• 마이크로전자및패키징학회지
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• 제28권1호
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• pp.61-66
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• 2021

SnO2는 3.6 eV를 갖는 반도체 물질로 광촉매 특성을 보유하고 있는 물질이다. 광촉매 특성을 극대화하기 위해 3차원 에어로겔 화를 통하여 높은 비표면적을 확보하고자 epoxide-initiated sol-gel method를 기반으로 하여 주석 산화물 에어로겔을 합성하였다. 좀더 향상된 비표면적을 구현하고자 합성공정 중 겔화전에 graphene oxide (GO) flake의 첨가를 통해 정렬된 기공구조와 결과적으로 높은 비표면적을 확보할 수 있었다. 0.5 wt%의 GO flake의 첨가로 에어로겔 복합체의 비표면적을 약 1.7배 향상시키는 결과를 도출하였다. 이렇게 향상된 비표면적을 기반으로 Rhodamine B 염료의 분해효과를 흡수광 intensity 변화를 관찰하여 정성적으로 광촉매 효율을 비교 분석하였다. 가장 높은 비표면적을 갖는 0.5 wt%의 복합체는 120분에 67.3%의 분해 효율을 확보하였다. 또한, GO를 첨가하지 않은 SnO2 에어로겔 보다 약 2배 향상된 reaction rate를 보유하였다.

• 자원리싸이클링
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• 제32권2호
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• pp.52-58
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• 2023

본 연구에서는 석회석 활용분야 확대를 위해 소석회를 이용한 소다라임 제조 기초 실험을 실시하였다. 소다라임 제조를 위해 압출식 방식과 디스크 방식의 펠렛타이져를 이용하였으며, 첨가제로 벤토나이트를 투입하여 제조한 소다라임의 이산화탄소 흡수 특성을 평가하였다. 실험결과, 제조 방식에 관계없이 이산화탄소와의 반응에 따라 소다라임에서 CaCO₃의 peak가 확인되었으며, 방해석과 아라고나이트가 함께 생성된 것을 확인하였다. 디스크 방식으로 제조한 소다라임이 압출방식에 비해 더 큰 비표면적을 나타내었고, 벤토나이트를 첨가한 조건에서도 비표면적이 향상되었다. 비표면적이 향상된 시료 조건에서 이산화탄소 흡수율이 증가되는 것으로 확인되었다.

• Journal of the Korean Wood Science and Technology
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• 제23권1호
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• pp.54-60
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• 1995

This paper reports on the changes of equilibrium moisture contents and specific surface areas of Poplar wood(Populus euramericana) for various steam explosion treatments. Equilibrium moisture contents(EMC) and specific surfaces of steam exploded woods were measured under the moisture adsorption course at 25$^{\circ}C$, and compared with those of other materials and wood meals. The EMCs of steam exploded wood meal were 1~5% less in comparison with that of wood meal. In the case of delignified steam exploded wood meal and delignified wood meal, the same tendency was appeared too. But absolute values of EMCs for delignified wood meals were larger than those of the wood meal. For the changes of EMC by the steam exploded conditions, the EMC decreased with the increase of the steam explosion pressure. On the other hand, specific surface areas were calculated from BET plots based on amounts of monomolecular vapor adsorption of various wood meals. Specific surface areas of the wood meal and delignified wood meal were 90~145, 34~90($m^2/g$) respectively, and which were greater in comparison with those of steam exploded wood meals and delignified steam exploded wood meals. From these results, it is considered that the amount of water vapor adsorption was decreased by the increase of the crystallinity, effect of heat treatment, and coating by melted lignin in during the steam explosion.

• 한국세라믹학회지
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• 제40권5호
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• pp.468-474
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• 2003

안정화 PAN(Polyacronitrile)계 섬유를 이용하여 물리적인 방법과 화학적인 방법으로 활성탄소섬유(Activated Carbon Fibers)를 제조하고, 그 특성을 비교평가 하였다. 본 연구에서는 안정화 PAN계 섬유를 수증기 및 $CO_2$를 이용한 물리적 활성화와 KOH를 이용한 화학적 활성화에 의해 여러 등급의 활성탄소섬유를 제조하였고, 비표면적, 요오드흡착량, 미세구조, 세공구조 등을 측정하였다. 물리적 활성화 방법에는 수증기와 $CO_2$가 사용되었는데, 수증기활성화의 경우 99$0^{\circ}C$의 활성화 온도에서 1635 m$^2$/g의 비표면적을 나타내었고, $CO_2$ 활성화의 경우에는 99$0^{\circ}C$의 활성화 온도에서 671 m$^2$/g의 비표면적을 나타내었다. KOH를 이용한 화학적 활성화 방법에서는 KOH와 안정화 PAN계 탄소섬유의 비가 1.5 : 1인 경우 90$0^{\circ}C$의 활성화 온도에서 3179 m$^2$/g의 비표면적을 나타내었다. 물리적 활성화와 화학적 활성화로 제조된 활성탄소섬유의 질소흡착등온선의 결과로 보면 type I의 형태와 type I에서 type II로의 전이형태의 등온흡착곡선을 나타내었다.

• 한국대기환경학회지
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• 제31권3호
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• pp.302-314
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• 2015

There is an adsorption method using activated carbon as a typical method for removing elemental mercury. Physical characteristics of activated carbon such as specific surface area and volume of pore (micro and meso) have positive effect for mercury adsorption. Activated carbon is carbon-based material with a high specific surface area. This activated carbon can be manufactured through carbonization and activation process. In this process, physical characteristics of specific surface area and pore distribution are changed by controlling operating parameters like temperature, time and reagent of activation. In this study, we evaluated characteristics of activated carbons manufactured from pinewood and coal with the operating parameters. We evaluated mercury adsorption capacities of the activated carbons having excellent physical characteristics and compared those to the commercial activated carbon.

• 한국세라믹학회지
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• 제30권4호
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• pp.279-288
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• 1993

A study on calcination and reduction of AUC(ammonium uranyl carbonate, (NH4)4UO2(CO3)3) has been carried out by using TG-DTA in N2, air and H2 atmospheres, respectively. Phases of various intermediate obtained during thermal analysis of AUC in different atmospheres were confirmed by XRD. Powder characteristics of each intermediate were investigated by measuring particle size and specific surface area, and also observed by SEM. As a results, regardless of applied atmosphere AUC was calcined into amorphous UO3, which was converted to $\alpha$-U3O8 Via $\alpha$-UO3 in both H2 and N2 atmosphere, but directly into $\alpha$-UO3 in air atmosphere. Further reduction of U3O8 was only detectable in hydrogen atmosphere. During calcination and reduction, average particle size was reduced to less than 30% of original value without morphology change. Specific surface area was dramatically increased with release of NH3, CO2 and H2O from AUC powder and reached maximum value around 25$0^{\circ}C$, and then gradually decreased with the increase of temperature due to sintering effect of uranium oxides such as UO3 and U3O8. It was also found that the change of average crystallite size and pore size were closely related to the changes of specific surface area of uranium oxides.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.94.2-94.2
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• 2011

In this work, multi-functional groups, i.e., nitrogen and oxygen, contained microporous carbons (MF-MCs) were prepared by the one step carbonization of the poly(vinylidene chloride-co-acrylonitrile-co-methyl methacryalte) (PVDC-AN-MMA) without activation. The electrochemical performance of MF-MCs was investigated as a function of carbonization temperature. It was found that MF-MCs had a high specific surface area over $800m^2/g$ without additional activation, resulting from the micropore's formation by the release of chlorine groups. In addition, although functional groups decreased, specific surface area was increased with increasing carbonization temperature, leading to the enhanced electrochemical performance. The pore size of the carbon distributed mainly in small micropore of 1.5 to 2 nm, which was idal for aqueous electrolyte. Indeed, the unique microstructure features, i.e. high specific surface area and optimized pore size provided high energy storage capability of MF-MCs. These results indicated that the microporous features of MF-MCs lead to feasible electron transfer during charge/discharge duration and the presence of nitrogen and oxygen groups on the MF-MCs electrode led to a pseudocapacitive reaction.

• 한국재료학회지
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• 제9권4호
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• pp.362-367
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• 1999

We intended to make the activated carbon fibers which could separate, remove and recover the volatile organic compounds of benzene, toluene, acetone and methanol. Changing activation temperature and time, large specific surface area and narrow pore distribution could be obtained. The activated carbon fibers have large adsorption capacity and selectivility for those organic compounds. We characterized the adsorption capability of the activated carbon fibers for benzene, toluene, acetone and methanol by BET specific surface area and pore size and micropore volume measurements. In the result of activation, the maximum value of BET specific surface area of the fibers was $1100\m^2$/g at $800^{\circ}C$ for 60 minutes and $K_2$O was reduced actively in this condition. Their average pore size was 5.8~5.9$\AA$. The activated carbon fibers prepared in this work had high adsorption rate to saturation and the selectibility for the above organic compounds. The adsorbed amount of acetone and methanol(diameter of$ 4.3\AA$ and $4.4\AA$ respectively) which are smaller than micropore diameter in size was 43~49%, which was larger value than benzene and toluene(in the same diameter as $5.9\AA$).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.346.1-346.1
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• 2014

Porous nano crystalline $TiO_2$ is currently used as a working electrode in a dye-sensitized solar cell (DSSC). The conventional working electrode is comprised of absorption layer (particle size:~20 nm) and scattering layer (particle size:~300 nm). We inserted window layer with 10 nm particle size in order to increase transmittance and specific surface area of $TiO_2$. The electrochemical impedance spectroscope analysis was conducted to analysis characterization of the electronic behavior. The Bode phase plot and Nyquist plot were interpreted to confirm the internal resistance caused by the insertion of window layer and carrier lifetime. The photocurrent that occurred in working electrode, which is caused by rise in specific surface area, increased. Accordingly, it was found that insertion of window layer in the working electrode lead to not only effectively transmitting the light, but also increasing of specific surface area. Therefore, it was concluded that insertion of window layer contributes to high conversion efficiency of DSSCs.

• 한국연초학회지
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• 제20권2호
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• pp.205-209
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• 1998

This study was conducted to evaluate the effect of triacetin(TA) treatment during manufacturing carbon dual filter for the adsorption of cigarette smoke components by activated carbons. The measurements were carried out by separation of activated carbon from carbon dual filter, and the specific surface area analyzed. The specific surface area of activated carbon from the domestic cigarette filter and from the foreign cigarette filter by degassing at 9$0^{\circ}C$ was 163$\pm$32$m^2$/g, and 16.6$\pm$1.9$m^2$/g, respectively. Those values were very lower than that of degassing at 35$0^{\circ}C$ (Domestic brand: 952$\pm$30$m^2$/g, and Foreign brand: 847$\pm$73$m^2$/g). By comparing the adsorption capacity of acetone and benzene with and without triacetin treated activated carbon, there was a 20% reduction of adsorption capacity by 5% triacetin treatment. Also, from the cilia toxicity test with carbon dual filter treated 0 % TA and 8 % TA, the cilia survival time was 706$\pm$74sec. and 603$\pm$64sec. for 0% TA and 8% TA, respectively. The delivery rate of vapour phase of cigarette smoke, which consists of main components of cilia toxicity, was higher at 8% TA filter than 0 % TA filter. Our results indicate that the treated TA covered the micro-pore of activated carbon, and then reduced specific surface area, finally, decreased the adsorption of vapour phase from cigarette smoke.