• 제목/요약/키워드: Spectrum intensity

검색결과 626건 처리시간 0.043초

전면 유기 발광 소자의 유기물층 두께 변화에 따른 광학적 특성 (Organic-layer thickness dependent optical properties of top emission organic light-eitting diodes)

  • 안희철;주현우;나수환;김태완;홍진웅;오용철;송민종
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.413-414
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    • 2008
  • We have studied an organic layer thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top emission device, structure is Al(100nm)ITPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(23nm). While a thickness of hole-transport layer of TPD was varied from 35 to 65nm, an emissive layer thickness of $Alq_3$ was varied from 50 to 100nm for two devices. A ratio of those two layers was kept to about 2:3. Variation of the layer thickness changes a traverse time of injected carriers across the organic layer, so that it may affect on the chance of probability of exciton formation. View-angle dependent emission spectra were measured for the optical measurements. Top-emission devices show that the emission peak wavelength shifts to longer wavelength as the organic layer thickness increases. For instance, it shifts from 490 to 555nm in the thickness range that we used. View-angle dependent emission spectra show that the emission intensity decreases as the view-angle increases. The organic layer thickness-dependent emission spectra show that the full width at half maximum decreases as the organic layer thickness increases. Top emission devices show that the full width at half maximum changes from 90 to 35nm as the organic layer thickness increases. In top-emission device, the microcavity effect is more vivid as the organic layer thickness increases.

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Evaluation of seismic response of soft-storey infilled frames

  • Santhi, M. Helen;Knight, G.M. Samuel;Muthumani, K.
    • Computers and Concrete
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    • 제2권6호
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    • pp.423-437
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    • 2005
  • In this study two single-bay, three-storey space frames, one with brick masonry infill in the second and third floors representing a soft-storey frame and the other without infill were designed and their 1:3 scale models were constructed according to non-seismic detailing and the similitude law. The models were excited with an intensity of earthquake motion as specified in the form of response spectrum in Indian seismic code IS 1893-2002 using a shake table. The seismic responses of the soft-storey frame such as fundamental frequency, mode shape, base shear and stiffness were compared with that of the bare frame. It was observed that the presence of open ground floor in the soft-storey infilled frame reduced the natural frequency by 30%. The shear demand in the soft-storey frame was found to be more than two and a half times greater than that in the bare frame. From the mode shape it was found that, the bare frame vibrated in the flexure mode whereas the soft-storey frame vibrated in the shear mode. The frames were tested to failure and the damaged soft-storey frame was retrofitted with concrete jacketing and, subjected to same earthquake motions as the original frames. Pushover analysis was carried out using the software package SAP 2000 to validate the test results. The performance point was obtained for all the frames under study, therefore the frames were found to be adequate for gravity loads and moderate earthquakes. It was concluded that the global nonlinear seismic response of reinforced concrete frames with masonry infill can be adequately simulated using static nonlinear pushover analysis.

Large eddy simulation of wind effects on a super-tall building

  • Huang, Shenghong;Li, Q.S.
    • Wind and Structures
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    • 제13권6호
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    • pp.557-580
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    • 2010
  • A new inflow turbulence generation method and a combined dynamic SGS model recently developed by the authors were applied to evaluate the wind effects on 508 m high Taipei 101 Tower. Unlike the majority of the past studies on large eddy simulation (LES) of wind effects on tall buildings, the present numerical simulations were conducted for the full-scale tall building with Reynolds number greater than $10^8$. The inflow turbulent flow field was generated based on the new method called discretizing and synthesizing of random flow generation technique (DSRFG) with a prominent feature that the generated wind velocity fluctuations satisfy any target spectrum and target profiles of turbulence intensity and turbulence integral length scale. The new dynamic SGS model takes both advantages of one-equation SGS model and a dynamic production term without test-filtering operation, which is particular suitable to relative coarse grid situations and high Reynolds number flows. The results of comparative investigations with and without generation of inflow turbulence show that: (1) proper simulation of an inflow turbulent field is essential in accurate evaluation of dynamic wind loads on a tall building and the prescribed inflow turbulence characteristics can be adequately imposed on the inflow boundary by the DSRFG method; (2) the DSRFG can generate a large number of random vortex-like patterns in oncoming flow, leading to good agreements of both mean and dynamic forces with wind tunnel test results; (3) The dynamic mechanism of the adopted SGS model behaves adequately in the present LES and its integration with the DSRFG technique can provide satisfactory predictions of the wind effects on the super-tall building.

신문혈(神門穴) 레이저침 시술이 정신적 스트레스를 가한 성인의 심박변이도에 미치는 영향 (The Effect of Laser Acupuncture at $HT_7$(Sinmun) for Mental Stress on Short-term Analysis of Heart Rate Variability)

  • 장진영;조성연;김소정;김용석;남상수
    • Journal of Acupuncture Research
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    • 제27권5호
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    • pp.51-58
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    • 2010
  • Objectives : The purpose of this study is to assess the effect of laser acupuncture at $HT_7$ for reducing mental stress using power spectrum analysis of the heart rate variability. Methods : 36 healthy volunteers(control group: 18, treatment group: 18) participated in this study. After instrumentation and 5-minute rest period, 5-minute metal stress by operation was provided. HRV was recorded before and after the mental stress(1st, 2nd HRV). After 2nd HRV recording, the control group rested for 15 minutes without any treatments. Participants in the treatment group received laser acupuncture to $HT_7$ unilaterally and rested for 15minutes. Points were irradiated for 60seconds, and the intensity was 1.8J(output 20%). And then 3rd HRV was recorded. Results : In simple rest group, LF norm showed a significant change after mental stress. In laser acupuncture group, LF norm, HF norm, LF, HF and LF/HF ratio showed a significant change after mental stress. But there were no significant difference between two groups(ANCOVA test, p>0.05). In laser acupuncture group, LF norm, HF norm, HF and LF/HF ratio showed a significant change after laser acupuncture treatment. And there were significant differences between two groups(p<0.05). Conclusions : This study suggests that laser acupuncture at $HT_7$ can regulate and prevent the alternation of autonomic nervous system due to mental stress.

다지점 가진에 의한 단일형 현장타설말뚝 교량의 지진거동 (Seismic Behavior of a Bridge with Pile Bent Structures Subjected to Multi-Support Excitation)

  • 선창호;안성민;김익현
    • 한국전산구조공학회논문집
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    • 제32권6호
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    • pp.425-434
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    • 2019
  • 연약지반이 두껍고 다양한 지층으로 구성된 지역에 건설되는 단일형 현장타설말뚝 교량은 다양한 지층을 통해서 단일형 말뚝으로 입력되는 지반운동에 대해서 내진안전성을 확보하는 것이 중요하다. 본 연구에서는 설계지반운동에 부합되는 다수의 인공합성지진을 생성하여 이를 암반의 입력지반으로 하여 지반해석을 수행하여 각 지층에서의 지반가속도이력을 산정하였다. 이 가속도이력을 이용하여 각 지층의 지반을 등가스프링으로 모델화하고, 각 지층에서의 가속도시간이력을 입력지반운동으로 하는 다지점 가진 지진해석을 수행하였다. 연약층의 비선형거동특성으로 입력지반운동의 세기는 크게 증폭되지 않아서 교량은 탄성영역 내에서 거동하였다. 한편, 특정 지층에서 산정된 가속도이력을 모든 지반스프링에 동시에 입력하면 응답이 감소하였다. 따라서, 다지점가진 해석을 수행하지 않으면 이러한 형식의 교량의 내진성능을 과대평가할 수 있다.

Effect of Thermal Imidization and Curing on Fluorescence Behavior of a Phenylethynyl-Terminated Poly(amic acid)

  • Cho, Donghwan;Yang, Gyeongmo;Drzal, Lawrence T.
    • Macromolecular Research
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    • 제11권5호
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    • pp.297-302
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    • 2003
  • The imidization and cure reaction of a thermosetting phenylethynyl-terminated amic acid (LaRC PETI-5) in film form have been monitored as a function of temperature by means of a steady-state fluorescence technique using a front-face illumination method. The variation of the fluorescence emission spectra of LaRC PETI-5 can be divided into four temperature regions; Region I: below 15$0^{\circ}C$, Region II: 150-25$0^{\circ}C$, Region III: 250-35$0^{\circ}C$, and Region IV: above 35$0^{\circ}C$. The fluorescence spectra in Region I are largely influenced by residual N-methyl-2pyrrolidinone in the polymer and also slightly by partial imidization of the polymer. There is a combined effect of imidization and solvent removal on the fluorescence behavior in Region II. The spectra in Regions III and IV are due significantly to the cure reaction of LaRC PETI-5 and to a post-cure effect of the polyimide, respectively. This spectroscopic evidence indicating the transformation of the amic acid imide oligomer into the corresponding polyimide via imidization and cure, agrees well with thermal analysis results obtained previously. The intermediate stage of cure in the range of 250-30$0^{\circ}C$ predominantly influences the change of the fluorescence intensity. The later stage above 30$0^{\circ}C$ significantly influences the position of the spectrum. This fluorescence study also supports the mechanism proposed in earlier work that the crosslinking reaction takes place at the reaction sites in the conjugated polyene and the phenylethynyl end group in the polyimide chain.

Amino-carbonyl 반응에 의한 glucose-poly-${\gamma}$-glutamate (Glu-PGA) 갈변 반응물질의 항산화적 특성 연구 (Antioxidative Characteristics of Browning Reaction Products of Glucose-Poly-${\gamma}$-Glutamate (GIu-PGA) obtained from Amino-carbonyl Reaction)

  • 이남근;함영태
    • 한국식품과학회지
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    • 제37권5호
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    • pp.812-815
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    • 2005
  • 청국장 점질물인 PGA의 갈변 및 갈변 반응물질의 분획에 따른 갈변도와 전자 공여능에 따른 항산화력을 알아보았다. PGA의 갈변은 자체적으로는 갈변이 잘 일어나지 않고, 염기적 조건 하에서 glucose을 첨가하고 가열하면 갈변이 급격하게 일어나며 전자 공여능 또한 높게 나타났다. 염기적 조건 하에서 얻은 PGA 갈변 반응 물질(Glu-PGA, pH 8.2)을 Sephadex G-50을 이용하여 분획하고, 분획에 따른 갈변도 및 DPPH를 이용한 전자 공여능을 측정하였다. 분획된 갈변 반응 물질들은 비교적 광범위한 갈변도 및 전자 공여능을 보여 주었다. 이들 중 갈변도 및 전자 공여능이 상대적으로 높은 F-7과 F-20의 UV-VIS 흡수대에 있어서는 F-20은 멜라노이딘의 흡수대인 260-320nm에 걸쳐 완만한 흡수곡선을 나타내었고, F-7은 270nm 부근에서 특징적인 최대 흡수대를 나타내었다. 두 분획 물질의 분자량은 SDS-PAGE로 분석한 결과 F-7은 대략 35kDa 이상으로 나타났고, F-20은 SDS-PAGE상에서 뚜렷한 크기는 알 수 없었으나, F-7 보다는 비교적 저분자량을 갖는 물질이라는 것을 알 수 있었다.

아세틸화가 Glycinin의 구조에 미치는 영향 (Effect of Acetylation on Conformation of Glycinin)

  • 김강성;이준식
    • 한국식품과학회지
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    • 제21권5호
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    • pp.714-720
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    • 1989
  • 콩의 주요 저장 단백질인 glycinin의 라이신 잔기를 적당량의 acetic anhydride를 이용하여 28, 65, 85, 95%로 아세틸화시켰다. 아세틸화에 의한 구조적 변화를 solvent perturbant 방법으로 측정한 결과 자연상태의 단백질에 있어서는 타이로신 잔기의 약 40% 미만이 단백질 표면에 노출되어 있었으나 85% 아세틸화 glycinin에 있어서는 70% 이상이 표면에 노출되어 용매에 대해 접근이 용이하게 되었다. 이와 같은 현상은 second derivative spectroscopy에 의해 서로 동일하게 나타났으며, 따라서 아세틸화에 의해 타이로신과 같은 소수성 아미노산이 단백질 표면으로 이동하여 단백질 구조가 변형되었음을 알 수 있었다. 한편 near UV circular dichriosim의 결과 자연상태의 glycinin과 아세틸화가 일어난 glycinin 모두 유사한 모양의 spectra를 나타내었으나 95% 아세틸화 glycinin의 경우에는 tryptophan의 영향이 두드러졌다. Specific viscosity의 경우 아세틸화가 일어날수록 급격히 증가하였는데 이는 아세틸화에 의해 구형의 glycinin이 변형되어 분자의 부피가 커졌을 뿐 아니라 subunit의 분리에 의해 입자수가 증가했기 때문이다.

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아르곤/이산화탄소 혼합가스의 유도 결합 플라즈마를 이용한 이산화탄소 분해 연구 (Study on CO2 Decomposition using Ar/CO2 Inductively Coupled Plasma)

  • 김경현;김관용;이효창;정진욱
    • KEPCO Journal on Electric Power and Energy
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    • 제1권1호
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    • pp.135-140
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    • 2015
  • 유도 결합 플라즈마를 활용하여 $Ar/CO_2$ 혼합가스에서 이산화탄소를 분해하는 연구이다. 고밀도 플라즈마를 발생시키기 위해 Ar 가스를 첨가하였고 이산화탄소 분해율을 측정하기 위해 광학적 광량 측정법을 사용 하였다. 유도 결합 플라즈마를 방전시키고 인가 전력, 압력, 혼합가스 비율을 변경하가며 단일 랭뮤어 프로브를 이용해 플라즈마 변수를 얻고 방출 분광기로 얻은 빛의 스펙트럼을 이용하여 분해율을 측정하였다. 측정된 플라즈마 변수로부터 $CO_2$ 유도 결합 플라즈마의 소스 특성을 확인했고 $CO_2$ 분해 메커니즘은 플라즈마 변수에 직접적인 영향을 받기 때문에 그 상관관계를 분석하였다.

Hot Wall Epitaxy (HWE)에 의한 CdGa$_2$Se$_4$ 단결정 박막 성장과 광전기적 특성 (Growth and Optoelectric Characterization of CdGa$_2$Se$_4$ Sing1e Crystal Thin Films)

  • 홍광준;박창선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.167-170
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    • 2001
  • The stochiometric mix of evaporating materials for the CdGa$_2$Se$_4$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, CdGa$_2$Se$_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperature were 630$^{\circ}C$ and 420$^{\circ}C$, respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of CdGa$_2$Se$_4$ single crystal thin films measured from Hall erect by van der Pauw method are 8.27x10$\^$17/ cm$\^$-3/, 345 $\textrm{cm}^2$/V$.$s at 293 K, respectively. From the Photocurrent spectrum by illumination of perpendicular light on the c-axis of the CuInSe$_2$ single crystal thin film, we have found that the values of spin orbit splitting ΔSo and the crystal field splitting ΔCr were 106.5 meV and 418.9 meV at 10 K, respectively. From the photoluminescence measurement on CdGa$_2$Se$_4$ single crystal thin film, we observed free excition (E$\_$X/) existing only high quality crystal and neutral bound exiciton (D$\^$0/,X) having very strong peak intensity. Then, the full-width-at-half-maximum(FWHM) and binding energy of neutral donor bound excision were 8 meV and 13.7 meV, respectivity. By Haynes rule, an activation energy of impurity was 137 meV,

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