• Carbon letters
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• 제1권3_4호
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• pp.148-153
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• 2001

The initial irreversible capacity, $Q_i$, is one of the parameters to express the material balancing of the cathode to anode. We introduced new terms, which are the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface ($Q_{is}$), to express precisely the irreversibility of an electrode/electrolyte system. Two terms depended on kinds of active-materials and compositions of the electrode, but did not change with charging state. MPCF had the highest value of IIE and the lowest value of $Q_{is}$ in 1M $LiPE_6$/EC + DEC (1 : 1 volume ratio) electrolyte. IIE value of $LiCoO_2$ electrode was 97-98%, although the preparation condition of the material and the electrolyte were different. $Q_{is}$ value of $LiCoO_2$ was 0~1 mAh/g. MPCF-$LiCoO_2$ cell system had the lowest of the latent capacity. $Q_{is}$ value increased slightly by adding conductive material. IIE and $Q_{is}$ value varied with the electrolyte. By introducing PC to EC+DEC mixed solvent, IIE values were retained, but $Q_{is}$ increased. In case of addition of MP, IIE value increased and $Q_{is}$ value also increased a little.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권5호
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• pp.189-193
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• 2003

Initial irreversible capacity (IIC) can be defined by means of the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface (IICs) with the linear-fit range of the intercalation so as to precisely express the irreversibility of an electrode-electrolyte system. Their relationship was IIC = Qc - Q$_{D}$ = (IIE$^{-1}$ - 1) Q$_{D}$ + IICs in the linear-fit range of IIE. Here, Qc and Qd signify charge and discharge capacity, respectively, based on a complete lithium ion battery cell. Charge indicates lithium insertion to carbon anode. Two terms of IIE and IICs depended on the types of active materials and compositions of the electrode and electrolyte but did not change with charging state. In an ideal electrode-electrolyte system, IIE and IICs would be 100%, 0 mAh/g for the electrode and mAh for the cell, respectively. These properties can be easily obtained by the Gradual Increasing of State of Charge (GISOC).OC).

• 방사성폐기물학회지
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• 제15권3호
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• pp.199-206
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• 2017

고준위폐기물을 처분하기 위한 심층 처분시설은 지하 500~1,000 m 깊이의 암반층에 설치된다. 심층 처분시스템의 구성 요소로는 처분용기, 완충재, 뒷채움 및 근계 암반이 있다. 이 중 완충재는 심층 처분시스템에 있어 필수적인 요소인데, 완충재는 지하수 유입으로부터 처분용기를 보호하고, 방사성 핵종 유출을 저지한다. 처분용기에서 발생하는 고온의 열량은 완충재로 전파되기에 완충재의 열물성은 처분시스템의 안정성 평가에 상당히 중요하다고 할 수 있다. 완충재의 열전도도 규명에 대한 연구는 많이 진행되고 있는 반면, 비열에 대한 연구는 미진한 상태이다. 따라서 본 연구에서는 국내 경주산 압축 벤토나이트 완충재(KJ-II)에 대한 비열 추정 모델을 개발하고자 하였다. 압축 벤토나이트 완충재의 비열은 이중 탐침법을 이용하여 다양한 포화도와 건조밀도에 따라 측정하였으며, 총 33개의 실험 데이터를 토대로 회귀분석을 이용하여 경주 압축 벤토나이트의 비열을 추정할 수 있는 모델을 제시하였다.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 1998년도 가을 학술발표회 프로그램
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• pp.2-4
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• 1998

Proliferation of Nocardia amarae cells in activated sludge has often been associated with the generation of nuisance foams. Despite intense research activities in recent years to examine the causes and control of Nocardia foaming in activated sludge, the foaming continued to persist throughout the activated sludge treatment plants in United States. In addition to causing various operational problems to treatment processes, the presence of Nocardia may have secondary effects on the fate of heavy metals that are not well known. For example, for treatment plants facing more stringent metal removal requirements, potential metal removal by Nocardia cells in foaming activated sludge would be a welcome secondary effect. In contrast, with new viosolid disposal regulations in place (Code o( Federal Regulation No. 503), higher concentration of metals in biosolids from foaming activated sludge could create management problems. The goal of this research was to investigate the metal sorption property of Nocardia amarae cells grown in batch reactors and in chemostat reactors. Specific surface area and metal sorption characteristics of N. amarae cells harvested at various growth stages were compared. Three metals examined in this study were copper, cadmium and nickel. Nocardia amarae strain (SRWTP isolate) used in this study was obtained from the University of California at Berkeley. The pure culture was grown in 4L batch reactor containing mineral salt medium with sodium acetate as the sole carbon source. In order to quantify the sorption of heavy metal ions to N amarae cell surfaces, cells from the batch reactor were harvested, washed, and suspended in 30mL centrifuge tubes. Metal sorption studies were conducted at pH 7.0 and ionlc strength of 10-2M. The sorption Isotherm showed that the cells harvested from the stationary and endogenous growth phase exhibited significantly higher metal sorption capacity than the cells from the exponential phase. The sequence of preferential uptake of metals by N. amarae cells was Cu>Cd>Ni. The specific surFace area of Nocardia cells was determined by a dye adsorption method. N.amarae cells growing at ewponential phase had significantly less specific surface area than that of stationary phase, indicating that the lower metal sorption capacity of Nocardia cells growing at exponential phase may be due to the lower specific surface area. The growth conditions of Nocardia cells in continuous culture affect their cell surface properties, thereby governing the adsorption capacity of heavy metal. The comparison of dye sorption isotherms for Nocardia cells growing at various growth rates revealed that the cell surface area increased with increasing sludge age, indicating that the cell surface area is highly dependent on the steady-state growth rate. The highest specific surface area of 199m21g was obtained from N.amarae cell harvested at 0.33 day-1 of growth rate. This result suggests that growth condition not only alters the structure of Nocardia cell wall but also affects the surface area, thus yielding more binding sites of metal removal. After reaching the steady-state condition at dilution rate, metal adsorption isotherms were used to determine the equilibrium distributions of metals between aqueous and Nocardia cell surfaces. The metal sorption capacity of Nocardia biomass harvested from 0.33 day-1 of growth rate was significantly higher than that of cells harvested from 0.5- and 1-day-1 operation, indicatng that N.amarae cells with a lower growth rate have higher sorpion capacity. This result was in close agreement with the trend observed from the batch study. To evaluate the effect of Nocardia cells on the metal binding capacity of activated sludge, specific surface area and metal sorption capacity of the mixture of Nocardia pure cultures and activated sludge biomass were determined by a series of batch experiments. The higher levels of Nocardia cells in the Nocardia-activated sludge samples resulted in the higher specific surface area, explaining the higher metal sorption sites by the mixed luquor samples containing greater amounts on Nocardia cells. The effect of Nocardia cells on the metal sorption capacity of activated sludge was evaluated by spiking an activated sludge sample with various amounts of pre culture Nocardia cells. The results of the Langmuir isotherm model fitted to the metal sorption by various mixtures of Nocardia and activated sludge indicated that the mixture containing higher Nocardia levels had higher metal adsorption capacity than the mixture containing lower Nocardia levels. At Nocardia levels above 100mg/g VSS, the metal sorption capacity of activate sludge increased proportionally with the amount of Noeardia cells present in the mixed liquor, indicating that the presence of Nocardia may increase the viosorption capacity of activated sludge.

• 한국재료학회지
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• 제26권9호
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• pp.493-497
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• 2016

This study was carried out to investigate the effect of deformation induced martensite on the damping capacity of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and; deformation induced martensite was formed with according to the specific direction and the surface relief. With an increasing degree of cold rolling, the volume fraction of ${\alpha}^{\prime}$-martensite increased rapidly, while the volume fraction of ${\varepsilon}$-martensite decreased after rising to a maximum value at a specific level of cold rolling. Damping capacity was increased, and then decreased with an increasing of the degree of cold rolling. Damping capacity was influenced greatly by the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of the volume fraction of ${\alpha}^{\prime}$-martensite have a actually on effect on the damping capacity.

• 한국과학교육학회지
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• 제16권2호
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• pp.134-145
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• 1996

The purpose of this study was to investigate effects of mental capacity and mental demand on problem solving. Two kinds of tests were used for this study. One was FIT 752 test which required general knowledge, the other was Ohm's law test which required domain specific knowledge. The items of each test had the same logical structure and content knowledge but had different sizes of mental demand. The results of the study were summarized as follows: As mental demand of the items increased, the success rates decreased. The analysis of the hierarchical relation among items was that items with large mental demand were higher than those with small demand or at least the same level. According to the results, mental of an item was a significant factor affecting solving the problem. Effect of mental capacity on problem solving was different according to the kind of required knowledge to solve. Mental capacity was a significant factor affecting solving the FIT 752 task which required general knowledge. On the contary, solving the task which required domain specific knowledge, the results were different depending on subjects' chunk size. The results of problem solving of the groups which had small chunk size were that mental capacity was appeared a significant factor. However, results of problem solving of groups which had large chunk size were that mental capacity was not.

• 열처리공학회지
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• 제10권1호
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• pp.47-54
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• 1997

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

• 센서학회지
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• 제32권1호
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• pp.39-43
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• 2023

Microscale thermophysical property measurements of liquids have been developed considering the increasing interest in the thermal management of cooling systems and energy storage/transportation systems. To accurately predict the heat transfer performance, information on the thermal conductivity, heat capacity, and density is required. However, a simultaneous analysis of the thermophysical properties of small-volume liquids has rarely been considered. Recently, we proposed a new methodology to simultaneously analyze the aforementioned three intrinsic properties using heater-integrated fluidic resonators (HFRs) in an atmospheric pressure environment comprising a microchannel, resistive heater/thermometer, and mechanical resonator. Typically, the thermal conductivity and volumetric heat capacity are measured based on a temperature response resulting from heating using a resistive thermometer, and the specific heat capacity can be obtained from the volumetric heat capacity by using a resonance densitometer. In this study, we analyze methods to improve the thermophysical property measurement performance using HFRs, focusing on the effect of the ambience around the sensor. The analytical method is validated using a numerical analysis, whose results agree well with preliminary experimental results. In a vacuum environment, the thermal conductivity measurement performance is enhanced, except for the thermal conductivity range of most gases, and the sensitivity of the specific heat capacity measurement is enhanced owing to an increase in the time constant.

• 한국시뮬레이션학회:학술대회논문집
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• 한국시뮬레이션학회 2000년도 춘계학술대회 논문집
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• pp.57-66
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• 2000

Production-distribution planning is the most important part in supply chain management (SCM). To solve this planning problem, either analytic or simulation approach has been developed. However these two approaches have their own demerits in problem solving. In this paper, we propose a hybrid approach which is a specific problem solving procedure combining analytic and simulation method to solve production-distribution problems in supply chain. The machine capacity and distribution capacity constraints in the analytic model are considered as stochastic factors and adjusted by the proposed specific process according to the results from independently developed simulation model which includes general production-distribution characteristics.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.144-148
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• 1997

We synthesized polyaniline films electrochemically under constant current conditions, which exhibited electric conductivity as high as 100 S/cm. By charge and discharge cycling of polyaniline films, we obtained specific discharge capacity as high as 195 mAH/g using HSO$_4$- doped polyaniline. For the polyaniline synthesized using H$_2$SO$_4$ and HClO$_4$ composite electrolyte. we also obtained specific discharge capacity as high as 134 mAHg which rivals inorganic electro- active materials.