• Bulletin of the Korean Chemical Society
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• v.26 no.6
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• pp.903-908
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• 2005

The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.

• Food Science and Preservation
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• v.16 no.3
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• pp.385-391
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• 2009

Analytical electron spin resonance (ESR) parameters were investigated in irradiated seasonings after exposure to different radiation sources. Two commercial seasonings (SS-1 and SS-2) were irradiated with 0.20 kGy under ambient conditions using a $^{60}Co$ gamma-ray irradiator or an electron beam accelerator. Crystalline sugar-induced multi-component signals with g-values of 2.031, 2.021, 2.017, 2.009, 2.002, 1.990, and 1.980 were observed in both irradiated samples, whereas singlet signals were detected in non-irradiated materials, thereby distinguishing irradiated from control samples. Under the same analytical conditions, the ESR signal intensity of electron beam-irradiated samples was greater than that of gamma-irradiated materials. Determination coefficients (R2 values) between irradiation doses and corresponding ESR responses were 0.9916-0.9973 for all samples, and the magnetic field of specified g-values for irradiated samples remained constant. The predominant ESR signals of g2 (2.021), g4 (2.009), g5 (2.002), and g6 (1.990) showed high correlations with the corresponding irradiation doses (R2=0.8243 - 0.9929).

• International Journal of Aeronautical and Space Sciences
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• v.8 no.2
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• pp.17-27
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• 2007

Minimum-time attitude maneuvers of three-axis stabilized spacecraft are presented to study the feasibility of using three magnetic torquers perform large angle maneuvers. Previous applications of magnetic torquers have been limited to spin-stabilized satellites or supplemental actuators of three axis stabilized satellites because of the capability of magnetic torquers to produce torques about a specific axes. The minimum-time attitude maneuver problem is solved by applying a parameter optimization method for orbital cases to verify that the magnetic torque system can perform as required. Direct collocation and a nonlinear programming method with a constraining method by Simpson's rule are used to convert the minimum-time maneuver problems into parameter optimization problems. An appropriate number of nodes is presented to find a bang-bang type solution to the minimum-time problem. Some modifications in the boundary conditions of final attitude are made to solve the problem more robustly and efficiently. The numerical studies illustrate that the presented method can provide a capable and robust attitude reorientation by using only magnetic torquers. However, the required maneuver times are relatively longer than when thrusters or wheels are used. Performance of the system in the presence of errors in the magnetometer as well as the geomagnetic field model still good.

• Proceedings of the KIEE Conference
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• 1998.07e
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• pp.1758-1760
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• 1998

MgO Protecting layer in AC PDP prevents ion bombardment in discharge plasma. The MgO layer also has the additional importance in lowering the firing voltage due to a large secondary electron emission coefficient. Until now, the MgO protecting layer is mainly prepared by E-beam Evaporation. However, the optimum activation manufacturing process of MgO thin film wasn't well known. Therefore in this study, after MgO protecting layer is prepared on dielectric layer by E-beam evaporation and liquid MgO spin coating, we carried out activation process of MgO thin film as a parameter of Temperature, Operating time and Operating pressure. In addition, discharge characteristics are also studied as a parameter of activation conditions.

• International Journal of Automotive Technology
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• v.8 no.4
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• pp.467-476
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• 2007

This work verifies the chaotic motion of a steer-by-wire vehicle dynamic system, and then elucidates an application of dither smoothing to control the chaos of a vehicle model. The largest Lyapunov exponent is estimated from the synchronization to identify periodic and chaotic motions. Then, a bifurcation diagram reveals complex nonlinear behaviors over a range of parameter values. Finally, a method for controlling a chaotic vehicle dynamic system is proposed. This method involves applying another external input, called a dither signal, to the system. The designed controller is demonstrated to work quite well for nonlinear systems in achieving robust stability and protecting the vehicle from slip or spin. Some simulation results are presented to establish the feasibility of the proposed method.

• Journal of the Korean Magnetic Resonance Society
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• v.7 no.1
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• pp.16-24
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• 2003

Nuclei with the spin quantum number not smaller than unity have not only the nuclear magnetic moment but also the electric quadrupole moment. The quadrupole moment couples with the electric field gradient (EFG) to produce the nuclear quadrupole interaction. It is well known that two independent parameters, i.e. the quadrupole coupling constant (QCC) and the asymmetry parameter ($\eta$) together with the principal axis directions can fully describe the interaction and are very sensitive to the local symmetry and structure of the solid. In order to obtain quantitative estimates of the EFG tensor for various simple ionic configurations surrounding the nucleus under consideration, we employ the simple point charge approximation and apply the calculated results to some real crystals. General agreement is rather satisfactory.

• Journal of Advanced Marine Engineering and Technology
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• v.16 no.4
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• pp.39-49
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• 1992

The coherent wake structures behind a spinning cylinder placed in a uniform flow were experimentally investigated by means of phase averaging technique. With a fixed cylinder Reynolds number (Re=6,600), the conditionally sampled velocity vectors were obtained at a section of 3.0 and 10 diameters behind the cylinder for the range of spin parameter S(the ratio of the peripheral velocity to that of the uniform flow) 0 to 2. Spectral analysis and vorticity contours of the velocity data show that up to S=1.2, a Karman vortex street exists within the wake, however, the coherent structures become obscure and their vorticity strength decreases as S increase. Beyond S=1.2, a distinct vortex shedding frequency no longer exists, furthermore coherent structures disappear when S is over 1.6.

• Transactions of Materials Processing
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• v.17 no.1
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• pp.19-26
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• 2008

In the present work, the ratcheting behavior under uniaxial cyclic loading is analyzed. A comparison between the published and the results from the present model is also included. In order to simulate the ratcheting behavior, Two-Back Stress model is proposed by combining the non-linear Armstrong-Frederick rule and the non-linear Phillips hardening rule based on kinematic hardening equation. It is shown that some ratcheting behaviors can be obtained by adjusting the control material parameters and various evolutions of the kinematic hardening parameter can be obtained by means of simple combination of hardening rules using simple rule of mixtures. The ultimate back stress is also derived for the present combined kinematic hardening models.

• Journal of Magnetics
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• v.3 no.4
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• pp.127-133
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• 1998

I have overviewed the change in GMR on annealing, in conjunction with the change in microstructure. The Co46Al19O35 granular thin films were annealed at 30$0^{\circ}C$ for various annealing time to change the microstructure. The magnitude of GMR decreases considerably with increasing annealing time, although the size of Co granules estimated from TEM observation show a small change. Parameter fits of magnetization curves and magnetoresistance curves to the Langevin function suggest that large clusters consisting of several small Co granules, which are coupled ferromagnetically, are related with the decrease of GMR on annealing. The temperature dependence of electrical resistivity ($\rho$) shows the relationship of log $\rho$ versus $T^{-1/2}$ for the sample annealed for 10 min., 1 hr. and 6 hrs. However, the sample annealed for 38 hrs. shows the relationship of log $\rho$ versus$ T^{-1/4},$ which represents a significant change in the transport mechanism.

• Current Optics and Photonics
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• v.3 no.4
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• pp.275-284
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• 2019

Chirality is ubiquitous in physics and biology from microscopic to macroscopic phenomena, such as fermionic interactions and DNA duplication. In photonics, chirality has traditionally represented differentiated optical responses for right and left circular polarizations. This definition of optical chirality in the polarization domain includes handedness-dependent phase velocities or optical absorption inside chiral media, which enable polarimetry for measuring the material concentration and circular dichroism spectroscopy for sensing biological or chemical enantiomers. Recently, the emerging field of non-Hermitian photonics, which explores exotic phenomena in gain or loss media, has provided a new viewpoint on chirality in photonics that is not restricted to the traditional polarization domain but is extended to other physical quantities such as the orbital angular momentum, propagation direction, and system parameter space. Here, we introduce recent milestones in chiral light-matter interactions in non-Hermitian photonics and show an enhanced degree of design freedom in photonic devices for spin and orbital angular momenta, directionality, and asymmetric modal conversion.