• 전기화학회지
• /
• 제9권3호
• /
• pp.118-123
• /
• 2006

반복적인 작동/멈춤에 의해 고분자전해질 연료전지의 성능 감소가 촉진되며, 이는 연료전지 자동차의 상용화를 위해 반드시 해결되야 한다. 고분자전해질 연료전지 스택의 운전을 정지했을 때 연료극 유로에는 수소가, 공기극 유로에는 공기가 남아 있어 연료전지가 열림회로 전위 상태에 한동안 유지되며 이로 인해 촉매의 소결이 촉진되고 과산화수소 라디칼이 형성되어 전해질를 분해시키는 것으로 보고되고 있다. 본 연구에서는 반복적인 작동/멈춤이 따라 고분자전해질 연료전지의 성능 감소와 막-전극 접합체의 특성에 미치는 영향을 조사하고, 운전 정지 시 잔존 수소를 제거함으로써 연료전지 스택의 내구성을 향상시키는 방법을 제안하였다.

• 신재생에너지
• /
• 제3권3호
• /
• pp.5-13
• /
• 2007

Stacks of solid oxide fuel cell with 1kW max power performance were designed on planar type employing anode-supported cells and metallic interconnects. The stacks composed of 3-cells, 8-cells, and 16-cells were fabricated and tested in serials by using anode-supported cells purchased from Indec, and sealants/interconnects prepared at RIST. In the performance test of the final 16-cells stack, OCV was recorded to be 16.7V. The peak power and the power density showed 1 kW, $0.77W/cm^2$ at $820^{\circ}C$, respectively. In addition, the long-term degradation rate of the power exhibited 2.25 % during 500h at $750^{\circ}C$.

• JSTS:Journal of Semiconductor Technology and Science
• /
• 제4권1호
• /
• pp.52-62
• /
• 2004

In this paper we look at the effect of Fringe-Enhanced-Barrier-lowering (FEBL) for high-K dielectric MOSFETs and the dependence of FEBL on various technological parameters (spacer dielectrics, overlap length, dielectric stack, S/D junction depth and dielectric thickness). We show that FEBL needs to be contained in order to maintain the performance advantage with scaled high-K dielectric MOSFETs. The degradation in high-K dielectric MOSFETs is also identified as due to the additional coupling between the drain-to-source that occurs through the gate insulator, when the gate dielectric constant is significantly higher than the silicon dielectric constant. The technology parameters required to minimize the coupling through the high-K dielectric are identified. It is also shown that gate dielectric stack with a low-K material as bottom layer (very thin $SiO_2$ or oxy-nitride) will be helpful in minimizing FEBL. The circuit performance issues with high-K MOS transistors are also analyzed in this paper. An optimum range of values for the dielectric constant has been identified from the delay and the energy dissipation point of view. The dependence of the optimum K for different technology generations has been discussed. Circuit models for the parasitic capacitances in high-K transistors, by incorporating the fringing effects, have been presented.

• Bulletin of the Korean Chemical Society
• /
• 제27권2호
• /
• pp.281-285
• /
• 2006

Microbial fuel cells (MFC) stacked with bipolar plates have been constructed and their performance was tested. In this design, single fuel cell unit was connected in series by bipolar plates where an anode and a cathode were made in one graphite block. Two types of bipolar plate stacked MFCs were constructed. Both utilized the same glucose oxidation reaction catalyzed by Gram negative bacteria, Proteus vulgaris as a biocatalyst in an anodic compartment, but two different cathodic reactions were employed: One with ferricyanide reduction and the other with oxygen reduction reactions. In both cases, the total voltage was the mathematical sum of individual fuel cells and no degradation in performance was found. Electricity from these MFCs was stored in a supercapacitor to drive external loads such as a motor and electric bulb.

• 대한금속재료학회지
• /
• 제47권11호
• /
• pp.722-727
• /
• 2009

The bipolar plates are not only the major part of the polymer electrolyte membrane fuel cell (PEMFC) stack in weight and volume, but also a significant contributor to the stack costs. Stainless steels are considered to be good candidates for bipolar plate materials of the PEMFC due to their low cost, high strength and easy machining, as well as corrosion resistance. In this paper, 316L stainless steel with and without nitrogen ion implantation were tested in simulated PEMFC environments for application as bipolar plates. The results showed that the nitride formed by nitrogen ion implantation contributed the decrease of the interfacial contact resistance without degradation of corrosion property. The combination of excellent properties indicated that nitrogen ion implanted stainless steel could be potential candidate materials as bipolar plates in PEMFC. Current efforts have focused on optimizing the condition of ion implantation.

• 한국수소및신에너지학회논문집
• /
• 제35권4호
• /
• pp.370-376
• /
• 2024

Load variations reduce the lifespan of polymer electrolyte fuel cells (PEFCs). To analyze the impact of load variations on durability of PEFCs, two stacks were built and operated continuously for 400 hours, one under load variations and the other under constant current condition with the same energy output. Using the example model provided by Mathworks, we obtained load variation data for the experiments. The performance curves were measured every 100 hours and analyzed by current interruption method and electrochemical impedance spectroscopy. The degradation comparison shows a much larger decrease in performance under the load variation. The activation resistance, electrical resistance, and mass transfer resistance are all found to increase more.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2017년도 추계학술대회
• /
• pp.167-168
• /
• 2017

This paper investigates to identify an optimal for analysis of battery behavior in system-level applications such as Battery Energy Storage Systems in Smart Grid infrastructures and Electrical vehicles. At system level applications, it is mandatory to check model for meaningful equivalency and practical ability for extension from unit cell to Battery stack. The investigation of current battery models in relation to their suitability for study and analysis of system level applications of battery helpful for identification of optimal model and it also provides an intuition and direction to develop the most suitable model, if such models are not available already.

• 대한기계학회논문집B
• /
• 제30권8호
• /
• pp.756-763
• /
• 2006

PEMFC has several technical problems such as water management, long term stability and performance degradation as. PEMFC has been studied not only to solve water management, but also to generate power in stable manner to system by using a hybrid system with auxiliary energy storage device. The purpose of this study is to couple PEMFC with supercapacitor to make a hybrid system and to design and test control strategies for stable power generation in case of changing output power. The polarization curve and dynamic behaviors while changing power were investigated to find out characteristics of PEMFC stack. A DC/DC converter was fabricated in order to increase fuel cell and supercapacitor voltage and to charge supercapacitor. We found that the operation strategy 2 was recommended to the system because of solving water management problem and increasing the dynamic behavior.

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
• /
• pp.213-218
• /
• 1999

용융탄산염 연료전지 (MCFC) 스택의 운전시에 가장 문제가 되는 사항들 중의 하나는 전지 반응에 의해 생성되는 많은 열량으로서, 이로 인해 내부 온도가 상승하고 심한 온도 분포가 존재하게 되며 이는 출력 전압 또는 전류의 불균일을 초래하는 동시에 전지 성능 열화(degradation)를 가속시켜 장기 운전에 큰 장애 요인이 된다. 현재 국내에서 개발중인 100kW급 MCFC 발전 시스템의 스택은 전극 면적이 6,000 $ extrm{cm}^2$ 혹은 그 이상에 이르며 25 kW 모듈당 적층되는 전지는 40장으로서 운전시의 발열량 조절이 매우 큰 문제로 등장한다.(중략)

• 한국정보처리학회:학술대회논문집
• /
• 한국정보처리학회 2015년도 춘계학술발표대회
• /
• pp.167-169
• /
• 2015

기존 그리드 및 클러스터 환경과 달리 클라우드 컴퓨팅 환경에서는 하나의 물리 호스트 위에 다수의 가상 머신 인스턴스가 할당 및 운용됨에 따라 가상 머신 간섭 (Virtual Machine Interference)에 의한 응용 처리 성능 저하가 발생한다. 본 논문에서는 클라우드 오픈소스 플랫폼인 오픈스택 (OpenStack)을 기반으로 하여 가상 머신 인스턴스 위에서 Montage 워크플로우 응용을 처리할 때 가상 머신 간섭이 처리 성능에 미치는 정도를 분석하고 이를 해결하기 위한 자원 할당 정책을 논의한다.