• Computers and Concrete
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• 제4권6호
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• pp.425-436
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• 2007

This study is mainly focused on applying Fuller's ideal gradation curve to theoretically design blended ratio of all solid materials of a reactive powder mortar (RPM), also known as reactive powder concrete (RPC), with the aid of error function, and then to study the effect of fly ash/slag on the performance of RPM. The solid particle is assumed to be spherical particles. Then, the void volume of paste ($V_{\nu}$) and the paste content with specific quality can be obtained. As conclusion, under Fuller's ideal grading curve, the amount of fly ash/slag mixture is higher than that with silica fume along due to it better filled the void within solid particle and obtains higher packing density.

• 동력기계공학회지
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• 제10권4호
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• pp.133-138
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• 2006

Effective thermal conductivity of particulate reinforced composite has been predicted by Eshelby's equivalent inclusion method modified with Mori-Tanaka's mean field theory. The predicted results are compared with the experimental results from the literature. The model composite is polymer matrix filled with ceramic particles such as silica, alumina, and aluminum nitride. The preliminary examination by Eshelby type model shows that the predicted results are in good agreements with the experimental results for the composite with perfect spherical filler. As the shape of filler deviates from the perfect sphere, the predicted error increases. By using the aspect ratio of the filler deduced from the fixed filler volume fraction of 30%, the predicted results coincide well with the experimental results for filler volume fraction of 40% or less. Beyond this fraction, the predicted error increases rapidly. It can be finally concluded from the study that Eshelby type model can be applied to predict the thermal conductivity of the particulate composite with filler volume fraction less than 40%.

• Korean Chemical Engineering Research
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• 제58권1호
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• pp.142-149
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• 2020

본 연구에서는 인조흑연의 낮은 이론용량을 개선하기 위하여 음극소재로서 흑연/실리콘/피치 복합소재의 전기화학적 성능을 조사하였다. 구형의 인조 흑연 표면을 polyvinylpyrrolidone (PVP) 양친성 물질로 코팅한 후 실리카를 성장시켜 흑연/실리카 소재를 합성하였으며, 석유계 피치 코팅과 마그네슘 열 환원법을 통해 흑연/실리콘/피치 복합소재를 제조하였다. 흑연/실리콘/피치 복합소재의 전극은 poly(vinylidene fluoride) (PVDF), carboxymethyl cellulose (CMC), polyacrylic acid (PAA) 바인더에 따라 제조하였으며, 다양한 전해액과 첨가제를 이용하여 전지를 조립하였다. 흑연/실리콘/피치 복합소재는 X-ray diffraction (XRD), scanning electron microscope (SEM)와 thermogravimetric analyzer (TGA)를 통해 물리적 특성을 분석하였으며, 전기화학적 특성은 충 방전 사이클, 율속, 순환전압전류, 임피던스 테스트를 통해 조사하였다. 흑연/실리콘/피치 복합소재는 흑연 : 실리카 : 피치 = 1 : 4 : 8일 때 높은 사이클 안정성을 보였다. PAA 바인더를 사용하여 제조된 전극은 높은 용량과 안정성을 보였으며, EC:DMC:EMC 전해액을 사용하였을 때 719 mAh/g의 높은 초기 용량과 우수한 사이클 안정성 나타내었다. 또한 vinylene carbonate (VC) 첨가시에 2 C/0.1 C 일 때 77% 용량 유지율과 0.1 C/0.1 C 일 때 88% 용량 회복을 나타냄을 확인하였다.

• Korean Chemical Engineering Research
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• 제40권6호
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• pp.752-756
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• 2002

PDP(Plasma Display Panel)용 녹색 형광체인 $Zn_2SiO_4:Mn$ 형광체의 제조에 있어 콜로이드 분무 열분해법을 도입하고, $Zn_2SiO_4$ wellimite 결정의 $Si^{4+}$ 자리를 치환하는 $Gd^{3+}/Li^+$ 부활성제를 첨가하여 형광체의 발광특성을 향상시키고자 하였다. 14 nm 크기의 fumed silica 입자를 규소 전구체로 도입한 콜로이드 분무열분해법에 의해서 제조되어진 $Zn_2SiO_4:Mn$ 입자는 응집이 없는 구형의 형상, 작은 입자 크기 및 좁은 입도 분포를 가졌다. $Gd^{3+}/Li^+$ 함량은 $Zn_2SiO_4:Mn$ 형광체 입자의 발광특성에 영향을 끼쳤으며, 적정한 함량의 $Gd^{3+}/Li^+$ 부활성제를 첨가함으로써 진공 자외선하에서 형광체의 발광휘도를 향상시키고, 잔광시간을 크게 줄일 수 있었다. 분무 열분해법에 의한 $Gd^{3+}/Li^+$이 코도핑된 $Zn_2SiO_4:Mn$ 형광체 입자의 제조에 있어서 후열처리 온도는 형광체의 발광특성을 결정짓는 주요한 인자이다. 0.1 mol%의 $Gd^{3+}/Li^+$ 부활제를 포함하고 $1,145^{\circ}C$ 온도에서 소결된 $Zn_2SiO_4:Mn$ 형광체 입자는 상업용 형광체에 비해 5% 높은 발광 휘도과 5.7 ms의 잔광시간을 가졌다.

• 공업화학
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• 제21권4호
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• pp.417-423
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• 2010

파라자일렌(p-xylene) 분리용 흡착제로서 효과적인 그래뉼 형태의 바인더리스 ZSM-5 성형체를 제조하는 방법을 검토하였다. $SiO_2/Al_2O_3$ = 50인 ZSM-5 결정분말에 무기 바인더인 colloidal silica sol 30 wt% 용액과 유기첨가물인 microcrystalline cellulose를 첨가하여 구형화한 후, 소성, 바인더리스 처리, ${NH_4}^+$ 이온교환, 활성화 등의 과정을 거쳐 충분한 강도(0.721 kgf) 및 높은 결정화도(94.6%)와 넓은 BET 비표면적($379.2m^2$/g)을 갖는 흡착제를 제조하였다. 제조된 성형체의 흡착특성을 평가하기 위해 자일렌 3가지 이성질체를 1 : 1 : 1의 무게비로 혼합하여 $100^{\circ}C$에서 회분식 흡착실험을 수행한 결과 제조된 바인더리스 ZSM-5 성형체는 상용흡착제보다 파라자일렌에 대해 높은 선택적 흡착성능을 나타냈다.

• 한국세라믹학회지
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• 제31권9호
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• pp.1076-1086
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• 1994

This study covers synthetic effect of the various hydrothermal treatments on formation of artificially made kaolinite mineral. The hydrothermal treatment includes the temperature treatment with time duration, addition of seeds, particle size of the starting material used, pH variation and the different types of organic acids. A colloidal silica and alumina sol which are commercially available are used for this study. A colloidal silica and alumina sol are mixed by the atomic ratio of Al/Si = 1, based on the theoretical kaolinite composition and calcined at $600^{\circ}C$ for 8 hours duration. It was found that the kaolinitic clay mineral was well developed; thereby, the different patterns of crystalline mineral are appeared. Spherical type as a crystal form was distinctively formed at the temperature of 20$0^{\circ}C$ to 25$0^{\circ}C$ with short duration time, while platy type as a crystal was highly yielded at 300~35$0^{\circ}C$. Moreover, by adding more than 20 wt% of seed as the natural kaolinitic clay to the starting material is widely distributed and developed when 2 ${\mu}{\textrm}{m}$ or less particle size of the starting material is used; also, when they are heat-treated at the temperature of 25$0^{\circ}C$ with 5 hours duration. With respect of the effect of pH variation on formation of the synthetic kaolinite minerals, the crystalline minerals are highly yielded at less than pH 2 and gradually diminished at more than pH9. Regarding to the effect of different acids on development of the kaolinite mineral, the organic acids with high chelating capacity produces good formation of crystalline minerals; whereas, amine radical-(NH2) is not an effective agent to generate the crystalline minerals.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.610-615
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• 2001

Over 800 thousand tons per year (TPY) agricultural biowastes, such as sugar cane bagasse, sugarcane leaf, rice straw, rice husk and corn leaf, are produced in Taiwan. These biomasses are the major types of agricultural wastes and are abundantly available. However, these biowastes cause disposal and landfill problems. Ossification ashes of the agricultural biowastes containing 70-95 % amorphous silica would make the utilization system of agricultural biowaste ashes become highly economically and environmentally attractive. Experimentally, high crystallinity (99%$^{+}$) zeolites ZSM-5 and ZSM-48 synthesized from the reaction mixtures containing a silica source from ashes of these biowastes gasification were investigated. Tetrapropylammonium bromide (TPABr) and 1,6-diamino-hexane (C$_{6}$ DN) were used as structure-directing agents in syntheses of ZSM-5 and ZSM-48, respectively. X-ray powder diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDX) data indicated that ZSM-5 or ZSM-48 with a high crystallinity can be obtained within 48 hours of crystallization in the high pressure (15-20 atm) autoclave at 393-473 K. The Si/Al ratios of synthetic zeolite products were determined by X-ray fluorescence (XRF) and induced couple plasma/mass spectroscopy (ICP/MS). It was observed that the ZSM-5 crystals a.e composed of hexagonal rod-shaped crystals with typically 8-13 пm in size by SEM. In addition, ZSM-48 crystalline materials are composed of spherical aggregates of needle-shaped or rod-like crystals with typically 2-3 пm in diameter and 6-8 пm in length.h.

• 한국결정성장학회지
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• 제6권4호
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• pp.521-531
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• 1996

분무건조법을 이용하여 무기질막 microcapsule과 무기질/유기질막 microcapsule을 제조하였다. 무기질막 microcapsule은 core 물질로 $K_{4}SO$와 clay shell 물질로 colloidal silica를 사용하였고, 무기질/유기질막 microcapsule은 core 물질로 상기 제조된 무기질막 microcapsule을 shell 물질로는 ethyl cellulose를 사용하여 각각의 microcapsule를 제조하였다. 제조된 microcapsule이 기능성을 갖기 위하여는 구형의 균일한 표면과 세공용적이 매우 중요하다. 무기질막 microcapsule인 경우 core/shell의 체적비가 0.3/0.7인 경우 구형의 균일한 표면의 microcapsule이 제조되었으며, 무기질/유기질막 microcapsule인 경우, 무게비가 0.76/0.24일 때 균일한 표면을 갖는 microcapsule이 제조되었다. 무기질/유기질막 microcapsule인 경우, 무기질막 microcapsule보다 세공용적이 감소하였고, shell물질(ethyl cellulose)의 양이 증가할수록 피복이 균일하게 되며, 세공용적도 감소하였다.

• 반도체디스플레이기술학회지
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• 제9권2호
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• pp.33-39
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• 2010

The moisture absorption properties such as diffusion coefficient and moisture content ratio of liquid type epoxy resin systems with the filler were investigated. Bisphenol A type and Bisphenol F type epoxy resin, Kayahard MCD as hardener and 2-methylimidazole as catalyst were used in these epoxy resin systems. The nano-sized spherical type fused silica as filler were used in order to study the moisture absorption properties of these liquid type epoxy encapsulant according to the change of filler size. The temperature of glass transition (Tg) of these epoxy resin systems was measured using Dynamic Scanning Calorimeter (DSC), and the moisture absorption properties of these epoxy resin systems according to the change of time were observed at $85^{\circ}C$ and 85% relative humidity condition using a thermo-hygrostat. The diffusion coefficients in these systems were calculated in terms of modified Crank equation based on Ficks' law. An increase of Tg and diffusion coefficient with filler size in these systems can be observed, which are attributed to the increase of free volume with Tg. The change of maximum moisture absorption ratio according to the filler size and filler content cannot be observed; however, the diffusion coefficients of these systems decreased with filler content. The diffusion via free volume is dominant in the epoxy resin systems with low nano-sized filler content; however, the diffusion with the interaction of absorption according the increase of the filler surface area is dominant in the liquid type epoxy encapsulant with high nano-sized filler content.

• Journal of Electrochemical Science and Technology
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• 제12권1호
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• pp.137-145
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• 2021

Among the non-precious metal catalysts, iron-nitrogen doped carbon (Fe-N/C) catalysts have been recognized as the most promising candidates for an alternative to Pt-based catalysts for the oxygen reduction reaction (ORR) under alkaline and acidic conditions. In this study, the nano replication method using mesoporous silica, which features tunable primary particle sizes and shape, is employed to prepare the mesoporous Fe-N/C catalysts with different shapes. Platelet SBA-15, irregular KIT-6, and spherical silica particle (SSP) were selected as a template to generate three different kinds of shapes of the mesoporous Fe-N/C catalyst. Physicochemical properties of mesoporous Fe-N/C catalysts are characterized by using small-angle X-ray diffraction, nitrogen adsorption-desorption isotherms, and scanning electron microscopy images. According to the electrochemical evaluation, there is no morphological preference of mesoporous Fe-N/C catalysts toward the ORR activity with half-cell configuration under alkaline electrolyte. By implementing X-ray photoelectron spectroscopy analysis of Fe and N atoms in the mesoporous Fe-N/C catalysts, it is possible to verify that the activity towards ORR highly depends on the portions of "Fe-N" species in the catalysts regardless of the shape of catalysts. It was suggested that active site distribution in the Fe-N/C is one important factor towards ORR activity.