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Effect of Target Material and the Neutron Spectrum on Nuclear Transmutation of 99Tc and 129I in Nuclear Reactors (표적물질 및 중성자 스펙트럼이 99Tc과 129I의 원자로 내부 핵변환에 미치는 영향)

  • Kang, Seung-gu;Lee, Hyun-chul
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.195-202
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    • 2018
  • As a rule, geological disposal is considered a safe method for final disposal of high-level radioactive waste. However, some long-lived fission products like $^{99}Tc$ and $^{129}I$ contained in spent nuclear fuel are highly mobile as less sorbing anionic species in the subsurface environment and can mainly cause exposure dose to the ecosystem by emission of beta rays in the hundreds of keV range. Therefore, if these two nuclides can be separated and converted with high efficiency into radioactively unharmful nuclides, this would have a positive effect on disposal safety. One candidate method is to transmute these two nuclides in nuclear reactors into short-lived nuclides or into stable nuclides. For this purpose, it is necessary to evaluate which reactor type is more efficient in burning these two nuclides. In this study, the simulation results of nuclear transmutation of $^{99}Tc$ and $^{129}I$ in light water reactor (PWR), heavy water reactor (CANDU) and fast neutron reactor (SFR, MET-1000) are compared and discussed.

The electrical and optical properties of the Ga-doped ZnO thin films grown on transparent sapphire substrate (투명 사파이어 기판위에 성장시킨 Ga-doped ZnO 박막의 전기적·광학적 특성)

  • Chung, Yeun Gun;Joung, Yang Hee;Kang, Seong Jun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.5
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    • pp.1213-1218
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    • 2013
  • In this study, Ga-doped ZnO (GZO) thin films were fabricated on transparent sapphire substrate by RF magnetron sputtering method and then investigated the effect of various substrate temperature on the electrical, optical properties and characteristic of crystallization of the GZO thin films. The electrical property indicated that the lowest resistivity ($4.18{\times}10^{-4}{\Omega}cm$), the highest carrier concentration ($6.77{\times}10^{20}cm^{-3}$) and Hall mobility ($22cm^2/Vs$) were obtained in the GZO thin film fabricated at $300^{\circ}C$. And for this condition, the highest c-axis orientation and (002) diffraction peak which exhibits a FWHM of $0.34^{\circ}$ were obtained. From the results of AFM measurements, it is known that the highest crystallinity is observed at $300^{\circ}C$. The transmittance spectrum in the visible range was approximately 80 % regardless of substrate temperature. The optical band-gap showed the blue-shift as increasing the substrate temperature to $300^{\circ}C$, and they are all larger than the band gap of bulk ZnO (3.3 eV). It can be explained by the Burstein-Moss effect.

Fundamental Cultural Characteristics of Chlorociboria spp. Native to Korea (한국에 자생하는 녹청균류의 기초 배양 특성)

  • Jeon, Sung-Min;Ka, Kang-Hyeon;Wang, Eun-Jin;Ryoo, Rhim;Jang, Yeongseon
    • The Korean Journal of Mycology
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    • v.46 no.2
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    • pp.145-160
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    • 2018
  • Members of Chlorociboria are soft-rot ascomycetes that produce blue-green pigment. We investigated the growth characteristics of two Korean species of Chlorociboria, eight strains of Chlorociboria aeruginascens and Chlorociboria poutoensis, under various culture conditions (solid media, temperature, pH) and screened them for extracellular enzyme activity. Although the growth rate was slow, all tested strains of Chlorociboria spp. grew well on potato dextrose agar (PDA; 16.3~42.6 mm after 60 days) or Sabouraud dextrose agar (SDA), but not on malt extract agar (MEA). Compared with C. aeruginascens strains, C. poutoensis strains exhibited higher expression of blue-green pigments on both PDA and SDA media. The optimal temperature for mycelial growth was $20{\sim}25^{\circ}C$, and mycelial growth was lower at $30^{\circ}C$ than at $10^{\circ}C$. All strains tended to have increased mycelial growth as the incubation temperature increased in the range of 10 to $20^{\circ}C$. The optimal pH of potato dextrose broth (PDB) for mycelial growth varied according to the strain under static culture conditions. Maximum biomass production was obtained at pH 6.0 for NIFoS 579 ($114.3{\pm}5.1mg/60days$), but it maintained a stable pigment expression under a broad pH spectrum. The activities of both cellulase and laccase were observed in all tested strains of Chlorociboria spp. Enzyme activities of NIFoS 579 were remarkably higher than those of the other strains. From these results, we suggest that C. poutoensis NIFoS 579 is a potential candidate for use as a source of natural blue-green dye.

Physicochemical Characteristics of Silk Fibroin Degummed by Protease in Bacillus licheniformis II. Behavior in Aqueous Solution of Silk fibroin (Bacillus licheniformis 단백질 분해 효소에 의한 정련 견사의 특성 III. 견 피브로인 수용액의 거동)

  • 김영대;남중희
    • Journal of Sericultural and Entomological Science
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    • v.35 no.1
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    • pp.60-68
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    • 1993
  • It has been known that the silk degumming treated by hot alkali solution is easy to handle but is liable to yield poor-quality silk due to the degree of degumming loss, incomplete-degumming or over-degumming. Therefore, many studies have been carried out on the silk degumming by enzyme in order to improve the quality of silk. However, no attention has been paid to the physicochemical analysis of enzymatic degummed silk. In this paper, two different degumming methods, soap and enzymatic, are compared in aqueous solution state of silk fibroin. The results can be summarized as follows: There was no significant difference between two solutions on the bases of polarizing microscopy, TEM observation and SDS-PAGE. Spherulite of silk fibroin was not observed in polarizing microscopy, however the leaf-shape fibril structure was developed upon solidification. The size of spherulites of silk fibroin in TEM observation were 30~120nm with a wide range of size distribution. The intrinsic viscosity of enzymatic degummed fibroin solution was lower than that of soap degummed solution. This can be explained that the silk fibroin was more degraded by enzymatic degumming method compared with the soap degumming method. SDS-polyacrylamide gel electrophoresis showed that the fibroin molecule was composed of large component of molecule weight above 50 kd and small component of molecule weight about 20 kd. There was no difference in crystallinity between two degumming methods on the bases of results of DSC thermograms and IR spectra.

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Development of Non-Destructive Sorting Technique for Viability of Watermelon Seed by Using Hyperspectral Image Processing (초분광 영상기술을 이용한 수박종자 발아여부 비파괴 선별기술 개발)

  • Bae, Hyungjin;Seo, Young-Wook;Kim, Dae-Yong;Lohumi, Santosh;Park, Eunsoo;Cho, Byoung-Kwan
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.1
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    • pp.35-44
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    • 2016
  • Seed viability is one of the most important parameters that is directly related with seed germination performance and seedling emergence. In this study, a hyperspectral imaging (HSI) system having a range of 1000-2500 nm was used to classify viable watermelon seeds from nonviable seeds. In order to obtain nonviable watermelon seeds, a total of 96 seeds were artificially aged by immersing the seeds in hot water ($25^{\circ}C$) for 15 days. Further, hyperspectral images for 192 seeds (96 normal and 96 aged) were acquired using the developed HSI system. A germination test was performed for all the 192 seeds in order to confirm their viability. Spectral data from the hyperspectral images of the seeds were extracted by selecting pixels from the region of interest. Each seed spectrum was averaged and preprocessed to develop a classification model of partial least square discriminant analysis (PLS-DA). The developed PLS-DA model showed a classification accuracy of 94.7% for the calibration set, and 84.2% for the validation set. The results demonstrate that the proposed technique can classify viable and nonviable watermelon seeds with a reasonable accuracy, and can be further converted into an online sorting system for rapid and nondestructive classification of watermelon seeds with regard to viability.

K+ Ion-Selective PVC Membrane Electrodes with Neutral Carriers (중성운반체를 이용한 K+ 이온선택성 PVC막 전극)

  • Kim, Yong-Ryul;Cho, Kyoung-Sub;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.734-741
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    • 1998
  • Electrode characteristics were studied in the interface between sample solutions and $K^+$ ion selective PVC membrane electrodes containing neutral carriers, dibenzo-18-crown-6(D18Cr6) and valinomycin(Val). The effect of doping of base electrolytes, the chemical structure and the content of carrier, variation of plasticizer, membrane thickness, and concentration variation of sample solution on the response characteristics of electrode such as the measured Nernstian slope, the detection limit, the linear response range, and potentiometric selectivity coefficients, were studied. In order to synthesize the membrane D18Cr6 and Val as neutral carriers were used, and complex between the carrier and $K^+$ ions were used as active materials. PVC membrane electrodes were made of plasticizers (DBP, DOS, and DBS), the base electrolyte[potassium tetraphenylborate(KTPB)], and solvent(THF). The chemical structure of carrier D18Cr6 was best for electrode and ideal electrode characteristics were appeared especially in case of doping of TPB. The optimum carrier content was about 3.23 wt % in case of D18Cr6 and Val. DBP was best as a plasticizer. As membrane thickness decreased the electrode characteristics was improved. But its characteristics were lowered below the optimum membrane thickness because of the elution of carrier, deterioration of membrane strength, etc. In the case of D18Cr6, the selectivity coefficients by the mixed solution method for the $K^+$ ion were in the order of $NH_4{^+}>Ca^{2+}>Mg^{2+}>Na^+$.

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Quantitative Analysis of Acid Value, Iodine Value and Fatty Acids Content in Sesame Oils by NIRS (근적외선분광광도법을 이용한 참기름의 산가, 요오드가, 지방산정량법에 관한 연구)

  • Kim, Jae-Kwan;Lee, Myung-Jin;Kim, Myung-Gill;Kim, Kyung-A;Park, Eun-Mi;Kim, Young-Sug;Ko, Hoan-Uck;Son, Jin-Seok
    • Journal of Food Hygiene and Safety
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    • v.21 no.4
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    • pp.204-212
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    • 2006
  • This study was conducted to investigate the possibility of rapid and non-des tructive evalution of AV (Acid Value), IV (Iodine Value) and fatty acids in sesame oils. The samples were scanned over the range $400\sim2500nm$ using transmittance spectrum of NIRS(Near-infrared spectroscopy). A calibration equation calculated by MPLS regression technique was developed and correlation coefficient of determination for AV, IV, palmitic acid, stearic acid, linoleic acid and linolenic acid content were 0.9907, 0.9677, 0.9527, 0.9210, 0.9829, 0.9736 and 0.9709 respectively. The validation model for measuring the AV content had R of 0.989, SEP of 0.058 and IV content had R of 0.944, SEP of 0.562 and palmitic acid content had R of 0.924, SEP of 0.194 and stearic acid content had R of 0.717, SEP of 0.168 and oleic acid content had R of 0.989, SEP of 0.221 and linoleic acid content had R of 0.967, SEP of 0.297 and linolenic acid content had R of 0.853, SEP of 0.480 by MPLS. The obtained results indicate that the NIRS procedure can potentially be used as a non-destructive analysis method for the purpose of rapid and simple measurement of AV, IV and fatty acids in sesame oils.

Analysis of Volatile Compounds in Kimchi-Flavored Steak Sauce (김치를 이용한 스테이크소스의 휘발성 향기성분)

  • Cho, Yong-Bum;Park, Woo-Po;Jung, Eun-Joo;Lee, Mi-Jeong;Lee, Yang-Bong
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.351-355
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    • 2002
  • Volatile compounds of kimchi-flavored steak sauce were isolated using simultaneous steam distillation and solvent extraction methods and identified by matching mass spectrum and retention index (RI) with the reference data. Twenty-three compounds including five aldehydes, four alcohols, four acids, three sulfur-containing compounds, one ketone, and six others were identified, among which the most abundant compound was eugenol. Sulfides such as dimethyl dis- and trisulfides, and acids such as acetic and dodecanoic acids showed strong effects on the kimchi flavor. Aroma extract dilution analysis with three fold dilution factor shown in over the FD value 34 identified 2-butanal, 2-pentylfuran, methyl-2-propenyl disulfide, and 2-furanmethanol. Strong good aroma was detected in the RI range between 1030 and 1357, bad aroma in RI 1561, sweety aroma in RI 2057, clover aroma of eugenol in RI 2122, and rancid flavor in RI 2251.

Automatic Selection of Optimal Parameter for Baseline Correction using Asymmetrically Reweighted Penalized Least Squares (Asymmetrically Reweighted Penalized Least Squares을 이용한 기준선 보정에서 최적 매개변수 자동 선택 방법)

  • Park, Aaron;Baek, Sung-June;Park, Jun-Qyu;Seo, Yu-Gyung;Won, Yonggwan
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.3
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    • pp.124-131
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    • 2016
  • Baseline correction is very important due to influence on performance of spectral analysis in application of spectroscopy. Baseline is often estimated by parameter selection using visual inspection on analyte spectrum. It is a highly subjective procedure and can be tedious work especially with a large number of data. For these reasons, it is an objective and automatic procedure is necessary to select optimal parameter value for baseline correction. Asymmetrically reweighted penalized least squares (arPLS) based on penalized least squares was proposed for baseline correction in our previous study. The method uses a new weighting scheme based on the generalized logistic function. In this study, we present an automatic selection of optimal parameter for baseline correction using arPLS. The method computes fitness and smoothness values of fitted baseline within available range of parameters and then selects optimal parameter when the sum of normalized fitness and smoothness gets minimum. According to the experimental results using simulated data with varying baselines, sloping, curved and doubly curved baseline, and real Raman spectra, we confirmed that the proposed method can be effectively applied to optimal parameter selection for baseline correction using arPLS.

A Frequency-Sharing Method to Use Frequency Resources Efficiently (효율적인 주파수 이용을 위한 주파수 공유 방법)

  • Kang, Sang-Gee;Hwang, Taek-Jin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.8
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    • pp.1349-1355
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    • 2008
  • Recently many short-range transceiver systems, such as ZigBee, Bluetooth and RFID(Radio Frequency Identification), have been developed. These systems are mostly low-power transceivers. In the near future many more low-power transceivers are appeared for WPAN(Wireless Personal Area Network) and interference mitigation technologies are necessary to the low-power transceivers for using frequency resources efficiently. In this paper we consider two methods for sharing frequency resources. The first case is that a frequency band previously assigned fer a certain system is shared and the second case is that the white frequency band is shared. We study the method and conditions for sharing frequency resources in the above two cases. When a frequency band is shared with ZigBee, RFID, DCP (Digital Cordless Phone) and Bluetooth as an example for the first case, the sharing conditions are investigated and the results are presented. We propose a balancing factor to maintain an equal transmitting conditions between systems having a different interference mitigation technique. In the interference simulation we use FH(Frequency Hopping) as a reference system and 0.9 of a balancing factor for LBT(Listen Before Talk) and 0.8 for DS(Direct Spreading). From the simulation results we know that a balancing factor reduces interference probability therefore many more systems can be operated in the same frequency bands compared with the case without using a balancing factor.