• Title/Summary/Keyword: Stability of oxidation

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Surface Flame Patterns and Stability Characteristics of Premixed Burner System for Fuel Reformers (개질기용 예혼합 버너의 화염형태 및 안정성 특성)

  • Lee, Pil-Hyong;Park, Bong-Il;Jo, Soon-Hye;Hwang, Sang-Soon
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.8-14
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    • 2010
  • Fuel processing systems which convert fuel into rich gas (such as stream reforming, partial oxidation, autothermal reforming) need high temperature environment ($600{\sim}1,000^{\circ}$). Generally, anode-off gas or mixture of anode-off gas and LNG is used as input gas of fuel reformer. In order to make efficient and low emission burner system for fuel reformer, it is necessary to elucidate the combustion and emission characteristic of fuel reformer burner. The purpose of this study is to develop a porous premixed flat ceramic burner that can be used for 1~5 kW fuel cell reformer. Ceramic burner experiments using natural gas, hydrogen gas, anode off gas, mixture of natural gas & anode off gas were carried out respectively to investigate the flame characteristics by heating capacity and equivalence ratio. Results show that the stable flat flames can be established for natural gas, hydrogen gas, anode off gas and mixture of natural gas & anode off gas as reformer fuel in the porous ceramic burner. For all of fuels, their burning velocities become smaller as the equivalence ratio goes to the lean mixture ratio, and a lift-off occurs at lean limit. Flame length in hydrogen and anode off gas became longer with increasing the heat capacity. In particular, the blue surface flame is found to be very stable at a very lean equivalence ratio at heat capacity and different fuels. The exhausted NOx and CO measurement shows that the blue surface flame represents the lowest NOx and CO emissions since it remains very stable at a lean equivalence ratio.

Stepwise Production of Syngas and Hydrogen from Methane on Ferrite Based Media Added with YSZ (YSZ 첨가 페라이트 매체상에서 메탄으로부터 합성 가스 및 수소의 단계적 생산)

  • Je, Han-Sol;Cha, Kwang-Seo;Kim, Hong-Soon;Lee, Young-Seak;Park, Chu-Sik;Kim, Young-Ho
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.1
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    • pp.50-57
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    • 2010
  • Stepwise production of syn-gas and hydrogen from methane on ferrite based media added with yttria-stabilized zirconia (YSZ) was carried out using a fixed bed infrared reactor. In this study, all M-ferrite (M=Co, Cu, Mn and Ni) media were prepared by co-precipitation method, and there the YSZ was added as a binder to improve thermal stability, reactivity, and resistance against carbon deposition. Most of the ferrite media containing YSZ showed the good redox property for temperature programmed reduction/oxidation (TPR/O) tests. Notably, the Cu-substituted ferrite medium with YSZ showed the great resistance against carbon deposition as well as the good reactivity for the stepwise production of syngas and hydrogen. Furthermore, it also showed the good durability without significant deactivation during five repeated cyclic tests.

Change in the photocatalytic activity of ZnO nanoparticles by additive H2O

  • Nam, Sang-Hun;Kim, Myoung-Hwa;Lee, Sang-Duck;Choi, Jin-Woo;Kim, Min-Hee;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.285-285
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    • 2010
  • Zinc oxide (ZnO) is a direct band gap semiconductor with 3.37 eV, which has in a hexagonal wurtzite structure. ZnO is a good candidate for a photocatalyst because it has physical and chemical stability, high oxidative properties, and absorbs of ultraviolet light. During ZnO is irradiated by UV light, redox (reduction and oxidation) reactions will occur on the ZnO surface, generating the radicals O2- and OH. These two powerful oxidizing agents have been proven to be effective in decomposition of harmful organic materials, converting them into CO2 and H2O. Therefore, we assume that oxygen on the surface of ZnO is a very important factor in the photocatalytic activities of ZnO nanoparticles. Recently, ZnO nanoparticles are studied in various application fields by many researchers. Photocatalyst research is progressing much in various application fields. But the ZnO nanoparticles have disadvantage that is unstable in water in comparison titanium dioxide (TiO2). The Zn(OH)2 was formed at the ZnO surface and ZnO become inactive as a photocatalyst when ZnO is present in the solution. Therefore, we prepared synthesized ZnO nanoaprticles that were immersed in the water and dried in the oven. After that, we measured photocatalytic activities of prepared samples and find the cause of their phtocatalytic activity changes. The characterization of ZnO nanoparticles were analyzed by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and BET test. Also we defined the photocatalytic activity of ZnO nanoparticles using UV-VIS Spectroscopy. And we explained changing of photocatalytic activity after the water treatment using X-ray Photoelectron Spectroscopy (XPS).

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Studies on the Refining and Utilization of Filefish Viscera Oil 2. Utilization of Filefish Viscera Oil (말쥐치 내장유의 정제 및 이용에 관한 연구 2. 말쥐치 내장유의 이용)

  • 강훈이;대도해명;소천천추;김동연;이응호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.2
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    • pp.181-186
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    • 1992
  • For the effective utilizing of refined filefish viscera oil, it was added to fish meat paste based products as a dietary supplement of polyunsaturated fatty acids. The storage stability and physicochemical properties of the product(kamaboko) was tested. Lipid oxidation of kamaboko could be retarded and texture expressed as jelly strength could be enhanced by adding of emulsion curd prepared from water, refined filefish viscera oil and soybean protein and sodium erythorbate during the storage at 5$^{\circ}C$. These results suggested the possibility that the refined filefish viscera oil containing highly polyunsaturated fatty acid, especially EPA and DHA could be used as a food ingredient for dietary supply of the lipids.

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The effect and stability of plant extract ingredient as uv absorber (자외선 흡수제로서의 식물추출성분의 안정성과 효과)

  • 김경동;이용두;박성순;윤성화;이석현
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.41-58
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    • 2000
  • Recently the harmfulness of W radiation is in creasing due to encironmental pollution. Environmental population may also play a role in global decrease of ozone layer, A major consequence of ozone depletion is increase in solar ultra violet radiation received at the earth's surface excessive exposure to W radiation cause a lot of problems in our skin. Plant extract that possess antioxidative activities has been reported to retard the oxidation process in product to which they have been added. Plant are alived under solar light. So it is expect the plants have so many protection mechanisms and UV absorbent ingredients against ultra violet radiation such as UVB, UVA. Plant extract which were flavonoids, alkaloids and others could be transformed into UV absorber by chemical modification. Therefore with the aim of finding alternative natural absorber that can safely be used in cosmetic, we have screened various extract for their UV absorbent effect. Thus, the cosmetic safety against human skin, antimicrobial effects and others could be improved by using the silicon.

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Degradation Behavior of Eutectic and Pb-free Solder Plated Ribbon in Crystalline Silicon Photovoltaic Module (유무연 용융도금 리본에 따른 결정질 실리콘 태양전지 모듈 열화거동)

  • Kim, Ju-Hee;Kim, A Yong;Park, Nochang;Ha, Jeong Won;Lee, Sang Guon;Hong, Won Sik
    • Journal of Welding and Joining
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    • v.32 no.6
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    • pp.75-81
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    • 2014
  • Usage of heavy metal element (Pb, Hg and Cd etc.) in electronic devices have been restricted due to the environmental banning of the European Union, such as WEEE and RoHS. Therefore, it is needed to develop the Pb-free solder plated ribbon in photovoltaic (PV) module. This study described that degradation characteristics of PV module under damp heat (DH, $85^{\circ}C$ and 85% R.H.) condition test for 1,000 h. Solar cell ribbons were utilized to hot dipping plate with Pb-free solder alloys. Two types of Pb-free solder plated ribbons, Sn-3.0Ag-0.5Cu (SAC305) and Sn-48Bi-2Ag, and an electroless Sn-40Pb solder hot dipping plated ribbon as a reference sample were prepared to evaluate degradation characteristics. To detect the degradation of PV module with the eutectic and Pb-free solder plated ribbons, I-V curve, electro-luminescence (EL) and cross-sectional SEM analysis were carried out. DH test results show that the reason of maximum power (Pm) drop was mainly due to the decrease fill factor (FF). It was attributed to the crack or oxidation of interface between the cell and the ribbon. Among PV modules with the eutectic and Pb-free solder plated ribbon, the PV module with SAC305 ribbon relatively showed higher stability after DH test than the case of PV module with Sn-40Pb and Sn-48Bi-2Ag solder plated ribbons.

Preparation of Sulfur Crosslinkable EVA and Blend With Rubbers (황가황형 EVA의 제조 및 고무와의 블렌드)

  • Jin, Je-Yong;Choi, Sei-Young
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.229-238
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    • 1999
  • In this study, double bond, unsaturated group was introduced to the main chain of EVA by chemically treating EVA, nondiene polymer. Benzene sulfonic acid, ENB and DCPD were used as a third element. Also, from blending CR and SBR, conventional synthetic rubber we prepared vulcanizates and examined their physical properties. The datum lead to the following conclusion that some problems were modified; limited temperature in use and mechanical properties like hardness, tensile strength, tensile stress, and elongation rate of thermoplastic EVA, keeping the following advantages of original EVA; green strength, injection molding by Pressure, adhesion, tackiness, dimensional stability, and ozone resistance, etc. It is expected that continuous research of the modification between nondiene and diene polymer will improve what were shown disadvantages in synthetic polymer; processing, oxidation resistance, and adhesion. In addition, it will be possible to continue process of rubber products by utilizing possible fluidity for fusion of EVA.

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Formation of Nickel Silicide from Atomic Layer Deposited Ni film with Ti Capping layer

  • Yun, Sang-Won;Lee, U-Yeong;Yang, Chung-Mo;Na, Gyeong-Il;Jo, Hyeon-Ik;Ha, Jong-Bong;Seo, Hwa-Il;Lee, Jeong-Hui
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2007.06a
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    • pp.193-198
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    • 2007
  • The NiSi is very promising candidate for the metallization in 60nm CMOS process such as FUSI(fully silicided) gate and source/drain contact because it exhibits non-size dependent resistance, low silicon consumption and mid-gap workfunction. Ni film was first deposited by using ALD (atomic layer deposition) technique with Bis-Ni precursor and $H_2$ reactant gas at $220^{\circ}C$ with deposition rate of $1.25{\AA}/cycle$. The as-deposited Ni film exhibited a sheet resistance of $5{\Omega}/{\square}$. RTP (repaid thermal process) was then performed by varying temperature from $400^{\circ}C$ to $900^{\circ}C$ in $N_2$ ambient for the formation of NiSi. The process window temperature for the formation of low-resistance NiSi was estimated from $600^{\circ}C$ to $800^{\circ}C$ and from $700^{\circ}C$ to $800^{\circ}C$ with and without Ti capping layer. The respective sheet resistance of the films was changed to $2.5{\Omega}/{\square}$ and $3{\Omega}/{\square}$ after silicidation. This is because Ti capping layer increases reaction between Ni and Si and suppresses the oxidation and impurity incorporation into Ni film during silicidation process. The NiSi films were treated by additional thermal stress in a resistively heated furnace for test of thermal stability, showing that the film heat-treated at $800^{\circ}C$ was more stable than that at $700^{\circ}C$ due to better crystallinity.

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Improvement of Rapid Sand Filtration to Two Stage Dual Media Filtration System in Water Treatment Plant (정수처리장내 급속모래 여과지의 이단복합여과시스템으로의 개량)

  • Woo, Dal-Sik;Hwang, Kyu-Won;Kim, Joon-Eon;Hwang, Byung-Gi;Jo, Kwan-Hyung
    • Journal of Environmental Health Sciences
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    • v.37 no.2
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    • pp.141-149
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    • 2011
  • This study aimed for developing a two stage dual media filtration system. It has a sand and activated carbon layer above the under-drain system, and a sand layer above the middle-drain system for pretreatment. When retrofitting an old sand filter bed or designing a new one, this technology can substitute the existing sand filter bed without requiring a new plant site. The removal rate of total particle is 93, and 3~7 ${\mu}m$ and 5~15 ${\mu}m$ particles are all 97%. These high removal efficiencies of each pollutant due to adsorption and biological oxidation in activated carbon filter layer. The best backwashing method of two stage dual media filtration system is ascertained by air injection, air + water injection and water injection sequence. In this study, a pilot plant of two stage and dual filtration system was operated for 4 months in water treatment plant. The stability of turbidity was maintained below 1 NTU. The TOC, THMFP and HAAFP were removed about 90% by two stage and dual media filtration system, which is almost 2 times higher than existing water treatment plant.

A Study on Combined Processes of Sliding Arc Plasma and Corona Dielectric Barrier Discharge for Improve the Efficiency Treatment of Harmful Substance (슬라이딩아크 방전과 코로나 방전의 복합공정을 통한 유해물질 처리효율 개선에 관한 연구)

  • Kwon, Woo-Taeg;Lee, Woo-Sik
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.108-113
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    • 2014
  • The combined process of Sliding Arc Plasma and corona dielectric barrier discharge process (CDBD) was used to efficiently improve harmful substance, which convert into OH radicals which have strong oxidation potential, and so have deodorization and sterilizing effects, by generating specific radicals and anion and then reacting with the moisture contained in harmful substance. As a result of experiment, even if the size of SAP reactor is reduced from 80 A to 50 A, there is no much change and therefore it is judged the size of reactor may be minimized. And it was confirmed that after the anion and ozone generated from CDBD rector react with harmful substance, a anion was reduced from 510,000 ppb to 470 ppb and ozone from 98 ppb to 22 ppb. It was also judged the stability and durability of plasma producer are excellent. Accordingly, it is considered the harmful substances which exist in indoor air quality will be efficiently improved and removed by using further plasma combined process through this study.