• Rapid Communication in Photoscience
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• v.4 no.2
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• pp.34-36
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• 2015

New spectroscopic characteristics of amorphous ferric hydroxide ($Fe(OH)_3$), interestingly in the near infrared (NIR) region, are presented in this study. The absorption spectrum of ferric hydroxide covers wide spectral regions from ultraviolet to NIR (200~900 nm). Unique emission bands were newly observed in the NIR regions (800~1400 nm). Several bands of this NIR emission are quiet well overlapped with the combinational vibrational absorption bands of water. From photothermal conversion study, very interestingly, temperature of aqueous mixture solution including the amorphous ferric hydroxide was significantly increased from ambient temperature to $38^{\circ}C$ for 30 minutes under irradiation of a standard helium lamp.

• Aerospace Engineering and Technology
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• v.6 no.1
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• pp.213-221
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• 2007

This paper showed how to analysis the object-based classification for wildfire fuel type map using Hyperion hyperspectral remote sensing data acquired in April, 2002 and compared the results of the object-based classification with the results of the pixel-based classification. Our methodological approach for wildfire fuel type map firstly processed correcting abnormal pixels and atypical bands and also calibrating atmospheric noise for enhanced image quality. Fuel type map is characterized by the results of the spectral mixture analysis(SMA). Object-based approach was based on segment-based endmember selection, while pixel-based method used standard SMA. To validate and compare, we used true-color high resolution orthoimagery.

• The Journal of the Acoustical Society of Korea
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• v.26 no.6
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• pp.259-268
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• 2007

This paper contributes to an improvement of the statistical bandwidth extension(BWE) system based on Hidden Markov Model(HMM). First, the existing HMM training method for BWE, which is suggested originally by Jax, is analyzed in comparison with the general Baum-Welch training method. Next, based on this analysis, a new HMM-based BWE method is suggested which adopts the Baum-Welch re-estimation algorithm instead of the Jax's to train HMM model. Conclusionally speaking, the Baum-Welch re-estimation algorithm is a generalized form of the Jax's training method. It is flexible and adaptive in modeling the statistical characteristic of training data. Therefore, it generates a better model to the training data, which results in an enhanced BWE system. According to experimental results, the new method performs much better than the Jax's BWE systemin all cases. Under the given test conditions, the RMS log spectral distortion(LSD) scores were improved ranged from 0.31dB to 0.8dB, and 0.52dB in average.

• Structural Engineering and Mechanics
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• v.63 no.6
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• pp.809-824
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• 2017

The accurate evaluation of wind characteristics and wind-induced structural responses during a typhoon is of significant importance for bridge design and safety assessment. This paper presents an expectation maximization (EM) algorithm-based angular-linear approach for probabilistic modeling of field-measured wind characteristics. The proposed method has been applied to model the wind speed and direction data during typhoons recorded by the structural health monitoring (SHM) system instrumented on the arch Jiubao Bridge located in Hangzhou, China. In the summer of 2015, three typhoons, i.e., Typhoon Chan-hom, Typhoon Soudelor and Typhoon Goni, made landfall in the east of China and then struck the Jiubao Bridge. By analyzing the wind monitoring data such as the wind speed and direction measured by three anemometers during typhoons, the wind characteristics during typhoons are derived, including the average wind speed and direction, turbulence intensity, gust factor, turbulence integral scale, and power spectral density (PSD). An EM algorithm-based angular-linear modeling approach is proposed for modeling the joint distribution of the wind speed and direction. For the marginal distribution of the wind speed, the finite mixture of two-parameter Weibull distribution is employed, and the finite mixture of von Mises distribution is used to represent the wind direction. The parameters of each distribution model are estimated by use of the EM algorithm, and the optimal model is determined by the values of $R^2$ statistic and the Akaike's information criterion (AIC). The results indicate that the stochastic properties of the wind field around the bridge site during typhoons are effectively characterized by the proposed EM algorithm-based angular-linear modeling approach. The formulated joint distribution of the wind speed and direction can serve as a solid foundation for the purpose of accurately evaluating the typhoon-induced fatigue damage of long-span bridges.

• Korean Journal of Remote Sensing
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• v.30 no.3
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• pp.399-415
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• 2014

The intensity of stormwater runoff is particularly acute across cities located in arid climates. During flash floods loose sediment and pollutants are typically transported across sun-hardened surfaces contributing to widespread degradation of water quality. Rapid, dense urbanization exacerbates the problem by creating continuous areas of impervious surfaces, perforated only by a few green patches. Our work demonstrates how the latest techniques in remote sensing can be used to routinely measure urban land cover types, impervious cover, and vegetated areas. In addition, multiple regression models can then infer relationships between urban land use and land cover types with stormwater quality data, initially sampled at discrete monitoring sites, and then extrapolated annually across an arid city; in our case, the city of Phoenix in Arizona, USA. Results reveal that from 30 storm event samples, solids and heavy metal pollutants were found to be highly related with general impervious surfaces; in particular, with industrial and commercial land use types. Repercussions stemming from this work include support for public policies that advocate environmental sustainability and the more recent focus on urban livability. Also, advocacy for new urban construction and re-development that both steer away from vast unbroken impervious surfaces, in place of more fragmented landscapes that harmonize built and green spaces.

• Korean Journal of Materials Research
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• v.4 no.4
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• pp.472-476
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• 1994

Phase transformation of PbO-precursor prepared from $Pb(NO_{3})_{2}$ by precipitation technique was observed by TG-DTA, XRD, FT-IR, and Raman spectral analysis. PbO-precursor was derived from an aqueous solution of $Pb(NO_{3})_{2}$ at $45^{\circ}C$ and pH of 9.0. The precipitate showed it to be the mixture of hydrous lead oxynitrate and lead hydroxynitrate. With increasing heat-treatment temperature ranging up to $560^{\circ}C$, the precursor changed to $3Pb(NO_{3})_{2}$ . 7Pb0, $Pb(NO_{3})_{2}$. 5Pb0 and PbO(litharge), in turn. Finally, it transformed to massicot form of PbO above $560^{\circ}C$.

• Journal of Electrochemical Science and Technology
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• v.8 no.3
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• pp.222-235
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• 2017

First, in this study, the inhibition efficiencies of metal complexes with Cu(II), Ni(II) and Zn(II) of STSC ligand for corrosion control of mild steel in oilfield formation water were investigated. The IEs for a mixture of 500 ppm STSC and 5 ppm metal ion ($Cu^{+2}$, $Ni^{+2}$, $Zn^{+2}$) were found to be 88.77, 87.96 and 85.13 %, respectively. The results were obtained from the electrochemical techniques such as open circuit potential, linear and tafel polarization methods. The polarization studies have showed that all used Schiff base metal complexes are anodic inhibitors. The protective film has been analyzed by FTIR technique. Also, to detect the presence of the iron-inhibitor complex, UV-Visible spectral analysis technique was used. The inhibitive effect was attributed to the formation of insoluble complex adsorbed on the mild steel surface and the adsorption process follows Langmuir adsorption isotherm. The surface morphology has been analyzed by SEM. Secondly, the computational studies of the ligand and its metal complexes were performed using DFT (B3LYP) method with the $6-311G^{{\ast}{\ast}}$ basis set. Finally, it is found that the experimental results were closely related to theoretical ones.

• Corrosion Science and Technology
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• v.22 no.5
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• pp.314-321
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• 2023

The aim of the present study was to investigate the effect of thymus extract on corrosion inhibition of aluminum 5083 alloy in a 0.1 M NaCl medium prepared using a mixture of ethylene glycol and water using potentiodynamic and electrochemical impedance spectroscopy (EIS) techniques. The potentiodynamic electrochemical technique showed an increase in corrosion inhibition efficiency starting from 49.63% at a concentration of 0.25 g/L to 92.71% at a maximum concentration of 1.25 g/L of the extract. These results were consistent with those obtained via EIS analysis. Spectral characterization of the tested plant extract using the Fourier-transform infrared spectroscopy (FTIR) technique confirmed the presence of organic compounds having different oxygen and aromatic functionalities in the extract that could help enhance the adsorption of these compounds on the aluminum surface. This study reveals possible adsorption isotherm of the thymus extract on the aluminum surface, supporting a Langmuir isotherm for the adsorption of inhibitor molecules on this surface.

• Korean Journal of Remote Sensing
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• v.29 no.2
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• pp.161-172
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• 2013

The construction of hyperspectral test-bed dataset is essential for the effective performance of hyperspectral image for various applications. In this study, we analyzed the technical points for generating of optimal hyperspectral test-bed site for hyperspectral sensors and the efficiency of hyperspectral test-bed site. In this regard regions we analyzed existing construction techniques for generating test-bed site in domestic and foreign, and designed the test-bed site to acquire images from the airborne hyperspectral sensor. To produce a reference data from the image of constructed test-bed site, this study applied vicarious correction as a pre-processing and analyzed its efficiency. The result presented that it was ideal to use tarp for the vicarious correction, but it is possible to use the materials with constant spectral reflectance or with relatively low variance of spectral reflectance. The test-bed data taken in this study can be employed as the reference of domestic and foreign studies for hyperspectral image processing.

• Analytical Science and Technology
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• v.30 no.6
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• pp.348-354
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• 2017

In this study, patterns of proteome expression were monitored and specifically expressed proteins in human milk were detected in collected human milk after 1 week, 3 weeks, and 6 weeks from delivery. A quantitative shotgun proteomic approach was used to identify human milk proteins and reveal their relative expression amounts. For each sample, two independent human milk samples from two mothers were pooled, and then three replicated shotgun proteomic analyses were carried out. Casein, which is a highly abundant protein in human milk, was removed, and then trypsin was treated to produce a digested peptide mixture. The peptides were loaded in the home-made reversed-phase C18 fused-silica capillary column, and then the eluted peptides were analyzed by using a linear ion-trap mass spectrometer. The relative quantitation of proteins was performed by the normalized spectral count method. For each sample, 81-109 non-redundant proteins were identified. The identified proteins consisted of glycoproteins, metabolic enzyme, and chaperon enzymes such as lactoferrin, carboxylic ester hydrolase, and clusterin. The comparative analysis for the 63 proteins, which were reproducibly identified in all three replications, revealed that 25 proteins were statically significant differentially expressed. Among the differentially expressed proteins, Ig lambda-7 chain C region and tenascin drastically decreased with the delivery time.