• 제목/요약/키워드: Specific capacity

검색결과 1,551건 처리시간 0.03초

A Carbon Nanotubes-Silicon Nanoparticles Network for High Performance Lithium Rechargeable Battery Anodes

  • Kim, Byung Gon;Shin, Weon Ho;Lim, Soo Yeon;Kong, Byung Seon;Choi, Jang Wook
    • Journal of Electrochemical Science and Technology
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    • 제3권3호
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    • pp.116-122
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    • 2012
  • As an effort to address the chronic capacity fading of Si anodes and thus achieve their robust cycling performance, herein, we develop a unique electrode in which silicon nanoparticles are embedded in the carbon nanotubes network. Utilizing robust contacts between silicon nanoparticles and carbon nanotubes, the composite electrodes exhibit excellent electrochemical performance : 95.5% capacity retention after 140 cycles as well as rate capability such that at the C-rate increase from 0.1C to 1C to 10C, the specific capacities of 850, 698, and 312 mAh/g are obtained, respectively. The present investigation suggests a useful design principle for silicon as well as other high capacity alloying electrodes that undergo large volume expansions during battery operations.

Optimal Buffer Allocation in Multi-Product Repairable Production Lines Based on Multi-State Reliability and Structural Complexity

  • Duan, Jianguo;Xie, Nan;Li, Lianhui
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제14권4호
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    • pp.1579-1602
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    • 2020
  • In the design of production system, buffer capacity allocation is a major step. Through polymorphism analysis of production capacity and production capability, this paper investigates a buffer allocation optimization problem aiming at the multi-stage production line including unreliable machines, which is concerned with maximizing the system theoretical production rate and minimizing the system state entropy for a certain amount of buffers simultaneously. Stochastic process analysis is employed to establish Markov models for repairable modular machines. Considering the complex structure, an improved vector UGF (Universal Generating Function) technique and composition operators are introduced to construct the system model. Then the measures to assess the system's multi-state reliability and structural complexity are given. Based on system theoretical production rate and system state entropy, mathematical model for buffer capacity optimization is built and optimized by a specific genetic algorithm. The feasibility and effectiveness of the proposed method is verified by an application of an engine head production line.

기상 활성화법에 의한 대나무 활성탄 제조 (Production of Activated Carbon from Bamboo by Gas Activation Method)

  • 조광주;박영철
    • 에너지공학
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    • 제13권2호
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    • pp.166-172
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    • 2004
  • The activated carbon was produced from Sancheong bamboo by steam and carbon dioxide gas activation methods. The carbonization of raw material was conducted at 90$0^{\circ}C$ and gas activation reactions were conducted with respect to various conditions. -activation temperature 750-90$0^{\circ}C$, the flow rate of steam 0.5-2g-$H_2O$/g-char$.$hr, the flow rate of carbon dioxide 5-30$m\ell$-$CO_2$/g-char-min and activation time 1-5 hr. The prepared activated carbons were measured yield, the adsorption capacity of iodine and methylene blue, BET specific surface area and pore size distribution. The adsorption capacity of iodine (680.5-1526.1 mg/g) and methylene blue (18.3-221.5 mg/g) increased with creasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the activation gas quantity in the range of 0.5-1.5g-$H_2O$/g-charㆍhr, 5-18.9$m\ell$-Co$_2$/g-charㆍmin. But those decreased over those range due to the pore shrinkage. The steam activation method was superior in efficiency to carbon dioxide activation method.

하중제한이 기존건물의 옥상조경계획에 미치는 영향 (Influence of Load Limitation on the Roofspace Planning of Existing Buildings)

    • 한국조경학회지
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    • 제26권2호
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    • pp.166-180
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    • 1998
  • In a city where the greenery always lacks landscaping roofs of existing buildings offers a way to solve the problem. But the most serious problem that poses is the matter of load limit. At present most existing buildings have the loading capacity of 200 kg/$m^2$ or less on their roofs. If the natural soil is used the loading capacity is easily surpassed because it simply is too heavy. To alleviate this problem it is realized to introduce the light weight artificial soil. The specific gravity of light soil is 0.65 whereas the natural soil is 1.8 when wet. It is three times lighter than the natural soil, thus eases the burden to the roof. The next problem to be confronted is the plant species to plant. It is possible to plant trees but they soon outgrow the loading capacity by weighing 8 times heavier in 10 years. Therefore shrubs and perennials are suggested to be planted because they don't weigh much even when they reach the mature height. The last problem is the stress put on roofs by the weight of the users. By some unexpected event the crowd gathered on a weak roof can cause the structural damage or even the collapse of the roof. The avoid the possibility of collapse a plaza or big pocket should not be designed in a roof garden because they hold crowd. By following the suggested means the old roofs of existing buildings can turn into the urban oases in the sky.

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$MnO_2$입자 크기에 따른 아연공기전지의 특성연구 (Size Effects of the Catalyst on Characteristics of Zn/Air Batteries)

  • 김지훈;엄승욱;문성인;윤문수;김주용;육경창;박정후
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1129-1131
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    • 2002
  • Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820mAh/g. When Zinc Air battery discharged by low rate current discharge voltage profile has very flat pattern until end of voltage. But, when Zinc Air battery discharged by high rate current discharge voltage and capacity become lower. Therefore, we focused on effects of catalyst size in cathode. So we examined performance of zinc air batteries, average discharge voltage, capacity, energy, resistance. And we also obtained resistance by the GSM pulse discharge. So we have got optimum size of catalyst for Zinc Air battery.

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Electrochemical Properties of $LiM_xFe_{1_x}PO_4$ Cathode Materials By Solid-state Reaction

  • Wang, Wan-Lin;Park, Kyung-Hee;Gil, Hal-Bon;Park, Bok-Kee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.212-212
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    • 2010
  • Recently, lithium transition metal phosphates with an ordered olivine-type structure, $LiMPO_4$ (M=Fe, Mn, Ni, and Co), have attracted extensive attention due to a high theoretical specific capacity (170 mAh/g). The $LiMPO_4$ is the most attractive because of its high stability, low cost, high compatibility with environment. However, it is difficult to attain its full capacity because its electronic conductivity is very low, and diffusion of Li-ion in the olivine structure is slow and the supervalue cation doping was used. In this research, we are used the supervalue cation doping methode such as Cu, Ti, and Mg were partially replace the Fe. The cycling performance resulted of the used $LiM_xFe_{1_x}PO_4$ cathode materials for lithium batteries exhibit excellent high capacity than $LiFePO_4$/Li cells.

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폴리싸이오펜전극의 제조와 수퍼커패시터로서의 응용 (Preparation of polythiophene electrode and it's application for supercapacitor)

  • 김한주;류부형;;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.573-576
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    • 2001
  • In the research fields of energy storage, and more specifically of supplying high powers, electrochemical supercapacitor have been among the most studied systems for many years. One of the possible applications is in electric vehicles. We have been working on electronically conducting polymers for use as active materials for electrodes in supercapacitors. These polymers have the ability of doping and undoping with rather fast kinetics and have an excellent capacity for energy storage. polythiophene (Pth) and polyparafluorophenylthiophene (PFPT) have been chemically synthesized for use as active materials in supercapacitor electrodes. Electrochemical characterization has been performed by cyclic voltammetry and an electrode study has been achieved to get the maximun capacity out of the polymers and give good cyclability. specific capacity values of 7mAh/g and 40mAh/g were obtained for PFPT and poly thiophene, respectively. Supercapacitors have been built to characterize this type of system. Energy storage levels of 260F/g were obtained with Pth and 110F/g with PFPT.

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Systematic Analysis of the Anticancer Agent Taxol-Producing Capacity in Colletotrichum Species and Use of the Species for Taxol Production

  • Choi, Jinhee;Park, Jae Gyu;Ali, Md. Sarafat;Choi, Seong-Jin;Baek, Kwang-Hyun
    • Mycobiology
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    • 제44권2호
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    • pp.105-111
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    • 2016
  • Paclitaxel (taxol) has long been used as a potent anticancer agent for the treatment of many cancers. Ever since the fungal species Taxomyces andreanae was first shown to produce taxol in 1993, many endophytic fungal species have been recognized as taxol accumulators. In this study, we analyzed the taxol-producing capacity of different Colletotrichum spp. to determine the distribution of a taxol biosynthetic gene within this genus. Distribution of the taxadiene synthase (TS) gene, which cyclizes geranylgeranyl diphosphate to produce taxadiene, was analyzed in 12 Colletotrichum spp., of which 8 were found to contain the unique skeletal core structure of paclitaxel. However, distribution of the gene was not limited to closely related species. The production of taxol by Colletotrichum dematium, which causes pepper anthracnose, depended on the method in which the fungus was stored, with the highest production being in samples stored under mineral oil. Based on its distribution among Colletotrichum spp., the TS gene was either integrated into or deleted from the bacterial genome in a species-specific manner. In addition to their taxol-producing capacity, the simple genome structure and easy gene manipulation of these endophytic fungal species make them valuable resources for identifying genes in the taxol biosynthetic pathway.

도전재 종류와 양에 따른 LiMn$_2$O$_4$정극의 충방전 용량 및 Cycle 안정성 (Charge/discharge capacity and cycle salability of LiMn$_2$O$_4$cathode by sorts and volume of conductive agent)

  • 정인성;박계춘;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.275-278
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    • 1997
  • We investigated effectness of sort and volume of conductive agent to charge/discharge capacity of LiMn$_2$O$_4$. LiMn$_2$O$_4$is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$(mole ratio 1 : 2) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. All LiMn$_2$O$_4$cathode active materials show spinel structure. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, charge/discharge characteristics and cycle stability have remarkable advantages. Used that super-s-black and 20wt% as conductive agent in LiMn$_2$O$_4$, it is excellent than property of cathode used Acetylene black or mixture of Super-s-black and acetylene black at charge/discharge capacity and cycle stability. Also, specific efficiency of cathode is excellent as over 98% and that of first cycle is excellent as 92%.

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알루미늄 합금 소실모형주조 시의 주형충전재에 따른 특성변화 (Investigation on Characteristics of Various Mold Packing Materials in Lost Foam Casting of Aluminum Alloy)

  • 김기영;이경환;임경화
    • 한국주조공학회지
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    • 제22권3호
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    • pp.137-143
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    • 2002
  • Silica sand, zircon sand, and steel shots were used as mold packing materials in lost foam casting of the aluminum alloy bar. Vibration acceleration in three directions and temperatures in the casting and mold were measured, and packing and cooling characteristics of these materials were investigated. Packing densities increased with increase in vibration magnitude and time, and were $1.41{\sim}1.49g/cm^2$ for silica sand, $2.54{\sim}2.86g/cm^2$ for zircon sand, and $3.92{\sim}4.52g/cm^2$ for steel shots. Sound castings were obtained only without evacuation of the flask during pouring. Solidification time became faster in order of silica sand, zircon sand and steel shot packing because steel shot has the highest cooling capacity of them. Solidification time of steel shot packing was shortened to about 1/2 of silica sand packing. Cooling capacity of sand mold was generally evaluated by heat diffusivity of the mold, however could be simply evaluated with specific heat per unit volume of the packing material in lost foam casting.