• 제목/요약/키워드: Stabilization energy

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인산염 비료 및 레드머드를 이용한 중금속 오염 광미의 안정화 (Stabilization of Heavy Metal-Contaminated Mine Tailings Using Phosphate Fertilizers and Red Mud)

  • 강신현;안준영;황경엽;서정윤;김재곤;송호철;임수빈;황인성
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권5호
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    • pp.31-41
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    • 2011
  • The objectives of this study were to investigate the efficiencies of the stabilizers such as mono-potassium phosphate (MKP), phosphate fertilizer and red mud in treating the mine tailings contaminated with heavy metals and to characterize the changes in fractionations of the heavy metals during the stabilization. The TCLP results showed that the stabilization efficiencies of Cd, Pb and Zn increased with the increase in the stabilizer dosage and the reaction times. MKP showed the highest efficiencies for the heavy metals stabilization among the stabilizers tested. When the mine tailings were amended with MKP, the TCLP concentrations of Cd, Pb and Zn were reduced by 79~97%, 61~84%, and 89~99%, respectively. When the composite stabilizers, MKP/phosphate fertilizer or MKP/red mud, were used, the stabilization efficiencies were lower than when MKP was used as a single stabilizer. The sequential extraction results showed that carbonates fraction of Cd and Zn increased generally. Especially, when red mud was used, carbonates fraction of Cd and Zn increased 5 and 18 times, respectively. In the case of Pb, the treatment with MKP increased residual fraction by 10 times. The results showed that MKP was the most effective in stabilizing the heavy metals (Cd, Pb and Zn) to improve the efficacy of the composite binders.

계면안정화를 통한 Si-SiO2-흑연 복합재 음극의 전기화학적 특성 개선 (Improved Cycling Ability of Si-SiO2-graphite Composite Battery Anode by Interfacial Stabilization)

  • 민정혜;배영산;김성수;송승완
    • 전기화학회지
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    • 제15권3호
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    • pp.154-159
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    • 2012
  • Si계 음극소재는 리튬 삽입-탈착 중 일어나는 큰 구조적 부피변화와 입도변화로 인해 빠른 성능 퇴화가 일어나는 단점이 있다. 산화물 SiO 음극소재는 리튬과의 반응 중 비활성상인 $Li_2O$ 및 lithium silicate가 형성되어 Si의 부피변화를 완화시키는 버퍼 역할을 하므로 용량은 Si보다 적으나 개선된 용량 유지 특성을 보이는 것으로 알려져 있다. 본 연구에서는 Si의 부피변화 완화를 위하여 저가의 $SiO_2$와 입자간 전기전도성을 향상시키는 흑연을 구조안정화 기재로서 사용하여 Si-$SiO_2$-흑연 복합재 음극을 제작하였다. 구조안정화 뿐만 아니라 silane계 전해액 첨가제를 이용하여 Si-$SiO_2$-흑연 복합재 음극과 전해액간 계면을 안정화시킴으로써 용량 유지 특성이 개선되는 효과에 대해 보고하고자 한다.

A Thermodynamic Investigation into the Stabilization of Poly(dA).[poly(dT)]2 Triple Helical DNA by Various Divalent Metal Ions

  • Choi, Byung-Hoon;Yeo, Ga-Young;Jung, Jin-Ah;Lee, Bae-Wook;Han, Sung-Wook;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • 제30권11호
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    • pp.2691-2696
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    • 2009
  • Effects of representative group II and transition metal ions on the stability of the $poly(dA){\cdot}[poly(dT)]_2$ triplex were investigated by the van’t Hoff plot constructed from a thermal melting curve. The transition, $poly(dA){\cdot}[poly(dT)]_2\;{\rightarrow}\;poly(dA){\cdot}poly(dT)\;+\;poly(dT)$, was non-spontaneous with a positive Gibb’s free energy, endothermic (${\Delta}H^{\circ}$ > 0), and had a favorable entropy change (${\Delta}S^{\circ}$ > 0), as seen from the negative slope and positive y-intercept in the van’t Hoff plot. Therefore, the transition is driven by entropy change. The $Mg^{2+}$ ion was the most effective at stabilization of the triplex, with the effect decreasing in the order of $Mg^{2+}\;>\;Ca^{2+}\;>\;Sr^{2+}\;>\;Ba^{2+}$. A similar stabilization effect was found for the duplex to single strand transition: $poly(dA){\cdot}poly(dT)\;+\;poly(dT)\;→\;poly(dA)\;+\;2poly(dT)$, with a larger positive free energy. The transition metal ions, namely $Ni_{2+},\;Cu_{2+},\;and\;Zn_{2+}$, did not exhibit any effect on triplex stabilization, while showing little effect on duplex stabilization. The different effects on triplex stabilization between group II metal ions and the transition metal ions may be attributed to their difference in binding to DNA; transition metals are known to coordinate with DNA components, including phosphate groups, while group II metal ions conceivably bind DNA via electrostatic interactions. The $Cd_{2+}$ ion was an exception, effectively stabilizing the triplex and melting temperature of the third strand dissociation was higher than that observed in the presence of $Mg_{2+}$, even though it is in the same group with $Zn_{2+}$. The detailed behavior of the $Cd_{2+}$ ion is currently under investigation.

STABILIZATION FOR THE VISCOELASTIC KIRCHHOFF TYPE EQUATION WITH A NONLINEAR SOURCE

  • Kim, Daewook
    • East Asian mathematical journal
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    • 제32권1호
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    • pp.117-128
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    • 2016
  • In this paper, we study the viscoelastic Kirchhoff type equation with a nonlinear source $$u^{{\prime}{\prime}}-M(x,t,{\parallel}{\bigtriangledown}u(t){\parallel}^2){\bigtriangleup}u+{\int}_0^th(t-{\tau})div[a(x){\bigtriangledown}u({\tau})]d{\tau}+{\mid}u{\mid}^{\gamma}u=0$$. Under the smallness condition with respect to Kirchhoff coefficient and the relaxation function and other assumptions, we prove the uniform decay rate of the Kirchhoff type energy.

Recovery system 적용을 통한 바이오가스플랜트의 안정화 기술 (Stabilization technology of biogas plant applied recovery system)

  • 장병인;정미화;조윤미;조용일;박경호
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.102.2-102.2
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    • 2010
  • We are to evaluate the stabilization technology of actual biogas plant facilities, which is operating currently. It describes the traits of the consistent facilities of mesophilic anaerobic digestion using Unison Biogas plant Recovery system(UBR). Also the economical efficiency is examined with the electric power sales earnings and applying the deserted heating by generating electric power, which is generated by operated combined heat and power using biogas produced by mesophilic anaerobic digestion. We have generated the 481,113kw for electric power and 1,376Gcal for thermal energy simultaneously. If these electric power and thermal energy are converted into diesel, we can achieve savings equal to 114,300L, and 152,109L in the quantity of heat. Finally, if CDM, RPS, liquid fertilizer sales business, etc. is activated, the earnings will be expected to improve dramatically and is considered to contribute a drop of the greenhouse gas.

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Emulsification of Chloroprene Rubber (CR) by Interfacial Chemistry; Stabilization and Enhancement of Mechanical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제52권4호
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    • pp.257-265
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    • 2017
  • In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.