• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.404-405
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• 2011

Cu(InGa)$Se_2$ (CIGS) 박막 태양전지의 저가 및 대면적화를 위한 양산화 공정인 two-step process (sputter/selenization) 공정에서는 sputtering으로 형성한 metal precursor stack을 $H_2$ Se gas를 이용하여 selenization하는 공정을 주로 이용한다. 하지만 이러한 selenization 공정은 유독한 $H_2$ Se gas를 이용해야 한다는 점과 긴 시간 동안 열처리를 해야 하는 단점을 가지고 있다. 이에 metal precursor stack 위에 Se 막을 우선 증착하고, Rapid Thermal Process (RTP)를 이용하여 selenization하는 방법이 현재 많은 관심을 끌고 있다. 본 논문에서는 sputtering 이후 RTP를 이용한 CIGS 흡수층 제작에 대한 선행연구의 일환으로 co-evaporator 장비를 이용하여 다양한 구조의 precursor를 제작하고 RTP 조건에 따른 selenization 효과를 연구하였다. Co-evaporator를 이용하여 CIGS, CIG/Se, CuGa/In/Se, In/CuGa/Se 4가지 구조의 precursor stack을 Mo coated soda lime glass 위에 제작하였다. 이때 amorphous 상태의 precursor stack을 만들기 위하여 기판에 열은 가하여 주지 않았으며, 각각의 stack 구조에서 가지고 있는 Cu, In, Ga, Se의 총량을 동일하게 유지하기 위하여 각 stack의 증착 시간을 동일하게 유지하였다. Selenization을 위한 RTP 조건은 550, $600^{\circ}C$ 각각에 대하여 1, 5, 10분으로 split을 진행하였다. Precursor stack의 증착 후 관찰한 XRD 결과는 비정질 상태를 잘 나타내었으며, SEM 결과 CIGS precursor stack을 제외한 나머지 구조의 stack에서는 In 박막의 surface roughness로 인하여 박막의 평탄화가 좋지 않음을 확인하였다. CIGS precursor stack의 경우, RTP 온도와 시간 split와 상관없이 결정화가 잘 이루어졌으나 grain의 성장이 부족하였다. 이에 비하여 CIG/Se, CuGa/In/Se, In/CuGa/Se 구조의 precursor stack의 경우, $550^{\circ}C$ 열처리에서는 InSe의 결정상이 관찰 되었으며 $600^{\circ}C$, 5분 이상 열처리에서 CIGS 결정상이 관찰되었다. 이러한 결과는 Se이 metal 원소들과 함께 있는 CIGS 구조에 비하여 metal precursor stack 위에 Se을 증착한 stack 구조들의 경우는 CIGS 결정을 형성하기 위해 Se이 metal 층들로 확산되어 반응을 하여야 하므로 상대적으로 많은 열에너지가 필요한 것으로 이해할 수 있으며, RTP를 이용한 selenization 공정으로 CIGS 박막 태양전지의 흡수층 형성이 가능함을 확인하였다.

• Geomechanics and Engineering
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• 제30권5호
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• pp.401-411
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• 2022

To obtain the dynamic mechanical properties, fracture modes, energy and brittleness characteristics of Furong Baijiao coal rock, the dynamic impact compression tests under 0, 4, 8 and 12 MPa confining pressure were carried out using the split Hopkinson pressure bar. The results show that failure mode of coal rock in uniaxial state is axial splitting failure, while it is mainly compression-shear failure with tensile failure in triaxial state. With strain rate and confining pressure increasing, compressive strength and peak strain increase, average fragmentation increases and fractal dimension decreases. Based on energy dissipation theory, the dissipated energy density of coal rock increases gradually with growing confining pressure, but it has little correlation with strain rate. Considering progressive destruction process of coal rock, damage variable was defined as the ratio of dissipated energy density to total absorbed energy density. The maximum damage rate was obtained by deriving damage variable to reflect its maximum failure severity, then a brittleness index BD was established based on the maximum damage rate. BD value declined gradually as confining pressure and strain rate increase, indicating the decrease of brittleness and destruction degree. When confining pressure rises to 12 MPa, brittleness index and average fragmentation gradually stabilize, which shows confining pressure growing cannot cause continuous damage. Finally, integrating dynamic deformation and destruction process of coal rock and according to its final failure characteristics under different confining pressures, BD value is used to classify the brittleness into four grades.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.352-359
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• 2005

본 논문에서는 암모니아의 전해 분해를 위한 분리막 반응기의 음극방 및 양극방에서 물의 전해에 따른 암모니아 용액의 pH 변화가 고찰되었으며, 단위 전해 셀이 적층된 다단 전해 반응기에서의 암모니아의 연속식 분해 특성이 평가되었다. 분리막을 가지는 반응기에서 암모니아 용액의 전해 반응 시, 양극에서는 pH가 8 이하에서부터 수소 이온이 생성되는 물 분해 반응이 일어나며, 음극에서는 pH가 11 이상에서부터 수산기 이온이 생성되는 물 분해 반응이 일어나 암모니아 용액의 pH를 변화시켜 암모니아 전해 분해에 영향을 크게 미쳤으며, 음이온 교환막을 사용하는 경우가 양이온 교환막을 사용하는 경우보다 양극방에서 암모니아 분해에 유리한 알카리 분위기를 보다 효과적으로 유지할 수 있었다. 분리막 전해 반응기의 특성을 이용하여 자체 pH 조정 기능을 가지는 연속식 암모니아 전해 반응기가 새롭게 고안하였고, 여기서는 pH-조정조 탱크 용액을 두고 이의 용액 일부를 음극방으로 순환시킴으로써, 양극방으로 주입되는 pH-조정조의 용액의 pH를 높여 암모니아 분해율을 높일 수 있었다. 또한, 그러한 반응기를 이용한 salt-free 연속식 암모니아 전해 분해 공정이 제시되었으며, 이러한 공정에서는 염소 이온을 가지는 암모니아 용액의 80％까지 연속적으로 암모니아를 환경에 무해한 질소로 분해 시킬 수 있었다.

• 대한산업공학회지
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• 제31권1호
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• pp.20-26
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• 2005

This paper proposes the heuristic algorithm for the generalized GT problems to consider the restrictions which are given the number of machine cell and maximum number of machines in machine cell as well as minimum number of machines in machine cell. This approach is split into two phase. In the first phase, we use the similarity coefficient which proposes and calculates the similarity values about each pair of all machines and sort these values descending order. If we have a machine pair which has the largest similarity coefficient and adheres strictly to the constraint about birds of a different feather (BODF) in a machine cell, then we assign the machine to the machine cell. In the second phase, we assign parts into machine cell with the smallest number of exceptional elements. The results give a machine-part grouping. The proposed algorithm is compared to the Modified p-median model for machine-part grouping.

• 한국기계가공학회지
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• 제10권3호
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• pp.73-78
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• 2011

This study contains to theory and analysis research for the stress and the translation of an expand disk that fix a ring gear for tooth profile machining. The stress of the expand disk is analysed by the finite element method(FEM) to calculate design parameters. From the analysis results, the stress of the expand shows a linear tendency under various fixing force. This results show that the expand disk have a elastic characteristics as a disk spring. The maximum stress was observed on under side in split section of the expand disk. It is verified that the analysis results are useful to calculate design parameters of the expand disk.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2001년도 추계학술대회(한국공작기계학회)
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• pp.196-201
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• 2001

This study reveals the thin sheet metal process with multi-forming die that the name is progressive die, as a pilotless type, also high precision production part is made. They require analysis of many kinds of important factors, i.e. theory and practice of metal press working and its phenomena die structure, machining condition for die making, die material, heat treatment of die components, know-how and so on. In this study, we designed and constructed a multi-forming progressive die as a bending and drawing working of multi-stage and performed through the try out for thin sheet metal. Out of the characteristics of this paper that nothing might be ever seen before such as this type of research method on the all of processes of thin and high precision production part.

• 한국전기전자재료학회논문지
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• 제14권10호
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• pp.779-784
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• 2001

In this work, we studied the characteristics of nitride films for the optimization of PMD(pro-metal dielectric) linear process, which can be applied to the recent semiconductor manufacturing process. We split the deposit condition of nitride films into four parts such as PO(protect overcoat) nitride, baseline, low hydrogen and high stress and low hydrogen, respectively. We tried to find out correlation between BPSG deposition and densification. In order to analyze the changes of Si-H and Si-NH-Si bonding density, we used FTIR area method. We also investigated the crack generation on wafer edge after BPSG densification, and the changes of nitride film stress as a function of RF power variation to judge whether the deposited films.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2000년도 추계학술대회 논문집
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• pp.78-81
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• 2000

In this study the plasic flow before welding stage in the cahamber is analyzed by FEM and experiments during the porthole extrusion process. The analysis is concerned with plastic flow in the port and welding chamber of rectangular hollow section extrusion through the porthole die with mandrell. Numerical simulation by finite element code to investigate the plastic flow is discussed for both tapered inlet and straight inlet chamber. To visualize the flow in extrusion process split dies and punches are designed and manufactred by wire EDM. Experiments are carried out by using the plasticine as a model material at room temperature. The theoretical predictions are reasonable agreements with experimental results in the welding lines and the deformed profiles.

• 소성∙가공
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• 제10권6호
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• pp.485-492
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• 2001

The paper is concerned with plastic flow in the port and welding chamber of rectangular hollow section extrusion through the porthole die. The extrusion process is analyzed by numerical simulation and experiments in the unsteady state. The effects of types of inlet with and without taper on the flow and extrusion load are mainly discussed and compared by FEA and experiments. Experiments are carried out by using the plasticine as a model material at room temperature. To visualize the plastic flow in the extrusion process, some split dies and punches are designed and manufactured by EDM. The theoretical predictions by FEM are reasonable agreements with experimental results on the deformed configurations and welding lines.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.1705-1708
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• 2003

The purpose of this study is to investigate the manufacturing technique on the U type Draw-Bending of inner grooved tube. This bending process make the U shape tube by Hair Pin Bending machine. The U type tube requires the quality of product that satisfy sufficient conditions for a heat exchanger. The mandrel components act the important roles that prevent wrinkles and keep the shape of cross section of bended tube at bending process. We performed the FEM simulation using LS-DYNA software and the bending test of inner groove tube and then, compared bending simulation with bending test results about mandrel ball diameter, mandrel position and optimal clearance between mandrel and tube.