• 제목/요약/키워드: Specific capacity

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오존수 산화를 이용한 활성탄 흡착탑의 현장 재생 시 흡착용량 및 구조특성의 변화 (Changes of Adsorption Capacity and Structural Properties during in situ Regeneration of Activated Carbon Bed Using Ozonated Water)

  • 이진주;이기세
    • 공업화학
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    • 제31권3호
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    • pp.341-345
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    • 2020
  • 하폐수처리 및 정수처리에 사용되는 활성탄 흡착 공정에서 기존의 활성탄 열재생법 비해 활성탄 손실과 불완전 연소로 인한 오염물질 발생도 적으며, 사용 활성탄의 인발-재생-재충진에 소요되는 시간의 절약이 가능한 재생 방법으로 오존수를 이용한 in situ regeneration에 대한 기초연구를 수행하였다. 활성탄 흡착 컬럼 상에서 페놀(phenol) 및 PEG를 흡착 파과 시킨 후 오존수 접촉으로 흡착물질을 분해 제거하는 흡착-재생 싸이클을 반복하였다. 오존수 접촉에 의한 재생 횟수가 증가할수록 페놀 흡착용량은 어느 정도 감소하지만, 일정 수준으로의 감소 후에는 구조 변화가 안정화되어 추가적인 감소가 일어나지 않았다. 흡착 용량이 감소하는 이유는 오존과의 반응에 의해 활성탄의 미세공 크기가 증가하면서 비표면적이 감소하기 때문으로 나타났다. 이러한 세공 크기의 변화와 비표면적의 변화로 인하여 재생 후 in-pore adsorption이 우세한 페놀과 같은 저분자량 물질의 흡착효율은 감소하게 되나 external adsorption 비율이 큰 PEG와 같은 고분자량 물질의 흡착효율은 크게 영향을 받지 않았다. 세공 크기 및 비표면적의 변화는 오존수와의 접촉시간이 길어질수록 심화되므로 제거하려는 물질의 크기를 고려하고 접촉시간을 조절함으로써 흡착 효율의 유지를 제어하는 것이 필요하다.

Fe-26Mn-4Co-2Al 제진합금의 감쇠능에 미치는 결정립 크기의 영향 (Effect of Grain Size on the Damping Capacity of Fe-26Mn-4Co-2Al Damping Alloy)

  • 정규성;김도훈;권순두;강창룡
    • 한국재료학회지
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    • 제28권3호
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    • pp.129-134
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    • 2018
  • This study was carried out to investigate the effect of grain size on the damping capacity of the Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ were formed by cold working, and these martensites were formed with a specific direction and surface relief. With an increase in grain size, the volume fraction of ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ increased by decrement the austenite phase stability. This volume fraction more rapidly increased in cold-rolled specimen than in the specimen that was not cold-rolled. The damping capacity also increased more with the augmentation an increased grain size and more rapidly increased in cold-rolled specimen than in the specimen that was not cold rolled. The effect of grain size on the damping capacity was larger in the cold-rolled specimen than the specimen that was not cold-rolled. Damping capacity linearly increased with an increase in volume fraction of ${\varepsilon}-martensite$. Thus, the damping capacity was affected by the ${\varepsilon}-martensite$.

합판 벽체의 단열성능 (Adiabatic property of plywood wall panel)

  • 박준철;홍순일
    • 임산에너지
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    • 제21권2호
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    • pp.62-68
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    • 2002
  • 본 실험에서는 합판벽체내의 단열재 종류에 따른 단열성능을 비교 평가하였다. 열의 통과량을 비교해 보기 위하여 열관류 실험을 하였다. 열관류 실험결과 스티로폼과 유리섬유의 열관류율이 적게 나타났다. 용적비열은 황토보드와 집성목이 높은 결과를 나타내었다. 합판 벽체로 제작된 모형 주택을 이용한 실내외 온도변화를 비교해 본 결과 단열재료로스티로폼과 유리섬유를 사용한 벽체의 경우 외부 온도에 쉽게 영향을 받는 것을 알 수 있었으며 용적비열이 높은 황토보드, 황토ㆍ톱밥 혼합재, 집성목을 사용한 벽체의 경우는 외부온도의 변화에 비해 적은 온도변화를 보였다. 실험결과 열관류율은 스티로폼과 유리섬유가 작았지만 용적비열이 높은 황토보드와 황토ㆍ톱밥 혼합재, 집성목이 단열성능면에서 우수함을나타내었다.

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활성탄의 물리적 특성과 표면 특성에 따른 수중의 methylene blue의 흡착특성 (Adsorption Characteristics of Methylene Blue from Aqueous Solution According to Physical and Surface Properties of Activated Carbons)

  • 감상규;유해나;이민규
    • 한국환경과학회지
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    • 제23권11호
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    • pp.1821-1826
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    • 2014
  • The adsorption characteristics of the methylene blue (MB) were studied using three activated carbons such as ACA and ACB with similar specific surface area (1,185 and $1,105m^2/g$), and ACC with relatively high specific surface area ($1,760m^2/g$). The surface chemical properties of these activated carbons were investigated by X-ray photoelectron spectroscopy (XPS). The results indicated that ACA had more functional groups (with phenol, carbonyl, and carboxyl etc.) than ACB (with carbonyl and carboxyl) and ACC (with carboxyl). The isotherm data were fitted well by Langmuir isotherm model. The adsorption capacities of ACA, ACB, and ACC for MB were 454.7 mg/g, 337.7 mg/g, and 414.0 mg/g, respectively. As phenol and carboxyl content of the surface on activated carbon increased, MB adsorption capacity was increased. Although ACA had a smaller specific surface area than ACC, the content of phenol and carboxyl group was abundant, so MB adsorption capacity was found to be higher than ACC.

전구체로서 PVDF를 이용한 탄소 도포 실리콘 재료의 개발 및 리튬이차전지 음극 특성 (Development of Silicone coated by Carbon driven PVDF and its anode characteristics for Lithium Battery)

  • 도칠훈;정기영;진봉수;김현수;문성인;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.350-351
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    • 2005
  • The electrochemical behavior of Si-C material synthesized by heating the mixture of silicon and polyvinylidene fluoride (PVDF). Coin cells of the type 2025 were made using the synthesized material and the electrochemical studies were performed. Si-C/Li cells were made by using the developed Si-C material. Charge/discharge test was performed at 0.1C hour rate. Initial charge and discharge capacities at Si-C material derived from 20 wt.% of PVDF was found to be 1,830 and 526 mAh/g respectively. Initial charge/discharge characteristics of the electrode were analyzed. The level of reversible specific capacity was about 216 mAh/g at Si-C material derived from 20 wt.% of PVDF, IIE, intercalation efficiency at initial charge/discharge, was 68 %. Surface irreversible specific capacity was 31 mAh/g, and average specific resistance was 2.6 ohm*g.

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Triacetin이 탄소복합 필터의 연기성분 흡착능에 미치는 영향

  • 김정열;신창호;김종열
    • 한국연초학회지
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    • 제20권2호
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    • pp.205-209
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    • 1998
  • This study was conducted to evaluate the effect of triacetin(TA) treatment during manufacturing carbon dual filter for the adsorption of cigarette smoke components by activated carbons. The measurements were carried out by separation of activated carbon from carbon dual filter, and the specific surface area analyzed. The specific surface area of activated carbon from the domestic cigarette filter and from the foreign cigarette filter by degassing at 9$0^{\circ}C$ was 163$\pm$32$m^2$/g, and 16.6$\pm$1.9$m^2$/g, respectively. Those values were very lower than that of degassing at 35$0^{\circ}C$ (Domestic brand: 952$\pm$30$m^2$/g, and Foreign brand: 847$\pm$73$m^2$/g). By comparing the adsorption capacity of acetone and benzene with and without triacetin treated activated carbon, there was a 20% reduction of adsorption capacity by 5% triacetin treatment. Also, from the cilia toxicity test with carbon dual filter treated 0 % TA and 8 % TA, the cilia survival time was 706$\pm$74sec. and 603$\pm$64sec. for 0% TA and 8% TA, respectively. The delivery rate of vapour phase of cigarette smoke, which consists of main components of cilia toxicity, was higher at 8% TA filter than 0 % TA filter. Our results indicate that the treated TA covered the micro-pore of activated carbon, and then reduced specific surface area, finally, decreased the adsorption of vapour phase from cigarette smoke.

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로우터리 경운(耕耘)의 부하특성(負荷特性) 및 소요동력(所要動力)에 관(関)한 연구(硏究) (Tilling Load Characteristics and Power Requirement for Rotary Tillers)

  • 최규홍;류관희
    • Journal of Biosystems Engineering
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    • 제9권2호
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    • pp.27-36
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    • 1984
  • This study was carried out to investigate the effects of the tilling depth, tilling travel speed and soil shear stress on the tilling load characteristics and power requirement for rotary tillers. The results obtained from the study are summarized as follows. 1. The average and maximum PTO torque increased as the tilling depth, tilling pitch and soil shear stress increased. A multiple linear regression equation to estimate the average PTO torque in terms of the above parameters was developed. 2. The ratios of maximum PTO torque to the average torque were in the range of 1.17 to 1.65 for the various tilling conditions tested. The variation in PTO torque increased greatly as the tilling pitch and soil shear stress increased, but decreased as the tilling depth increased. 3. Power requirement for the PTO shaft increased with the tilling depth, travel speed and soil shear stress, but decreased slightly as the tilling pitch increased. A multiple linear regression equation to estimate power requirement for the PTO shaft in terms of the above parameters was developed. 4. The specific power requirement for the rotary tiller was in the range of $0.008-0.015ps/cm^2$ for the various tilling conditons tested. The specific tilling capacity decreased as the tilling depth and soil shear stress increased, but increased with the tilling pitch. A multiple linear regression equation to estimate the specific tilling capacity in terms of the above parameters was developed.

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극저비속도 영역에서 임펠러 관련인자 변화에 따른 원심펌프 성능 평가 (Performance Evaluation on Impeller Related Parameters Change in Centrifugal Pump of very Low Specific Speed)

  • 정영대;이계복
    • 한국유체기계학회 논문집
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    • 제14권1호
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    • pp.11-17
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    • 2011
  • The numerical study was conducted to investigate the pump performance due to impeller related parameters change in centrifugal pump of very low specific speed by using CFD code. A small centrifugal pump whose specific speed is $N_s=76.2$ was used, and the performance characteristics were discussed for different number of vanes, rotational speed, and the length and height of vane. The numerical results at a very low specific speed show that the increase of the number of vanes has little effect on improvement of output pressure but results in the reduction of pressure fluctuation, and that the head increases with the increase in the rotational speed. The decreasing the length of vane has a considerable reduction of the capacity coefficient in comparison with decreasing the height of vane.

풍력발전기의 설비이용률 계산을 위한 확률밀도함수의 비교 (Comparison of Probability Density Functions for Caculation of Capacity Factors of Wind Turbine Generator)

  • 강택근;허종철;좌종근
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 B
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    • pp.1338-1341
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    • 2002
  • The Weibull probability density function and the Rayleigh function are compared by analyzing the relations of the capacity factors which are compared the actual wind speed frequency curve with which are modelled using the probability density functions with different mean wind speeds. For this analysis, the wind speed means of arithmetic, root mean square, cubic mean cuberoot, and standard deviations are computed from the measured wind speed data of a specific site and the coefficients of probability density functions are calculated. The capacity factors for Vestas 850[kW] wind turbine are calculated and analyzed. The results shows that the wind speed frequency curve by Rayleigh function is more close to the actual curve than by Weibull function. The more the wind speed frequency curve is close to the actual one, the more the capacity factors become large values.

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