• Journal of Hydrogen and New Energy
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• v.18 no.2
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• pp.109-115
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• 2007

Solar energy conversion to hydrogen was carried out via a two-step thermochemical water splitting using metal oxide redox pair. To simulate the solar radiation, a 7 kW short arc Xe-lamp was used. Partially reduced iron oxide and cerium oxide have the water splitting ability, respectively. So, $Fe_3O_4$ supported on $CeO_2$ was selected as the active material. $Fe_3O_4/CeO_2$(20 wt/80 wt%) was prepared by impregnation method, then the active material was washcoated on the ceramic honeycomb monolith made of mullite and cordierite. Oxygen was released at the reduction step($1673{\sim}1823\;K$) and hydrogen was produced from water at lower temperature($873{\sim}1273\;K$). The result demonstrate the possibility of the 2-step thermochemical water splitting hydrogen production by the active material washcoated monolith. And hydrogen and oxygen was produced separately without any separation process in a monolith installed reactor. But the SEM and EDX analysis results revealed that the support used in this experiment is not suitable due to the thermal instability and coating material migration.

• Journal of Hydrogen and New Energy
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• v.14 no.3
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• pp.268-275
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• 2003

The water-splitting process by the metal oxides using solar heat is one of the hydrogen production method. The hydrogen production process using the metal oxides (NiFe2O4/NiAl2O4,CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite) was carried out by two steps. The first step was carried out by the CH4-reduction to increase activation of metal oxides at operation temperature. And then, it was carried out the water-splitting reaction using the water at operation temperature for the second step. Hydrogen was produced in this step. The production rates of H2 were 110, 160, 72, 29, 17, $21m{\ell}/hr{\cdot}g-_{Metal\;Oxide}$ for NiFe2O4/NiAl2O4, CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite respectively in the second step. CoFe2O4/CoAl2O4 had higher H2 production rate than the other metal oxides.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.234-238
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• 2004

A stoichiometric mixture of evaporating materials for $CuInSe_2$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $CuInSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $620^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuInSe_2$ single crystal thin films measured with Hall effect by van der Pauw method are $9.62{\times}10^{l6}\;cm^{-3}$ and $296\;cm^2/V{\cdot}s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CuInSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)\;=\;1.1851\;eV\;-\;(8.99{\times}10^{-4}\;eV/K)T^2/(T+153K)$. The crystal field and the spin-orbit splitting energies for the valence band of the $CuInSe_2$ have been estimated to be 0.0087 eV and 0.2329 eV at 10K, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}_{so}$ definitely exists in the $\Gamma_6$ states of the valence band of the $CuInSe_2$. The three photocurrent peaks observed at 10K are ascribed to the $A_1-$, $B_1-$, and $C_1$-exciton peaks for n = 1.

• Journal of computational fluids engineering
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• v.5 no.1
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• pp.1-7
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• 2000

In general, FDM(finite difference method) and FVM(finite volume method) are used for analyzing the fluid flow numerically. However it is difficult to apply them to problems involving complex geometries, multi-connected domains, and complex boundary conditions. On the contrary, FEM(finite element method) with coordinates transformation for the unstructured grid is effective for the complex geometries. Most of previous studies have used commercial codes such as KIVA or STAR-CD for the flow analyses in the engine cylinder, and these codes are mostly based on the FVM. In the present study, using the FEM for three-dimensional, unsteady, and incompressible Navier-Stokes equation, the velocity and pressure fields in the engine cylinder have been numerically analyzed. As a numerical algorithm, 4-step time-splitting method is used and ALE(arbitrary Lagrangian Eulerian) method is adopted for moving grids. In the Piston-Cylinder, the calculated results show good agreement in comparison with those by the FVM and the experimental results by the LDA.

• The Journal of the Acoustical Society of Korea
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• v.22 no.8
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• pp.727-739
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• 2003

In this paper, we propose a generation method of regression classes for adaptation in the HM-Net (Hidden Markov Network) system. The MLLR (Maximum Likelihood Linear Regression) adaptation approach is applied to the HM-Net speech recognition system for expressing the characteristics of speaker effectively and the use of HM-Net in various tasks. For the state level sharing, the context domain state splitting of PDT-SSS (Phonetic Decision Tree-based Successive State Splitting) algorithm, which has the contextual and time domain clustering, is adopted. In each state of contextual domain, the desired phoneme classes are determined by splitting the context information (classes) including target speaker's speech data. The number of adaptation parameters, such as means and variances, is autonomously controlled by contextual domain state splitting of PDT-SSS, depending on the context information and the amount of adaptation utterances from a new speaker. The experiments are performed to verify the effectiveness of the proposed method on the KLE (The center for Korean Language Engineering) 452 data and YNU (Yeungnam Dniv) 200 data. The experimental results show that the accuracies of phone, word, and sentence recognition system increased by 34∼37%, 9%, and 20%, respectively, Compared with performance according to the length of adaptation utterances, the performance are also significantly improved even in short adaptation utterances. Therefore, we can argue that the proposed regression class method is well applied to HM-Net speech recognition system employing MLLR speaker adaptation.

• Journal of applied mathematics & informatics
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• v.25 no.1_2
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• pp.119-136
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• 2007

Block Jacobi and Gauss-Seidel iterative methods are studied for solving $n{\times}n$ fuzzy linear systems. A new splitting method is considered as well. These methods are accompanied with some convergence theorems. Numerical examples are presented to illustrate the theory.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2005.10a
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• pp.57-78
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• 2005

The vehicle routing problem (VRP) is to determine a set of feasible vehicle routes, one for each vehicle, such that each customer is visited exactly once and the total distance travelled by the vehicles is minimized. A feasible route is defined as a simple circuit including the depot such that the total demand of the customers in the route does not exceed the vehicle capacity. While there have been significant advances recently in exact solution methodology, the VRP is not a well solved problem. We find most approaches still relying on the branch and bound method. These approaches employ various methodologies to compute a lower bound on the optimal value. We introduce a new modelling approach, termed route-splitting, for the VRP that allows us to address problems whose size is beyond the current computational range of set-partitioning models. The route-splitting model splits each vehicle route into segments, and results in more tractable subproblems. Lifting much of the burden of solving combinatorially hard subproblems, the route-splitting approach puts more weight on the LP master problem, Recent breakthroughs in solving LP problems (Nemhauser, 1994) bode well for our approach. Lower bounds are computed on five symmetric VRPs with up to 199 customers, and eight asymmetric VRPs with up to 70 customers. while it is said that the exact methods developed for asymmetric instances have in general a poor performance when applied to symmetric ones (Toth and Vigo, 2002), the route splitting approach shows a competent performance of 93.5% on average in the symmetric VRPs. For the asymmetric ones, the approach comes up with lower bounds of 97.6% on average. The route-splitting model can deal with asymmetric cost matrices and non-identical vehicles. Given the ability of the route-splitting model to address a wider range of applications and its good performance on asymmetric instances, we find the model promising and valuable for further research.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.18 no.1
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• pp.27-41
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• 2014

In this paper, we present an efficient numerical method for multiphase image segmentation using a multiphase-field model. The method combines the vector-valued Allen-Cahn phase-field equation with initial data fitting terms containing prescribed interface width and fidelity constants. An efficient numerical solution is achieved using the recently developed hybrid operator splitting method for the vector-valued Allen-Cahn phase-field equation. We split the modified vector-valued Allen-Cahn equation into a nonlinear equation and a linear diffusion equation with a source term. The linear diffusion equation is discretized using an implicit scheme and the resulting implicit discrete system of equations is solved by a multigrid method. The nonlinear equation is solved semi-analytically using a closed-form solution. And by treating the source term of the linear diffusion equation explicitly, we solve the modified vector-valued Allen-Cahn equation in a decoupled way. By decoupling the governing equation, we can speed up the segmentation process with multiple phases. We perform some characteristic numerical experiments for multiphase image segmentation.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3209-3214
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• 2007

This study numerically investigates the unsteady flow and acoustic characteristics of a flapping wing using a hydrodynamic/acoustic splitting method. The Reynolds number based on the maximum translation velocity of the wing is Re=8800 and Mach number is M=0.0485. The flow around the flapping wing is predicted by solving the two-dimensional incompressible Navier-Stokes equations (INS) and the acoustic field is calculated by the linearized perturbed compressible equations (LPCE), both solved in moving coordinates. Numerical results show that the hovering sound is largely generated by wing translation (transverse and tangential), which have different dipole sources with different mechanisms. As a distinctive feature of the flapping sound, it is also shown that the dominant frequency varies around the wing.

• Computers and Concrete
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• v.19 no.6
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• pp.667-675
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• 2017

One of the main disadvantages of Ultra High Performance Concrete exists in the large suggested value of UHPC ingredients. The purpose of this study was to find the models mechanical properties which included a 7, 14 and 28-day compressive strength test, a 28-day splitting tensile and modulus of rupture test for Ultra High Performance Concrete, as well as, a study on the interaction and correlation of five variables that includes silica fume amount (SF), cement 42.5 amount, steel fiber amount, superplasticizer amount (SP), and w/c mechanical properties of UHPC. The response surface methodology was analyzed between the variables and responses. The relationships and mathematical models in terms of coded variables were established by ANOVA. The validity of models were checked by experimental values. The offered models are valid for mixes with the fraction proportion of fine aggregate as; 0.70-1.30 cement amount, 0.15-0.30 silica fume, 0.04-0.08 superplasticizer, 0.10-0.20 steel fiber, and 0.18-0.32 water binder ratio.