  • This study dealt with the Kogi River, located in Kaizuka City, Osaka, which has experienced different improvements from the upper through the lower regions, aimed at revealing temporal relations between residents and the river, as well as probing future problems and directions regarding the river in the suburban area, by conducting a survey of local residents. The result showed that, in the upper region where nature remains in its natural state and the good water quality has been maintained, the relations between the residents and the river continued until around 1965; meanwhile in the middle region the relations have been disappearing since about 1955, and in the lower region where the stream has been repeatedly rehabilitated since 1955, there are fewer involvements of the people with the river. It also revealed that the weaker the relations between people and the river became, the larger the number of residents, even in the upper region, who became concerned over the deteriorating river environment after about 1975, and that in the middle and lower areas, about a decade earlier than in the upper area, the number of those who were aware of the environmental deterioration began to increase. Consequently, with an eye to resuming the relations between people and the river in an suburban area, their future challenges would be the space improvements depending on the environmental characteristics of the area; for example, the recovery of grassy banks for the purpose of protection in the lower region; the preservation and maintenance of many waterside woods as well as the creation of open spaces utilizing the river banks in the middle area; and throughout the whole region, the establishment of a system in which the relations between man and the river can be passed down to future generations, by utilizing the local human resources including those who know the former river landscapes or about the playing in and around the river.

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부드러운 카메라 움직임을 위한 EM 알고리듬을 이용한 삼차원 보정 (Structure and Motion Estimation with Expectation Maximization and Extended Kalman Smoother for Continuous Image Sequences)

  • Seo, Yong-Duek;Hong, Ki-Sang
    • 한국정보과학회논문지:소프트웨어및응용
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    • 제31권2호
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    • pp.245-254
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    • 2004
  • 이 논문은 카메라가 연속적으로 움직일 때 그 카메라로부터 얻은 동영상을 분석하여 카메라의 움직임에 대한 정보와 영상내의 구조물의 삼차원 정보를 계산하는 알고리듬에 대한 것이다. 일반적으로 불 연속한 위치에서 얻은 영상의 집합으로부터 삼차원정보 및 카메라 정보를 얻는 경우에는 카메라의 움직임에 대한 제약조건이 필요 없지만, 비디오 카메라를 이용하여 동영상을 취득하는 경우에는 항상 카메라의 움직임이 부드러워야 한다는 조건이 따라 붙는다. 따라서, 이 논문에서는 ‘부드러운 움직임을 가지는 카메라’라는 제약조건을 포함하는 카메라 및 삼차원정보의 최적화 과정에 대하여 연구하였다. 목적하는 바를 얻기 위하여 Expectation-Maximization 방법을 사용하여 카메라의 움직임에 대한 모델 파라메터를 동시에 추정하였는데, 이를 위하여 Extended Kalman Filter 와 Extended Kalman Smoother를 적용하였다. 이 연구는 길이가 긴 비디오 영상열의 비젼 해석에 기본이 된다. 실제 영상을 이용하여 실험한 결과를 보였다.

고전계와 저전계에서 천연고무의 전기전도기구 (Natural Rubber Electrical Conduction Mechanism in High and Low Electric Fields)

  • 윤주호;최용성;문종대;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.307-308
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    • 2007
  • This work shows the experimental results obtained from ageing at a temperature of 100 C for 48, 70 and 312 h, although the application of AC electrical tension in samples and the measuring of current leakage are presented. The measurements in samples were carried out with samples prepared from the deformulated commercial materials and respectively reformulated into thin films. The obtained results showed the mechanisms of conduction of samples in low and high electric fields. It was also identified an electric tension transition showing that in low fields it prevails the Ohm's law conduction, and in high electric fields it prevails the conduction of space charge limited current (SCLC). These results can support the natural rubber formulation process having as their main objective the reducing of the mechanisms that occur under high conduction current in high electric fields, which leads the material to a dielectric breakdown. Raw Natural rubber in Brazil is extracted from rubber trees (Hevea brasiliensis) in farms in So Paulo State by using some new plantation technology in smaller spaces, with trees placed a few meters from each other. In the Amazon rain forest the rubber trees are found naturally and their spacing may be of hundreds of meters or even kilometers between them. It is necessary to research this raw material from different internationally standard clones to characterize dielectric and electric properties for industrial applications. Moreover, this natural material has a low commercial price when compared to the synthetic ones.

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Trapping centers due to native defects in the $CdIn_2S_4$ films grown by hot wall epitaxy

  • Hong, Myung-Seuk;Hong, Kwang-Joon
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.167-168
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    • 2007
  • $CdIn_2S_4$ (110) films were grown on semi-insulating GaAs (100) by a hot wall epitaxy method. Using photocurrent (PC) measurement, the PC spectra in the temperature range of 30 and 10 K appeared as three peaks in the short wavelength region. It was found that three peaks, A-, B-, and C-excitons, correspond to the intrinsic transition from the valence band states of ${\Gamma}_4(z),\;{\Gamma}_5(x),\;and\;{\Gamma}_5(y)$ to the exciton below the conduction band state of ${\Gamma}_1(s)$, respectively. The 0.122 eV crystal field splitting and the 0.017 eV spin orbit splitting were obtained. Thus, the temperature dependence of the optical band gap obtained from the PC measurement was well described by $E_g$(T)=2.7116eV - $(7.65{\times}10^{-4}\;eV/K)T^2$/(425+T). But, the behavior of the PC was different from that generally observed in other semiconductors. The PC intensities decreased with decreasing temperature. This phenomenon had ever been reported at a PC experiment on the bulk crystals grown by the Bridgman method. From the relation of log $J_{ph}$ vs 1/T, where $J_{ph}$ is the PC density, two dominant levels were observed, one at high temperatures and the other at low temperatures. Consequently, the trapping centers due to native defects in the $CdIn_2S_4$ film were suggested to be the causes of the decrease in the PC signal with decreasing temperature.

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PLD 방법에 의해서 증착된 ZnO 박막의 전기적 특성 및 접합 특성에 관한 연구 (Electrical Characterization and Metal Contacts of ZnO Thin Films Grown by the PLD Method)

  • 강수창;신무환
    • 한국전기전자재료학회논문지
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    • 제15권1호
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    • pp.15-23
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    • 2002
  • In this study, metal/ZnO contacts were thermally annealed at different temperatures (as-dep., 400$^{\circ}C$, 600$^{\circ}C$, 800$^{\circ}C$, 1000$^{\circ}C$) for the investigation of electrical properties, and surface and interface characteristics. The analysis of the element composition and the chemical bonding state of the surface was made by the XPS(X-ray photoelectron spectroscopy). An attempt was made to establish the electrical property-microstructure relationship for the (Ti, Au)/ZnO. The Ti/ZnO contact exhibits an ohmic characteristics with a relatively high contact resistance of 4.74${\times}$10$\^$-1/ $\Omega$$\textrm{cm}^2$ after an annealing at 400$^{\circ}C$. The contact showed a schottky characteristics when the samples were annealed at higher temperature than 400$^{\circ}C$. The transition from the ohmic to schottky characteristics was contributed from the formation of the oxide layers as was confirmed by the peaks for O-O and Ti-O bondings in XPS analysis. For the Au/ZnO contact the lowest contact resistance was obtained from the as-deposited sample. The resistance was slowly increased with annealing temperature up to 600$^{\circ}C$. The ohmic characteristics were maintained eden fort 600$^{\circ}C$ annealing. The XPS analysis showed that the Au-O intensity was dramatically decreased with temperature above 600$^{\circ}C$.