• Title/Summary/Keyword: Spectrum shift

Search Result 364, Processing Time 0.022 seconds

$^{13}C$ Nuclear Magnetic Resonance Study of Graphite Intercalated Superconductor $CaC_6$ Crystals in the Normal State ($CaC_6$ 결정에 대한 정상상태에서의 $^{13}C$ 핵자기공명 측정)

  • Kim, Sung-Hoon;Kang, Ki-Hyeok;Mean, B.J.;Ndiaye, B.;Lee, Moo-Hee;Kim, Jun-Sung
    • Progress in Superconductivity
    • /
    • v.12 no.1
    • /
    • pp.51-56
    • /
    • 2010
  • $^{13}C$ NMR (nuclear magnetic resonance) measurements have been performed to investigate the local electronic structure of a superconducting graphite intercalation compound $CaC_6$ ($T_c$ = 11.4 K). A large number of single crystals were stacked and sealed in a quartz tube for naturally abundant $^{13}C$ NMR. The spectrum, Knight shift, linewidth, and spin-lattice relaxation time $T_1$ were measured in the normal state as a function of temperature down to 80 K at 8.0 T perpendicular to the c-axis. The $^{13}C$ NMR spectrum shows a single narrow peak with a very small Knight shift. The Knight shift and the linewidth of the $^{13}C$ NMR are temperature-independent around, respectively, +0.012% and 1.2 kHz. The spin-lattice relaxation rate, $1/T_1$, is proportional to temperature confirming a Korringa behavior as for non-magnetic metals. The Korringa product is measured to be $T_1T\;=\;210\;s{\cdot}K$. From this value, the Korringa ratio is deduced to be $\xi$ = 0.73, close to unity, which suggests that the independent-electron description works well for $CaC_6$, without complications arising from correlation and many-body effects.

OFDM based mimicking dolphin whistle for covert underwater communications (OFDM 기반 돌고래 휘슬음 모방 수중 은밀 통신 기법)

  • Lee, Hojun;Ahn, Jongmin;Kim, Yongcheol;Seol, Seunghwan;Kim, Wanjin;Chung, Jaehak
    • The Journal of the Acoustical Society of Korea
    • /
    • v.40 no.3
    • /
    • pp.219-227
    • /
    • 2021
  • This paper proposed an Orthogonal Frequency Division Multiplexing (OFDM) based biomimetic communication method using a dolphin whistle which covertly transmits communication signals to allies. The proposed method divides the dolphin whistle into several time slots corresponding to a number of OFDM symbols, and modulates the communication signal by mapping differential phase shift keying (DPSK) symbols into subcarriers that have the frequency bands of the dolphin whistle in each slot. The advantages of the proposed method are as follows: In the conventional Chirp Spread Spectrum (CSS) and Frequency Shift Keying (FSK) based biomimetic communication methods, the discontinuity of the frequency contour is large, but the proposed method can reduce the discontinuity. Even if the modulation order is increased, the degradation of the mimicking performance is small. The computer simulations demonstrate that the Bit Error Rate (BER) and mimicking performance of the proposed method are better performance than those of the conventional CSS and FSK.

Spectroscopic Analysis of Partially Folded State of Ubiquitin (유비퀴틴 단백질의 부분적으로 폴딩된 구조에 대한 분광학적 분석)

  • Park, Soon-Ho
    • Applied Biological Chemistry
    • /
    • v.46 no.4
    • /
    • pp.305-310
    • /
    • 2003
  • Hydrophobic core variant of ubiquitin appeared to have partially folded structure at pH around 2. The intrinsic tryptophan fluorescence emission maximum of this ubiquitin variant at pH 2 showed slight blue shift compare to that of unfolded state, suggesting that some residual tertiary structures remain in this solvent condition. At the same solvent condition, this ubiquitin variant binds with hydrophobic dye, 8-anilinonaphthalene-1-sulfonic acid(AMS), which is known to bind to exposed hydrophobic surface. Furthermore, far-UV circular dichroic spectrum of this ubiquitin variant in the diminished pH was remarkably different from the far-UV CD spectrum of the native state or unfolded state. Based on the molar ellipticity at 220 nm, this ubiquitin variant at pH 2 appeared to have significant amount of secondary structures. All these observations suggest that this ubiquitin variant in the diminished solvent pH has loosely folded hydrophobic core with some secondary structures, which are key features of molten globule conformation. Since molten globule has long been considered as a protein folding intermediate, it is considered that this hydrophobic core variant ubiquitin will serve as a valuable model to study protein folding process.

Performance analysis and experiment results of multiband FSK signal based on direct sequence spread spectrum method (직접 수열 확산 방식 기반 다중 밴드 FSK 신호의 성능 분석 및 실험 결과)

  • Jeong, Hyun-Woo;Shin, Ji-Eun;Jung, Ji-Won
    • The Journal of the Acoustical Society of Korea
    • /
    • v.40 no.4
    • /
    • pp.370-381
    • /
    • 2021
  • This paper presented an efficient transceiver structure of multiband Frequency Shift Keying (FSK) signals with direct sequence spread spectrum for maintaining covertness and performance. In aspect to covertness, direct sequence spread spectrum method, which multiplying by Pseudo Noise (PN) codes whose rate is much higher than that of data sequence, is employed. In aspect to performance, in order to overcome performance degradation caused by multipath and Doppler spreading, we applied multiband, turbo equalization, and weighting algorithm are applied. Based on the simulation results, by applying 4 number of multiband and number of chips are 8 and 32, experiments were conducted in a lake with a distance of moving from 300 m to 500 m between the transceivers. we confirmed that the performance was improved as the number of bands and chips are increased. Furthermore, the performance of multiband was improved when the proposed weighting algorithm was applied.

Cancellation of MRI Motion Artifact in Image Plane

  • Kim Eung-Kyeu
    • Journal of the Institute of Convergence Signal Processing
    • /
    • v.1 no.1
    • /
    • pp.49-57
    • /
    • 2000
  • In this study, a new algorithm for canceling a MRI artifact due to the translational motion In the image plane is described. Unlike the conventional iterative phase retrieval algorithm, in which there is no guarantee for the convergence, a direct method for estimating the motion is presented. In previous approaches, the motions in the x(read out) direction and the y(phase encoding) direction were estimated simultaneously. However, the feature of x and y directional motions are different from each other. By analyzing their features, each x and y directional motion is canceled by the different algorithms in two steps. First, it is noticed that the x directional motion corresponds to a shift of the x directional spectrum of the MRI signal, and the non-zero area of the spectrum just corresponds to the projected area of the density function on the x axis. So the motion is estimated by tracing the edges between non-zero area and zero area of the spectrum, and the x directional motion is canceled by shifting the spectrum in an reverse direction. Next, the y directional motion is canceled by using a new constraint condition, with which the motion component and the true image component can be separated. This algorithm is shown to be effective by using a phantom image with simulated motion.

  • PDF

Analysis of Spectrum Sharing Policy and Spectrum Usage Rights (주파수 공동사용 정책 및 주파수 이용권 분석)

  • Kim, Chang-Joo;Kang, Young-Heung;Kye, Kyung-Moon;Kim, Young Soo;Park, Duk-Kyu;Park, Seokji;Bae, Jung-Kee;Yoon, Hyun-Bo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.24 no.8
    • /
    • pp.805-819
    • /
    • 2013
  • In this paper, we analyze the paradigm shift of radio policy with the development of radio technology. In particular, we propose the definition of spectrum sharing, which is now omitted in the Korean radio law, and analyze the category of spectrum sharing depending on the licensing regime. Also we propose to extend the spectrum usage right, which defines only exclusive usage rights by spectrum auction in the Korean radio law, to all the stations which use radio spectrum and to restructure the Korean radio law.

Excitation Energy Induced S-shaped PL behavior in Graphene Quantum Dots

  • Jang, Min-Ho;Jo, Yong-Hun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.351.2-351.2
    • /
    • 2016
  • Graphene quantum dots (GQDs) have attracted much attention because of various advantages such as cost-effectiveness of synthesis, low toxicity, and photostability. The origins of photoluminescence (PL) in GQDs were suggested as the intrinsic states for localized sp2 carbon domains and the extrinsic states formed by oxygen-functional groups.[1,2] Nevertheless, it is still unclear to understand the information of electric band structure in GQD. Here, we observed excitation energy induced S-shaped PL behavior. The PL peak energy position shows an S-shaped shift (redshift-blueshift-redshift) as function of the excitation wavelengths. From various samples, we only observed S-shaped PL shift in the GQDs with both luminescent origins of intrinsic and extrinsic states. Therefore, this S-shaped PL shift is related to different weight of intrinsic and extrinsic states in PL spectrum depending on the excitation wavelengths. This would be the key result to understand the electric band structure of the GQDs and its derivatives.

  • PDF

Large Solvent and Noise Peak Suppression by Combined SVD-Harr Wavelet Transform

  • Kim, Dae-Sung;Kim, Dai-Gyoung;Lee, Yong-Woo;Won, Ho-Shik
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.7
    • /
    • pp.971-974
    • /
    • 2003
  • By utilizing singular value decomposition (SVD) and shift averaged Harr wavelet transform (WT) with a set of Daubechies wavelet coefficients (1/2, -1/2), a method that can simultaneously eliminate an unwanted large solvent peak and noise peaks from NMR data has been developed. Noise elimination was accomplished by shift-averaging the time domain NMR data after a large solvent peak was suppressed by SVD. The algorithms took advantage of the WT, giving excellent results for the noise elimination in the Gaussian type NMR spectral lines of NMR data pretreated with SVD, providing superb results in the adjustment of phase and magnitude of the spectrum. SVD and shift averaged Haar wavelet methods were quantitatively evaluated in terms of threshold values and signal to noise (S/N) ratio values.

Analysis of the Temperature Dependence of Phosphor Conversion Efficiency in White Light-Emitting Diodes

  • Ryu, Guen-Hwan;Ryu, Han-Youl
    • Journal of the Optical Society of Korea
    • /
    • v.19 no.3
    • /
    • pp.311-316
    • /
    • 2015
  • We investigate the temperature dependence of the phosphor conversion efficiency (PCE) of the phosphor material used in a white light-emitting diode (LED) consisting of a blue LED chip and yellow phosphor. The temperature dependence of the wall-plug efficiency (WPE) of the blue LED chip and the PCE of phosphor are separately determined by analyzing the measured spectrum of the white LED sample. As the ambient temperature increases from 20 to $80^{\circ}C$, WPE and PCE decrease by about 4.5% and 6%, respectively, which means that the contribution of the phosphor to the thermal characteristics of white LEDs can be more important than that of the blue LED chip. When PCE is decomposed into the Stokes-shift efficiency and the phosphor quantum efficiency (QE), it is found that the Stokes-shift efficiency is only weakly dependent on temperature, while the QE decreases rapidly with temperature. From 20 to $80^{\circ}C$ the phosphor QE decreases by about 7% while the Stokes-shift efficiency changes by less than 1%.

Variations of imaging depth and chloroplast emission spectrum of Arabidopsis thaliana with excitation wavelength in two-photon microscopy (이광자현미경 여기 광 파장에 따른 Arabidopsis thaliana 촬영 깊이 및 엽록체 형광 스펙트럼의 변화)

  • Joo, Yongjoon;Son, Si Hyung;Kim, Ki Hean
    • Journal of the Korean Society of Visualization
    • /
    • v.12 no.3
    • /
    • pp.9-14
    • /
    • 2014
  • Two-photon microscopy (TPM) has been used in plant research as a high-resolution high-depth 3D imaging modality. However, TPM is known to induce photo-damage to the plant in case of long time exposure, and optimal excitation wavelength for plant imaging has not been investigated. Longer excitation wavelength may be appropriate for in vivo two-photon imaging of Arabidopsis thaliana leaves, and effects of longer excitation wavelength were investigated in terms of imaging depth, emission spectrum. Changes of emission spectrum as a function of exposure time at longer excitation wavelength were measured for in vivo longitudinal imaging. Imaging depth was not changed much probably because photon scattering at the cell wall was a limiting factor. Chloroplast emission spectrum showed its intensity peak shift by 20 nm with transition of excitation wavelength from 849 nm or below to 850 nm or higher. Emission spectrum showed different change patterns with excitation wavelengths in longitudinal imaging. Longer excitation wavelengths appeared to interact with chloroplasts differently in comparison with 780 nm excitation wavelength, and may be good for in vivo imaging.